Effects of pH on dynamics and rheology during association and gelation via the Ugi reaction of aqueous alginate

European Polymer Journal

Volumn 41, Issue 8, 2005, Pages 1708-1717

  Bu, Huaitian ^a   Kjøniksen, Anna Lena ^a   Nyström, Bo ^a  

^a UNIVERSITY OF OSLO   (Norway)

Author keywords

Alginate; Dynamics; Gelation; pH effect; Rheology; Ugi cross linking reaction

Indexed keywords

CONDENSATION; CROSSLINKING; ENZYME IMMOBILIZATION; GELATION; HYDROPHOBICITY; PH EFFECTS; POSITIVE IONS; REACTION KINETICS; RELAXATION PROCESSES; RHEOLOGY; SOLUTIONS;

ALGINATE; DIVALENT CATIONS; HYDROPHOBIC PROPERTIES; UGI CROSS LINKING REACTION;

HYDROGELS;

EID: 20444410038     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2005.02.035     Document Type: Article

References (43)

1. R.L. Reis D. Cohn Polymer based systems on tissue engineering replacement and regeneration 2002 Kluwer Academic Dordrecht
2. A. Haug, B. Larsen, and O. Smidsrød A study of the constitution of alginic acid by partial acid hydrolysis Acta Chem Scand 20 1 1966 183 190
3. A. Haug, B. Larsen, and O. Smidsrød Sequence of uronic acid residues in alginic acid Acta Chem Scand 21 3 1967 691 704
4. A. Haug, S. Myklestad, B. Larsen, and O. Smidsrød Correlation between chemical structure and physical properties of alginate Acta Chem Scand 21 3 1967 768 778
5. R. Kohn, I. Furda, A. Haug, and O. Smidsrød Binding of calcium and potassium ions to some polyuronides and monouronates Acta Chem Scand 22 10 1968 3098 3102
6. O. Smidsrød, and A. Haug Dependence upon the gel-sol state of the ion-exchange properties of alginates Acta Chem Scand 26 5 1972 2063 2074
7. O. Smidsrød, A. Haug, and S.G. Whittington Molecular basis for some physical properties of glycuronans Acta Chem Scand 26 6 1972 2563 2566
8. M.A. LeRoux, F. Guilak, and L.A. Setton Compressive and shear properties of alginate gel: effects of sodium ions and alginate concentration J Biomed Mater Res 47 1 1999 46 53
9. A. King Brown seaweed extracts (alginates) M. Glicksman Food hydrocolloids Vol. 2 1983 CRC Press Boca Raton, FL 115 188
10. K.I. Draget, G. Skjåk Bræk, and O. Smidsrød Alginic acid gels: the effect of alginate chemical composition and molecular weight Carbohydr Polym 25 1 1994 31 38
11. S.G. Baldursdóttir, and A.L. Kjøniksen Rheological characterization and turbidity of riboflavin-photosensitized changes in alginate/GDL systems Eur J Pharm Biopharm 59 3 2005 501 510
12. E.D.T. Atkins, W. Mackie, K.D. Parker, and E.E. Smolko Crystalline structures of poly-d-mannuronic and poly-l-guluronic acids J Polym Sci B 9 4 1971 311 316
13. I. Ugi, S. Lohberger, and R. Karl The Passerini and Ugi reaction B.M. Trost C.H. Heathcock Comprehensive organic synthesis Vol. 2 1991 Pergamon Press Oxford 1083 1107
14. I. Ugi, A. Dömling, and W. Hörl Multicomponent reactions in organic chemistry Endeavour 18 3 1994 115 122
15. S. König, and I. Ugi Cross-linking of aqueous alginic acid by 4 component condensation with inclusion immobilization of enzymes Z Naturforsch 46 9 1991 1261 1265
16. V. Crescenzi, A. Francescangeli, D. Capitani, L. Mannina, D. Renier, and D. Bellini Hyaluronan networking via Ugi's condensation using lysine as cross-linker diamine Carbohydr Polym 53 3 2003 311 316
17. A.E.J. De Nooy, G. Masci, and V. Crescenzi Versatile synthesis of polysaccharide hydrogels using the Passerine and Ugi multicomponent condensations Macromolecules 32 4 1999 1318 1320
18. A.E.J. De Nooy, D. Capitani, G. Masci, and V. Crescenzi Ionic polysaccharide hydrogels via the Passerini and Ugi multicomponent condensations: synthesis, behavior and solid-state NMR characterization Biomacromolecules 1 2 2000 259 267
19. H. Bu, A.L. Kjøniksen, K.D. Knudsen, and B. Nyström Rheological and structural properties of aqueous alginate during gelation via the Ugi multicomponent condensation reaction Biomacromolecules 5 4 2004 1470 1479
20. J.C. Scanlan, and H.H. Winter Composition dependence of the viscoelasticity of end-linked poly(dimethylsiloxane) at the gel point Macromolecules 24 1 1991 47 54
