Studies toward the synthesis of azadirachtin, part 2: Construction of fully functionalized ABCD ring frameworks and unusual intramolecular reactions induced by close-proximity effects

Angewandte Chemie - International Edition

Volumn 44, Issue 22, 2005, Pages 3447-3452

  Nicolaou, K C ^a,b   Sasmal, Pradip K ^a,b   Koftis, Theocharis V ^a,b   Converso, Antonella ^a,b   Loizidou, Eriketi ^c   Kaiser, Florian ^a,b   Roecker, A J ^a,b   Dellios, Constantinos C ^a,b   Sun, Xiao Wen ^a,b   Petrovic, Goran ^a,b  

^a SCRIPPS RESEARCH INSTITUTE   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c SAN DIEGO STATE UNIVERSITY   (United States)

Author keywords

Asymmetric synthesis; Degradation; Natural products; Radical reactions; Total synthesis

Indexed keywords

AROMATIC COMPOUNDS; MOLECULAR STRUCTURE; REACTION KINETICS; SYNTHESIS (CHEMICAL);

ANTIFEEDANT AGENTS; AZADIRACHTIN PRECURSORS; MOLECULAR ARCHITECTURE;

INSECTICIDES;

AZADIRACHTIN; BRIDGED COMPOUND; DECALIN; INSECTICIDE; LIMONOID; NAPHTHALENE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; SYNTHESIS;

BRIDGED COMPOUNDS; INSECTICIDES; LIMONINS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; NAPHTHALENES;

EID: 20444362418     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200500217     Document Type: Article

References (11)

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2. Angew. Chem. Int. Ed. 2005, 44, 3443-3447, preceding Communication in this issue.
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11. Note added in proof: After submission of this manuscript, we isolated the other bromoketal diastereomer in approximately 10% yield from experiments carried out on a larger scale.