The complexation of the Na+ by 18-crown-6 studied via nuclear magnetic resonance

Journal of Chemical Education

Volumn 81, Issue 5, 2004, Pages 715-717

  Peters, Steven J ^a   Stevenson, Cheryl D ^a  

^a ILLINOIS STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BINDING ENERGY; COMPLEXATION; ENCAPSULATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POSITIVE IONS; STUDENTS; TEACHING;

ALKALI METAL CATIONS; BINDING CONSTANTS; EQUILIBRIUM CONSTANT; HOMOGENEOUS CATION; STABILITY CONSTANTS;

SODIUM;

EID: 2042439760     PISSN: 00219584     EISSN: None     Source Type: Journal    
DOI: 10.1021/ed081p715     Document Type: Article

References (9)

1. (a) Gokel, G. Crown Ethers & Cryptands; The Royal Society of Chemistry: Cambridge, United Kingdom, 1991.
2. (b) Pedersen, C.J. J. Am. Chem. Soc. 167, 106, 7017-7036.
3. Lin, J. D.; Popov, A. I. J. Am. Chem. Soc. 1981, 103, 3773-3777.
4. (a) Schmidt, E.; Tremillon, J.; Kintzinger, J.; Popov, A. I. J. Am. Chem. Soc. 1983, 105, 7563-7566.
5. (b) Ishihara, K.; Miura, H.; Funahashi, S.; Tanaka, M. Inorg. Chem. 1988, 27, 1706-1710.
6. Braun S.; Kalinowski, H.O.; Berger, S. 150 and More Basic NMR Experiments; Wiley-VCH: Weinheim, Germany, 1998.
7. (a) Dunford, H. B. J. Chem. Educ. 1984, 61, 129-132.
8. s can also be used, such the Benesi-Hildebrand equation (as explained in ref 4a).
9. Hallwass, F.; Engelsberg, M.; Simas, A. M. J. Phys. Chem. A. 2002, 106, 589-594.