Formation of 4,4-dialkoxycyclohexa-2,5-dienone N-(Thiol-S-yl)imine during reaction of 4-alkoxynitrosobenzenes with Thiols in alcoholic solvents

Chemical Research in Toxicology

Volumn 11, Issue 12, 1998, Pages 1423-1433

  Gallemann, Dieter ^a,b   Buhrow, Ingrid ^a,c  

^a UNIVERSITY OF MUNICH   (Germany)

^b MERCK KGAA   (Germany)

^c MAX PLANCK INSTITUTE OF BIOCHEMISTRY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ACETAL DERIVATIVE; ALCOHOL; ALKOXYBENZENE DERIVATIVE; GLUTATHIONE; NITROSOBENZENE; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; SOLVENT; SULFENAMIDE DERIVATIVE; THIOL DERIVATIVE;

ALLERGIC REACTION; ARTICLE; CARCINOGENICITY; CHEMICAL REACTION; CHEMICAL STRUCTURE; DETOXIFICATION; MUTAGENICITY; SYNTHESIS;

ALCOHOLS; ALKANES; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; DRUG STABILITY; MAGNETIC RESONANCE SPECTROSCOPY; NITROSO COMPOUNDS; SOLVENTS; SPECTROMETRY, MASS, FAST ATOM BOMBARDMENT; SPECTROPHOTOMETRY, INFRARED; SPECTROPHOTOMETRY, ULTRAVIOLET; SULFHYDRYL COMPOUNDS;

EID: 20644468190     PISSN: 0893228X     EISSN: None     Source Type: Journal    
DOI: 10.1021/tx980088i     Document Type: Article

References (2)

1. Eyer, P., and Gallemann, D. (1996) Reactions of nitrosoarenes with SH groups. In The Chemistry of Amino, Nitroso, Nitro and Related Groups (Patai, S., Ed.) Vol. Suppl. F2, Part 2, pp 999-1040, John Wiley & Sons, Chichester.
2. Kazanis, S., and McClelland, R. A. (1992) Electrophilic intermediate in the reaction of glutathione and nitrosoarenes. J. Am. Chem. Soc. 114, 3052-3059.