Studies of an enneanuclear manganese single-molecule magnet

Journal of the American Chemical Society

Volumn 127, Issue 15, 2005, Pages 5572-5580

  Piligkos, Stergios ^b   Rajaraman, Gopalan ^b   Soler, Monica ^c   Kirchner, Nadeschda ^f   Van Slageren, Joris ^f   Bircher, Roland ^e   Parsons, Simon ^a   Güdel, Hans Ulrich ^e   Kortus, Jens ^g,h   Wernsdorfer, Wolfgang ^d   Christou, George ^c   Brechin, Euan K ^a,b  

^a UNIVERSITY OF EDINBURGH   (United Kingdom)

^b UNIVERSITY OF MANCHESTER   (United Kingdom)

^c University of Florida ^*  (United States)

^d LABORATOIRE DE CRISTALLOGRAPHIE   (France)

^e UNIVERSITY OF BERN   (Switzerland)

^f UNIVERSITY OF STUTTGART   (Germany)

^g MAX PLANCK INSTITUT FÜR FESTKÖRPERFORSCHUNG   (Germany)

^h INSTITUT DE PHYSIQUE ET CHIMIE DES MATÉRIAUX DE STRASBOURG   (France)

Author keywords

[No Author keywords available]

Indexed keywords

DATA ACQUISITION; FREQUENCY DOMAIN ANALYSIS; GROUND STATE; MAGNETIC RESONANCE SPECTROSCOPY; MAGNETIC SUSCEPTIBILITY; NEUTRON SCATTERING;

DIRECT CURRENT (DC); ENNEANUCLEAR MANGANESE SINGLE MOLECULE-MAGNET; FREQUENCY DOMAIN MAGNETIC RESONANCE SPECTROSCOPY (FDMRS); INELASTIC NEUTRON SCATTERING (INS);

MANGANESE;

ION; MANGANESE; MANGANESE DERIVATIVE; METAL;

ANISOTROPY; ARTICLE; CHEMICAL REACTION; COMPLEX FORMATION; CRYSTAL; DENSITY FUNCTIONAL THEORY; HYSTERESIS; MAGNETISM; NEUTRON SCATTERING; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; TEMPERATURE; TEMPERATURE DEPENDENCE;

EID: 20244371331     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja042302x     Document Type: Article

References (45)

