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Volumn , Issue 9, 2005, Pages 1389-1392

Deoxygenation of N-oxides with triphenylphosphine, catalyzed by dichlorodioxomolybdenum(VI)

Author keywords

Azoxy compounds; Molybdenum(VI); N oxides; Nitrones; Oxotransfer catalysis

Indexed keywords

CHLORINE DERIVATIVE; MOLYBDENUM COMPLEX; OXIDE; TRIPHENYLPHOSPHINE;

EID: 20544478114     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2005-868504     Document Type: Article
Times cited : (82)

References (28)
  • 2
    • 0000648778 scopus 로고
    • Trost, B. M.; Fleming, I., Eds.; Pergamon: Oxford
    • (b) Gilchrist, T. L. In Comprehensive Organic Synthesis, Vol. 8; Trost, B. M.; Fleming, I., Eds.; Pergamon: Oxford, 1991, 390.
    • (1991) Comprehensive Organic Synthesis , vol.8 , pp. 390
    • Gilchrist, T.L.1
  • 15
    • 20544458404 scopus 로고    scopus 로고
    • note
    • 3 only deoxygenates pyridine N-oxides at temperatures over 250 °C.
  • 24
    • 20544469989 scopus 로고    scopus 로고
    • unpublished results
    • We have found that in general alkylamines react with dioxomolybdenum chlorides leading to decomposition products some of them have been characterized as alkylammonium polymolybdates: Arnáiz, F. J.; Pedrosa, M. R.; Aguado, R. unpublished results.
    • Arnáiz, F.J.1    Pedrosa, M.R.2    Aguado, R.3
  • 25
    • 20544462918 scopus 로고    scopus 로고
    • note
    • The complete reduction of 5 required about 15 h.
  • 26
    • 33845281614 scopus 로고
    • See for instance: (a) Holm, R. H. Chem. Rev. 1987, 87, 1401.
    • (1987) Chem. Rev. , vol.87 , pp. 1401
    • Holm, R.H.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.