Highly selective reaction of α-halo-αβ-unsaturated esters with ketones or aldehydes promoted by SmI2: An efficient alternative access to Baylis-Hillman adducts

Journal of Organic Chemistry

Volumn 70, Issue 12, 2005, Pages 4714-4719

  Concellón, José M ^a   Huerta, Mónica ^a  

^a UNIVERSITY OF OVIEDO   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONITRILE; ALDEHYDES; AROMATIC COMPOUNDS; KETONES; PHASE TRANSITIONS; REACTION KINETICS; SAMARIUM COMPOUNDS; SYNTHESIS (CHEMICAL); UNSATURATED COMPOUNDS;

ADDUCTS; BAYLIS-HILLMAN ADDUCTS; STEREOSELECTIVITY; UNSATURATED ESTERS;

ESTERS;

2 [(1 HYDROXY 1 METHYL)PROPYL] 3 PHENYLPROPENOATE; 2 [(CYCLOHEXYLHYDROXYPHENYL)METHYL] 3 PHENYLPROPENOATE; ACETONITRILE; ACRYLIC ACID; ALDEHYDE; ESTER DERIVATIVE; ETHYL 2 (1 HYDROXYCYCLOPENTYL) 3 PHENYLPROPENOATE; ETHYL 2 (1 HYDROXYOCTYL) 3 PHENYLPROPENOATE; ETHYL 2 (CYCLOHEXYHYDROXYMETHYL) 3 PHENYLPROPENOATE; ETHYL 2 [(1 HYDROXY 1 METHYL)PROPYL] 3 PHENYLPROPNEOATE; ETHYL 2 [(CYCLOHEXYLHYDROXYPHENYL)METHYL] 3 PHENYLPROPENOATE; ETHYL 2 CHLORO 3 PHENYLPROPENOATE; ETHYL ALPHA CHLOROCINNAMATE; KETONE; METHYL 2 (CYCLOHEXYHYDROXYMETHYL) 3 PHENYLPROPENOATE; METHYL 2 BROMO 3 PHENYLPROPENOATE; PHENYL 2 (1 HYDROXYCYCLOHEXYL)HEPT 2 ENOATE; PHENYL 2 [(1 HYDROXY 1 METHYL)HEPTYL]HEPT 2 ENOATE; PHENYL 2 CYCLOHEXY 2 [(1 HYDROXY 1 METHYL)PROPYL]PROPENOATE; PHENYL 3 CYCLOHEXYL 2 [(1 HYDROXY 1 METHYL 2 PHENYL)ETHYL]PROPENOATE; SAMARIUM DIIODIDE; UNCLASSIFIED DRUG;

ARTICLE; BAYLIS HILLMAN REACTION; CHEMICAL REACTION; REACTION ANALYSIS; STEREOCHEMISTRY; SYNTHESIS;

EID: 20344398198     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo0504969     Document Type: Article

References (33)

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