Similar luminescent behavior in an established rhenacarborane complex, [3,3-(CO)2-3-NO-closo-3,1,2-ReC2B9H 11] and a new complex anion, [3,3,3-(CO)3-8-I-closo-3,1,2- ReC2B9H10]-

Journal of Luminescence

Volumn 114, Issue 1, 2005, Pages 60-64

  Fischer, Matthew J ^a   Jelliss, Paul A ^a   Orlando, Justin H ^a   Phifer, Lisa M ^a   Rath, Nigam P ^b  

^a Saint Louis University   (United States)

^b UNIVERSITY OF MISSOURI ST LOUIS   (United States)

Author keywords

Carborane; Exciplex; Luminescence; Rhenium

Indexed keywords

CARBON; COMPLEXATION; ENERGY ABSORPTION; ENERGY GAP; LIGHT REFLECTION; NEGATIVE IONS; PHOSPHORESCENCE; PROBABILITY DENSITY FUNCTION; RHENIUM; SPECTROSCOPIC ANALYSIS; SPECTRUM ANALYSIS; ULTRAVIOLET RADIATION;

CARBORANE; EXCIPLEX; HIGHEST OCCUPIED MOLECULAR ORBITALS (HOMO); POLYHEDRAL SKELETAL ELECTRON (PSE);

RHENIUM COMPOUNDS;

EID: 20544440273     PISSN: 00222313     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jlumin.2004.12.005     Document Type: Article

References (23)

1. M.S. Wrighton, and D.L. Morse J. Am. Chem. Soc. 96 1974 998
2. S.M. Fredericks, J.C. Luong, and M.S. Wrighton J. Am. Chem. Soc. 101 1979 7415
3. J.V. Caspar, B.P. Sullivan, and T.J. Meyer Inorg. Chem. 23 1984 2104
4. A.J. Lees Chem. Rev. 87 1987 711
5. B.P. Sullivan J. Phys. Chem. 93 1989 24
6. T.J. Meyer Acc. Chem. Res. 22 1989 163
7. V.W.-W. Yam J. Chem. Soc. Chem. Commun. 2001 789
8. M.F. Hawthorne, and T.D. Andrews J. Am. Chem. Soc. 87 1965 2496
9. A. Zalkin, T.E. Hopkins, and D.H. Templeton Inorg. Chem. 5 1966 1189
10. D.D. Ellis, P.A. Jelliss, and F.G.A. Stone Organometallics 18 1999 4982
11. D.D. Ellis, P.A. Jelliss, and F.G.A. Stone J. Chem. Soc., Chem. Commun. 1999 2385
12. T.E. Bitterwolf, W.B. Scallorn, C.A. Weiss, and P.A. Jelliss Organometallics 21 2002 1856
13. M.F. Hawthorne, J.I. Zink, J.M. Skelton, M.J. Bayer, C. Liu, E. Livshits, R. Baer, and D. Neuhauser Science 303 2004 1849
14. O. Crespo, M.C. Gimeno, P.G. Jones, A. Laguna, J.M. López-de- Luzuriaga, M. Monge, J.L. Pérez, and M.A. Ramón Inorg. Chem. 64 2003 2000
15. -1). The lower energy absorptions have been previously reported and discussed in Ref. [4].
16. H. Kunkely, V. Pawlowski, and A. Vogler Inorg. Chim. Acta 335 2002 147 150
17. Photoluminescence measurements were made on 50 μM solutions with a Photon Technologies QM4 fluorescence spectrophotometer with a Xe arc lamp light source and digital PMT detector. Emission and reference source gain excitation corrections were applied to all data, with the exception of the solid-state measurement, where an excitation correction was applied using the standard instrument configuration. Slit widths were set between 2 and 5 nm. Appropriate cut-off filters were used to eliminate peaks due to solvent Raman-shifted bands and excitation harmonics. Solution samples (50 μM) at ambient temperatures were measured in a quartz sample cuvette with Schlenk attachment to deoxygenate samples. Samples measured at 77 K were degassed and analyzed in a quartz NMR tube with Schlenk attachment and set in a quartz-bottomed Dewar flask in an argon-filled sample chamber. Solid-state samples (ca. 5-10 mg) were mounted in a fabricated powder sample holder and analyzed in the reflectance mode. Excited state decay measurements for complex 3a were made using a Xe flash lamp. Data were collected over 100 channels and with an integration time of 10 μs. A total of 25 shots were taken at a frequency of 10 Hz for each data point, and the total decay was then averaged over three experimental runs, without an instrument response function.
18. L.J. Bellamy, W. Gerrard, M.F. Lappert, and R.L. Williams J. Chem. Soc. Abstr. 1958 2412
19. F. Hanousek, B. Štíbr, S. Heřmanek, J. Plešek, A. Vitek, and F. Haruda Collectn. Czech. Chem. Commun. 37 1972 3001
20. 3Re (661.45); C, 9.1; H, 1.5; I, 19.2. Found: C, 9.3; H, 1.6; I, 18.8%.
21. -3.
22. A. Vogler, and H. Kunkely Coord. Chem. Rev. 171 1998 3
23. J.R. Lakowicz Principles of Fluorescence Spectroscopy 1983 Plenum New York