Trigonal-prismatic vs. Octahedral geometry for MnII Complexes with innocent didentate ligands: A subtle difference as shown by XRD and DFT on [Mn(acac)2(bpy)]

European Journal of Inorganic Chemistry

Volumn , Issue 11, 2005, Pages 2255-2261

  Van Gorkum, Remy ^a   Buda, Francesco ^a   Kooijman, Huub ^b   Spek, Anthony L ^b   Bouwman, Elisabeth ^a   Reedijk, Jan ^a  

^a LEIDEN UNIVERSITY   (Netherlands)

^b UTRECHT UNIVERSITY   (Netherlands)

Author keywords

Density Functional Theory (DFT); Distorted octahedron; Manganese(II); Packing effects; Trigonal prism

Indexed keywords

CRYSTAL STRUCTURE; DENSITY FUNCTIONAL THEORY; ELECTRON SPIN RESONANCE SPECTROSCOPY; GEOMETRY; MAGNETIC SUSCEPTIBILITY; MANGANESE COMPOUNDS; SINGLE CRYSTALS; X RAY DIFFRACTION;

COORDINATION GEOMETRY; DENSITY FUNCTIONAL THEORY; DENSITY-FUNCTIONAL-THEORY; DISTORTED OCTAHEDRON; MANGANESE(II); OCTAHEDRAL GEOMETRY; PACKING EFFECTS; PRISMATIC STRUCTURES; TRIGONAL PRISMS; XRD;

LIGANDS;

EID: 20444469340     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200401005     Document Type: Article

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