Homoleptic, σ-bonded octahedral [M(CO)6]2+ cations of iron(II), ruthenium(II), and osmium(II): Part 1: Syntheses, thermochemical and vibrational characterizations, and molecular structures as [Sb2F11]- and [SbF6]- salts. A comprehensive, comparative study

Inorganic Chemistry

Volumn 44, Issue 12, 2005, Pages 4189-4205

  Bernhardt, Eduard ^a,b,c   Bach, Christian ^a   Bley, Bianca ^a   Wartchow, Rudolf ^a   Westphal, Ulrich ^b   Sham, Iona H T ^d   Von Ahsen, Britta ^b   Wang, Chanqing ^d   Willner, Helge ^a,b,c   Thompson, Robert C ^d   Aubke, Friedhelm ^d  

^a LEIBNIZ UNIVERSITY HANNOVER   (Germany)

^b UNIVERSITY OF DUISBURG ESSEN   (Germany)

^c UNIVERSITY OF WUPPERTAL   (Germany)

^d UNIVERSITY OF BRITISH COLUMBIA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 20744445002     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic040115u     Document Type: Article

References (100)

1. Ellis, J. E. Adv. Organomet. Chem. 1990, 31, 1.
2. Ellis, J. E. Organometallics 2003, 22, 3322.
3. th ed.; Wiley: New York, 1988.
4. Ełschenbroich, C.; Salzer, A. Organometallics, 2nd ed.; VCH: Weinheim, Germany, 1992.
5. Crabtree, R. H. The Organometallic Chemistry of the Transition Metals, 2nd ed.; Wiley: New York, 1994.
6. Abel, E. W.; Tyfield, S. P. Adv. Organomet. Chem. 1970, 8, 117.
7. Beck, W.; Sünkel, K. Chem. Rev. 1988, 88, 1405.
8. Olah, G. A. Angew. Chem., Int. Ed. Engl. 1993, 32, 167.
9. Willner, H.; Aubke, F. Angew. Chem., Int. Ed. Engl. 1997, 36, 2402.
10. Willner, H.; Aubke, F. Organometallics 2003, 22, 3612.
11. Willner, H.; Aubke, F. In Inorganic Chemistry Highlights; Meyer, G. W., Naumann, D., Wesemann, L., Eds.; Wiley-VCH: Weinheim, Germany, 2002; p 195.
12. Willner, H.; Aubke, F. Chem. Eur. J. 2003, 9, 1668.
13. von Ahsen, B.; Berkei, M.; Henkel, G.; Willner, H.; Aubke, F. J. Am. Chem. Soc. 2002, 124, 8371.
14. Willner, H.; Bach, C.; Wartchow, R.; Wang, C.; Rettig, S. J.; Trotter, J.; Jonas, V.; Thiel, W.; Aubke, F. Inorg. Chem. 2000, 39, 1933.
15. Bach, C.; Willner, H.; Wang, C., Rettig, S. J.; Trotter, J.; Aubke, F. Angew. Chem., Int. Ed. Engl. 1996, 35, 1974.
16. von Ahsen, B.; Berkei, M.; Köckerling, M.; Willner, H.; Hägele, G.; Aubke, F. Inorg. Chem. 2003, 42, 3801.
17. Bernhardt, E.; Finze, M.; Willner, H.; Lehmann, C. W.; Aubke, F. Angew. Chem., Int. Ed. Engl. 2003, 42, 2077.
18. Wang, C.; Bley, B.; Blazer-Jöllenbeck, G.; Lewis, A. R.; Siu, S. C. ; Willner, H.; Aubke, F. J. Chem. Soc., Chem. Commun. 1995, 2071.
19. von Ahsen, B.; Bach, C.; Pernice, H.; Willner, H.; Aubke, F. J. Fluorine Chem. 2000, 102, 243.
20. Bernhardt, E.; Bley, B.; Wartchow, R.; Willner, H.; Bill, E.; Kuhn, P.; Sham, I. H. T.; Bodenbinder, M.; Bröchler, R.; Aubke, F. J. Am. Chem. Soc. 1999, 121, 7188 and references therein.
21. Jonas, V.; Thiel, W. Organometallics 1998, 17, 353.
22. Szillagy, R. Frenking, G. Organometallics 1997, 16, 4807.
23. Ehlers, A. W.; Ruiz-Morales, Y.; Baerends, F. J.; Ziegler, T. Inorg. Chem. 1997, 36, 5031.
24. Diefenbach, A.; Bickelhaupt, F. M.; Frenking, G. J. Am. Chem. Soc. 2000, 122, 6449.
25. Barr, J.; Thompson, R. C.; Gillespie, R. J. Inorg. Chem. 1964, 3, 1149.
