Dicopper and disilver complexes of octaphyrin(1.1.1.1.1.1.1.1): Reversible hydrolytic cleavage of the pyrrolic ring to a keto-imine

Angewandte Chemie - International Edition

Volumn 44, Issue 24, 2005, Pages 3726-3729

  Shimizu, Soji ^a   Tanaka, Yasuo ^a   Youfu, Katsuyuki ^a   Osuka, Atsuhiro ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

Copper; Macrocycles; Porphyrinoids; Silver

Indexed keywords

COMPLEXATION; COPPER; HYDROLYSIS; IONS; SILVER;

DISILVER COMPLEXES; HYDROLYTIC RINGS; PYRROLE RINGS; SILVER IONS;

AROMATIC HYDROCARBONS;

EID: 20444450615     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200500676     Document Type: Article

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25. w = 0.1731 (all data), GOF = 0.972 (I ' 2σ(I)).
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28. w = 0.253 (all data), GOF = 1.298 (I ' 2σ(I)).
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34. w = 0.117 (I ' 3σ(I)), GOF = 0.945. CCDC-264267 (5), 264268 (9), and 264302 (8) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
35. 1 ions probably as a result of through-space interactions (see Supporting Information).