21. F. Chambon, and H.H. Winter Linear viscoelasticity at the gel point of a cross-linking PDMS with imbalanced stoichiometry J Rheol 31 8 1987 683 697
22. E.E. Holly, S.K. Venkataraman, F. Chambon, and H.H. Winter Fourier-transform mechanical spectroscopy of viscoelastic materials with transient structure J Non-Newtonian Fluid Mech 27 1 1988 17 26
23. K. Te Nijenhuis, and H.H. Winter Mechanical properties at the gel point of a crystallizing poly(vinyl chloride) solution Macromolecules 22 1 1989 411 414
24. D.F. Hodgson, and E.J. Amis Dynamic viscoelasticity during sol-gel reactions J Non-Cryst Solids 131-133 part 2 1991 913 920
25. J.E. Martin, J. Wilcoxon, and J. Odinek Decay of density-fluctuations in gels Phys Rev A 43 2 1991 858 872
26. B. Nyström, H. Walderhaug, and F.K. Hansen Dynamic crossover effects observed in solutions of a hydrophobically associating water-soluble polymer J Phys Chem 97 29 1993 7743 7752
27. K. Mortensen, W. Brown, and E. Jørgensen Phase behavior of poly(propylene oxide)-poly(ethylene oxide)-poly(propylene oxide) triblock copolymer melt and aqueous solutions Macromolecules 27 20 1994 5654 5666
28. Z. Sun, and C.H. Wang Quasielastic light scattering and viscoelastic responses of polymer solutions Macromolecules 27 20 1994 5667 5673
29. B. Nyström, and B. Lindman Dynamic and viscoelastic properties during the thermal gelation process of a nonionic cellulose ether dissolved in water in the presence of ionic surfactants Macromolecules 28 4 1995 967 974
30. J.F. Douglas, and J.B. Hubbard Semiempirical theory of relaxation: concentrated polymer solution dynamics Macromolecules 24 11 1991 3163 3177
31. C.H. Wang, and X.Q. Zhang Quasielastic light scattering and viscoelasticity of polystyrene in diethyl phthalate Macromolecules 26 4 1993 707 714
32. K.L. Ngai Dynamics of semidilute solutions of polymers and associating polymers Adv Colloid Interface Sci 64 1996 1 43
33. P.G. De Gennes Scaling concepts in polymer physics 1979 Cornell University Press Ithaca, NY
34. B. Nyström, K. Thuresson, and B. Lindman Rheological and dynamic light-scattering studies on aqueous solutions of a hydrophobically modified nonionic cellulose ether and its unmodified analogue Langmuir 11 6 1995 1994 2002
35. M. Tsianou, A.L. Kjøniksen, K. Thuresson, and B. Nyström Light scattering and viscoelasticity in aqueous mixtures of oppositely charged and hydrophobically modified polyelectrolytes Macromolecules 32 9 1999 2974 2982
36. K. Thuresson, S. Nilsson, A.L. Kjøniksen, H. Walderhaug, B. Lindman, and B. Nyström Dynamics and rheology in aqueous solutions of associating diblock and triblock copolymers of the same type J Phys Chem B 103 9 1999 1425 1436
37. A.L. Kjøniksen, S. Nilsson, K. Thuresson, B. Lindman, and B. Nyström Effect of surfactant on dynamic and viscoelastic properties of aqueous solutions of hydrophobically modified ethyl(hydroxyethyl)cellulose, with and without spacer Macromolecules 33 3 2000 877 886
38. K.L. Ngai, and R.W. Rendell A coupling model analysis of dynamics of concentrated colloidal suspensions Philos Mag B 77 2 1998 621 631
39. K.L. Ngai, and G.D.J. Phillies Coupling model analysis of polymer dynamics in solution: Probe diffusion and viscosity J Chem Phys 105 18 1996 8385 8397
40. M. Nydén, and O. Söderman An NMR self-diffusion investigation of aggregation phenomena in solutions of ethyl(hydroxyethyl)cellulose Macromolecules 31 15 1998 4990 5002
41. K.A. Streletzky, and G.D.J. Phillies Coupling analysis of probe diffusion in high molecular weight hydroxypropylcellulose J Phys Chem B 103 11 1999 1811 1820
42. R.A. Lauten, A.L. Kjøniksen, and B. Nyström Colloid polymer interactions and aggregation in aqueous mixtures of polystyrene latex, sodium dodecyl sulfate, and a hydrophobically modified polymer: A dynamic light scattering study Langmuir 17 3 2001 924 930
43. A.L. Kjøniksen, M. Hiorth, and B. Nyström Temperature-induced association and gelation of aqueous solutions of pectin. A dynamic light scattering study Eur Polym J 40 11 2004 2427 2435