26. Zhang, D.; Rettig, S. J.; Trotter, J.; Aubke, F. Inorg. Chem. 1996, 35, 6113.
27. Dudley, F. B.; Cady, G. H. J. Am. Chem. Soc. 1959, 79, 513.
28. Zhang, D.; Wang, C.; Mistry, F.; Powell, B.; Aubke, F. J. Fluorine Chem. 1996, 76, 83.
29. Leung, P. C.; Aubke, F. Can. J. Chem. 1984, 62, 2892.
30. Leung, P. C.; Wong, G. B.; Aubke, F. J. Fluorine Chem. 1987, 35, 607.
31. Weinstock, B.; Malm, J. G. J. Am. Chem. Soc. 1958, 80, 4466.
32. Holloway, J. H. Chem. Commun. 1966, 22.
33. Sheldrick, G. M. SHELXS-86: Program for Crystal Structure Solution; Universität Göttingen: Göttingen, Germany, 1986.
34. Sheldrick, G. M. SHELXS-93: Program for Crystal Structure Refinement; Universität Göttingen: Göttingen, Germany, 1993.
35. O'Donnell, T. A. Superacids and Acidic Melts as Inorganic Reaction Media; VCH: Weinheim, Germany, 1993.
36. Olah, G. A.; Prakash, G. K. S.; Sommer, J. Superacids; Wiley: New York, 1985.
37. Fahré, P. L.; Devynk, J.; Tremillon, B. Chem. Rev. 1982, 82, 591.
38. Christe, K. O.; Dixon, D. A.; McLemore, D.; Wilson, W. W.; Sheehy, J. A. ; Boatz, J. A. J. Fluorine Chem. 2000, 101, 151.
39. Hyman, H. M.; Quaterman, L.; Kirkpatrick, M.; Katz, J. J. Phys. Chem. 1961, 65, 123.
40. Gillespie, R. J.; Moss, K. C. J. Chem. Soc. A 1966, 1170.
41. Culman, J.-C.; Fauconet, M., Jost, R.; Sommer, J. New J. Chem. 1999, 23, 863 and references therein.
42. Bröchler, R., Sham, I. H. T.; Bodenbinder, M.; Schmitz, V.; Rettig, S. J.; Trotter, J.; Willner, H.; Aubke, F. Inorg. Chem. 2000, 39, 2172.
43. Willner, H.; Bodenbinder, M.; Bröchler, R.; Hwang, G.; Rettig, S. J.; Trotter, J.; v. Ahsen, B.; Westphal, U.; Jonas, V.; Thiel, W.; Aubke, F. J. Am. Chem. Soc. 2001, 123, 588.
44. Bodenbinder, M.; Bałzer-Jöllenbeck, G., Willner, H.; Batchelor, B. J.; Einstein, F. W. B.; Wang, C.; Aubke, F. Inorg. Chem. 1996, 35, 82.
45. Willner, H.; Schaebs, J.; Hwang, G.; Mistry, F.; Jones, R.; Trotter, J.; Aubke, F. J. Am. Chem. Soc. 1992, 114, 8972.
46. Küster, R.; Seppelt, K. Z. Anorg. Allg. Chem. 2000, 626, 236.
47. Pearson, R. J. J. Am. Chem. Soc. 1963, 85, 3533.
48. Ahrland, S.; Chatt, J.; Davies, N. R. Q. Rev. Chem. Soc. 1958, 12, 265.
49. Pyykkö, P.; Desclaux, P. J. Acc. Chem. Res. 1979, 12, 276.
50. Pyykkö, P. Chem. Rev. 1988, 88, 563.
51. Goldman, A. S.; Krogh-Jesperson, K. J. Am. Chem. Soc. 1996, 118, 12159.
52. Gantar, D.; Leban, I.; Frlec, B.; Holloway, J. H. J. Chem. Soc., Dalton Trans. 1987, 2379.
53. Figgis, B. N. Introduction to Ligand Fields; Interscience: New York, 1966.
54. Bley, B.; Willner, H.; Aubke, F. Inorg. Chem. 1997, 36, 158.
55. Sham, I. H. T. Ph.D. Thesis, University of British Columbia, 2002.
56. Sham, I. H. T.; Willner, H.; Thompson, R. C.; Aubke, F., manuscript in preparation.
57. Birchall, T.; Dean, P. A. W.; Valle, B. D.; Gillespie, R. J. Can. J. Chem. 1975, 53, 667.
58. Bröchler, R.; Freidank, D.; Bodenbinder, M.; Sham, I. H. T.; Willner, H.; Rettig, S. J.; Trotter, J.; Aubke, F. Inorg. Chem. 1999, 38, 3684.
59. McRae, V. M.; Peacock, R. D.; Russel, D. R. Chem. Commun. 1969, 62.
60. Sladky, F. Noble Gases; Butterworth: London, 1972; Vol. 3.
61. Nandana, W. A. S.; Passmore, J.; White, P. S. J. Chem. Soc., Dalton Trans. 1985, 1623.
