Nitromethane as solvent in capillary electrophoresis

Journal of Chromatography A

Volumn 1079, Issue 1-2 SPEC. ISS., 2005, Pages 246-253

  Subirats, Xavier ^a,b   Porras, Simo P ^c   Rosés, Martí ^b   Kenndler, Ernst ^a  

^a UNIVERSITY OF VIENNA   (Austria)

^b UNIVERSITY OF BARCELONA   (Spain)

^c UNIVERSITY OF HELSINKI   (Finland)

Author keywords

Capillary electrophoresis; Contactless conductivity detection; Heteroconjugation; Mobility; Nitromethane; Non aqueous; Organic solvent; pKa shift; UV detection

Indexed keywords

BOILING LIQUIDS; CONCENTRATION (PROCESS); DISSOCIATION; ELECTROLYTES; ELECTROPHORESIS; FREEZING; IONIC STRENGTH; METHANE; SOLUTIONS; VISCOSITY OF LIQUIDS;

BOILING POINT; FREEZING POINT; HETEROCONJUGATION; IONIC CONSTITUENT;

ORGANIC SOLVENTS;

BUFFER; CHLORIDE; ELECTROLYTE; NITROMETHANE; SOLVENT; WATER;

ARTICLE; CAPILLARY ELECTROPHORESIS; COMPARATIVE STUDY; COMPLEX FORMATION; CONCENTRATION (PARAMETERS); CONJUGATION; ELECTROPHORETIC MOBILITY; IONIC STRENGTH; PH; PRIORITY JOURNAL; THEORETICAL STUDY;

ELECTROPHORESIS, CAPILLARY; HYDROGEN-ION CONCENTRATION; METHANE; NITROPARAFFINS; OSMOLAR CONCENTRATION; SOLVENTS; SPECTROPHOTOMETRY, ULTRAVIOLET; VISCOSITY; WATER;

EID: 20444493552     PISSN: 00219673     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chroma.2005.02.072     Document Type: Article

References (20)

1. J. Muzikar, T. van de Goor, and E. Kenndler Anal. Chem. 74 2002 434
2. S.P. Porras, M.-L. Riekkola, and E. Kenndler Electrophoresis 24 2003 1485
3. X.-L. Liu, J.-D. Wang, and L.-H. Su Fenxi Shiyanshi 20 2001 8
4. S.B. Markofsky B. Elvers S. Hawkins G. Schulz Ullmann's Encyclopedia of Industrial Chemistry 1991 VCH Weinheim
5. Y. Marcus The Properties of Solvents 1998 Wiley Chichester
6. K. Izutsu Acid-Base Dissociation Constants in Dipolar Aprotic Solvents 1990 Blackwell Oxford
7. K. Izutsu Electrochemistry in Nonaqueous Solutions 2002 Wiley-VCH Weinheim
8. D. Augustin-Nowacka, and L. Chmurzynski J. Solution Chem. 29 2000 837
9. E. Kaczmarczyk, K. Maj, and L. Chmurzynski J. Chem. Thermodyn. 32 2000 901
10. R. Fernández-Prini A.K. Covington T. Dickinson Physical Chemistry of Organic Solvent Systems 1973 Plenum Press London 525
11. A. D'Aprano, B. Sesta, V. Mauro, and M. Salomon J. Solution Chem. 29 2000 1075
12. B. Gaš, J. Zuska, P. Coufal, and T. van de Goor Electrophoresis 23 2002 3520
13. T. Okada J. Chromatogr. A 771 1997 275
14. S.P. Porras, and E. Kenndler Electrophoresis 25 2004 2946
15. S.P. Porras, E. Kenndler, Electrophoresis 26 (2005) in press.
16. K. Sarmini, and E. Kenndler J. Biochem. Biophys. Methods 38 1999 123
17. S.P. Porras, K. Sarmini, S. Fanali, and E. Kenndler Anal. Chem. 75 2003 1645
18. Y. Marcus, M.J. Kamlet, and R.W. Taft J. Phys. Chem. 92 1988 3613
19. Y. Marcus Ion Properties 1997 Marcel Dekker New York
20. A. Albert, and E.P. Serjeant The Determination of Ionization Constants - A Laboratory Manual 1984 Chapman and Hall London