Formylmethyl and Formylmethylperoxyl Radicals and Their Chlorinated Derivatives. Formation and Reactions in Irradiated Aqueous Solutions

Journal of Physical Chemistry

Volumn 100, Issue 39, 1996, Pages 15961-15967

  Alfassi, Z B ^a   Khaikin, G I ^a   Johnson III, R D ^b   Neta, P ^c  

^a NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY   (United States)

^b BEN GURION UNIVERSITY OF THE NEGEV   (Israel)

^c RUSSIAN ACADEMY OF SCIENCES   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 20644452310     PISSN: 00223654     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp961628s     Document Type: Article

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28. It is interesting to note, however, that when the radical site is shifted from the α-carbon to the carbonyl carbon, hydration of the carbonyl group becomes extremely rapid, as has been reported for the acetyl radical (Schuchmann, M. N.; von Sonntag, C. J. Am. Chem. Soc. 1988, 110, 5698).
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31. -) ∼ G(OH) ∼ 2.8, since the yield of captured radicals increases with solute concentration and 2-PrOH was used at relatively high concentrations.
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