62. Manchot, W.; Manchot, W. J. Z. Anorg. Allg. Chem. 1936, 236, 385.
63. Hieber, W.; Stallmann, H. Z. Elektrochem. 1943, 49, 288.
64. Calderazzo, F.; L'Eplattenier, F. Inorg. Chem. 1967, 6, 1220.
65. Rushman, P.; van Buren, G. N.; Shiralian, M.; Pomeroy, R. K. Organometallics 1983, 2, 693.
66. Huang, J.; Hedberg, K.; Pomeroy, R. K. Organometallics 1988, 7, 2049.
67. Huang, J.; Hedberg, K.; Davies, H. B.; Pomeroy, R. K. Inorg. Chem. 1990, 29, 3923.
68. Hieber, W.; Kruck, T. Angew. Chem. 1961, 73, 580.
69. Sternberg, H. W.; Friedel, A. R.; Shufler, S. L.; Wender, I. J. J. Am. Chem. Soc. 1955, 77, 2675.
70. Hieber, W.; Frey, V.; John, P. Chem. Ber. 1967, 100, 1961.
71. Bernhardt, E.; Willner, H.; Aubke, F. Angew. Chem., Int. Ed. 1999, 36, 823.
72. Bernhardt, E.; Willner, H.; Jonas, V.; Thiel, W.; Aubke, F. Angew. Chem., Int. Ed. 2000, 39, 168.
73. Hurlburt, P. K.; Rack, J. J.; Luck, J. S.; Dec, S. F.; Webb, J. D.; Anderson, O. P.; Strauss, S. H. J. Am. Chem. Soc. 1994, 116, 10003.
74. Strauss, S. H. J. Chem. Soc., Dalton Trans. 2000, 1.
75. Lupinetti, A. J.; Frenking, G.; Strauss, S. H. Prog. Inorg. Chem. 2001, 49, 1.
76. Krossing, I. Chem. Eur. J. 2001, 7, 490.
77. Reed, C. Acc. Chem. Res. 1998, 31, 133.
78. Strauss, S. H. Chem. Rev. 1993, 93, 927.
79. Hieber, W. Advances in Organometallic Chemistry; Academic Press: New York, 1970; Vol. 8.
80. Hieber, W.; Bader, C. Chem. Ber. 1928, 61, 1717.
81. Hieber, W.; Lagally, H. Z. Anorg. Aug. Chem. 1940, 245, 295.
82. Hieber, W.; Wirsching, A. Z. Anorg. Allg. Chem. 1940, 245, 35.
83. Doherty, N. N.; Hoffman, N. W. Chem. Rev. 1991, 91, 553.
84. Murphy, E. F.; Murgavel, R.; Roesky, H. W. Chem. Rev. 1997, 97, 3425.
85. Hieber, W.; Lagally, H.; Wirsching, A. Z. Anorg. Allg. Chem. 1940, 245, 3005.
86. Iqbal, Z.; Waddington, T. C. J. Chem. Soc. A 1968, 1238.
87. von Ahsen, B.; Bley, B.; Bodenbinder, M.; Balzer, G.; Willner, H.; Hwang-Mistry, G.; Wang, C.; Hägele, G.; Aubke, F. Inorg. Chem., in preparation.
88. Wang, C.; Willner, H.; Bodenbinder, M.; Batchelor, R.; Einstein, F. W. B.; Aubke, F. Inorg. Chem. 1994, 33, 3521.
89. von Ahsen, B.; Wartchow, R.; Willner, H.; Jonas, V.; Aubke, F. Inorg. Chem. 2000, 39, 4424.
90. Orpen, A. G.; Brammer, L.; Allen, F. H.; Kennard, O.; Watson, D. G.; Taylor, R. J. Chem. Soc., Dalton Trans. 1989, Suppl. 1.
91. Bruce, D. M.; Holloway, J. H.; Russell, D. R. J. Chem. Soc., Dalton Trans. 1978, 64.
92. Alcock, N. W. Adv. Inorg. Chem. Radiochem. 1972, 15, 1.
93. Sham, I. H. T.; Patrick, B. O.; Thompson, R. C.; Aubke, F.; von Ahsen, B.; von Ahsen, S.; Willner, H. Solid State Sci. 2002, 4, 1457.
94. Bondi, A. J. Phys. Chem. 1964, 68, 441.
95. Jones, L. H.; McDowell, R. S.; Goldblatt, M. Inorg. Chem. 1988, 27, 2349.
96. Abel, E. W.; McLean, R. A. N.; Tyfield, S. P.; Braterman, P. S.; Walker, A. P.; Hendra, P. J. J. Mol. Spectrosc. 1969, 30, 29.
97. Cotton, F. A.; Kraihanzel, C. S. J. Am. Chem. Soc. 1962, 84, 4432.
98. Dewar, J. S. Bull. Soc. Chim. Fr. 1951, 18, C71.
99. Chatt, J.; Duncanson, L. A. J. Chem. Soc. 1953, 2939.
100. Finze, M.; Bernhardt, E.; Willner, H.; Lehmann, C. W.; Aubke, F. Inorg. Chem, 2005, 44, 4206-4214.