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In contrast, the phase transition is instantaneous in pure 5CB. Trace impurities, however, can lead to finite speeds as observed in ref 19.
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32
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The images shown in ref 19 were taken in 300-μm-thick capillaries 100 fan above the bottom plane. According to the images the domain size can exceed 250 μm. In that case no three-dimensional bulk structure can evolve, because the cavities may span almost the entire thickness of the capillary.
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According to our experience, in a Perkin-Elmer calorimeter (used in ref 35) it is hard to keep the sample isotropic during loading. The second peak, therefore, may have been caused by a temperature drop during the loading procedure.
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