1. (a) Sessoli, R.; Gatteschi, D.; Hendrickson, D. N.; Christou, G. MRS Bull. 2000, 25, 66-71.
2. (b) Sessoli, R.; Tsai, H.-L.; Schake, A. R.; Wang, S.; Vincent, J. B.; Folting, K.; Gatteschi, D.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1993, 115, 1804-1816.
3. (c) Sessoli, R.; Gatteschi, D.; Caneschi, A.; Novak, M. A. Nature 1993, 365, 141-143.
4. (d) Caneschi, A.; Gatteschi, D.; Sessoli, R.; Barra, A. L.; Brunel, L. C.; Guillot, M. J. Am. Chem. Soc. 1991, 113, 5873-5874.
5. Hendrickson, D. N.; Christou, G.; Ishimoto, H.; Yoo, J.; Brechin, E. K.; Yamaguchi, A.; Rumberger, E. M.; Aubin, S. M. J.; Sun, Z.; Aromi, G. Mol. Cryst. Liq. Cryst. 2002, 376, 301-313.
6. See for example: (a) Tasiopoulos, A. J.; Vinslava, A.; Wernsdorfer, W.; Abboud, K. A.; Christou, G. Angew. Chem., Int. Ed. 2004, 43, 2117-2121. (b) Miyasaka, H.; Clérac, R.; Wemsdorfer, W.; Leeren, L.; Bonhomme, C.; Sugiura, K.; Yamashita, M. Angew. Chem., Int. Ed. 2004, 43, 2801-2805. (c) Murugesu, M.; Wernsdorfer, W.; Raftery, J.; Christou, G.; Brechin, E. K. Inorg. Chem. 2004, 43, 4203-4209. (d) Milios, C. J.; Raptopoulou, C. P.; Terzis, A.; Lloret, F.; Vicente, R.; Perlepes, S. P.; Escuer, A. Angew. Chem., Int. Ed. 2003, 43, 210-212. (e) Wittick. L. M.; Murray, K. S.; Moubaraki, B.; Batten, S. R.; Spiccia, L.; Berry, K. J. Dalton Trans. 2004, 1003-1011.
7. See for example: (a) Tasiopoulos, A. J.; Vinslava, A.; Wernsdorfer, W.; Abboud, K. A.; Christou, G. Angew. Chem., Int. Ed. 2004, 43, 2117-2121. (b) Miyasaka, H.; Clérac, R.; Wemsdorfer, W.; Leeren, L.; Bonhomme, C.; Sugiura, K.; Yamashita, M. Angew. Chem., Int. Ed. 2004, 43, 2801-2805. (c) Murugesu, M.; Wernsdorfer, W.; Raftery, J.; Christou, G.; Brechin, E. K. Inorg. Chem. 2004, 43, 4203-4209. (d) Milios, C. J.; Raptopoulou, C. P.; Terzis, A.; Lloret, F.; Vicente, R.; Perlepes, S. P.; Escuer, A. Angew. Chem., Int. Ed. 2003, 43, 210-212. (e) Wittick. L. M.; Murray, K. S.; Moubaraki, B.; Batten, S. R.; Spiccia, L.; Berry, K. J. Dalton Trans. 2004, 1003-1011.
8. See for example: (a) Tasiopoulos, A. J.; Vinslava, A.; Wernsdorfer, W.; Abboud, K. A.; Christou, G. Angew. Chem., Int. Ed. 2004, 43, 2117-2121. (b) Miyasaka, H.; Clérac, R.; Wemsdorfer, W.; Leeren, L.; Bonhomme, C.; Sugiura, K.; Yamashita, M. Angew. Chem., Int. Ed. 2004, 43, 2801-2805. (c) Murugesu, M.; Wernsdorfer, W.; Raftery, J.; Christou, G.; Brechin, E. K. Inorg. Chem. 2004, 43, 4203-4209. (d) Milios, C. J.; Raptopoulou, C. P.; Terzis, A.; Lloret, F.; Vicente, R.; Perlepes, S. P.; Escuer, A. Angew. Chem., Int. Ed. 2003, 43, 210-212. (e) Wittick. L. M.; Murray, K. S.; Moubaraki, B.; Batten, S. R.; Spiccia, L.; Berry, K. J. Dalton Trans. 2004, 1003-1011.
9. See for example: (a) Tasiopoulos, A. J.; Vinslava, A.; Wernsdorfer, W.; Abboud, K. A.; Christou, G. Angew. Chem., Int. Ed. 2004, 43, 2117-2121. (b) Miyasaka, H.; Clérac, R.; Wemsdorfer, W.; Leeren, L.; Bonhomme, C.; Sugiura, K.; Yamashita, M. Angew. Chem., Int. Ed. 2004, 43, 2801-2805. (c) Murugesu, M.; Wernsdorfer, W.; Raftery, J.; Christou, G.; Brechin, E. K. Inorg. Chem. 2004, 43, 4203-4209. (d) Milios, C. J.; Raptopoulou, C. P.; Terzis, A.; Lloret, F.; Vicente, R.; Perlepes, S. P.; Escuer, A. Angew. Chem., Int. Ed. 2003, 43, 210-212. (e) Wittick. L. M.; Murray, K. S.; Moubaraki, B.; Batten, S. R.; Spiccia, L.; Berry, K. J. Dalton Trans. 2004, 1003-1011.
10. See for example: (a) Tasiopoulos, A. J.; Vinslava, A.; Wernsdorfer, W.; Abboud, K. A.; Christou, G. Angew. Chem., Int. Ed. 2004, 43, 2117-2121. (b) Miyasaka, H.; Clérac, R.; Wemsdorfer, W.; Leeren, L.; Bonhomme, C.; Sugiura, K.; Yamashita, M. Angew. Chem., Int. Ed. 2004, 43, 2801-2805. (c) Murugesu, M.; Wernsdorfer, W.; Raftery, J.; Christou, G.; Brechin, E. K. Inorg. Chem. 2004, 43, 4203-4209. (d) Milios, C. J.; Raptopoulou, C. P.; Terzis, A.; Lloret, F.; Vicente, R.; Perlepes, S. P.; Escuer, A. Angew. Chem., Int. Ed. 2003, 43, 210-212. (e) Wittick. L. M.; Murray, K. S.; Moubaraki, B.; Batten, S. R.; Spiccia, L.; Berry, K. J. Dalton Trans. 2004, 1003-1011.
11. Friedman, J. R.; Sarachik, M. P.; Tejada, J.; Ziolo, R. Phys. Rev. Lett. 1996, 76, 3830-3833.
12. Sanudo, E. C. et al. Polyhedron 2003, 22, 2267-2271.
13. Jones, L. F.; Rajaraman, G.; Brockman, J.; Murugesu, M.; Raftery, J.; Teat, S. J.; Wernsdorfer, W.; Christou, G.; Brechin, E. K.; Collison, D. Chem.-Eur. J. 2004, 10, 5180-5194.
14. (a) Khan, M. I.; Zubieta, J. Prog. Inorg. Chem. 1995, 43, 1-149.
15. (b) Cavaluzzo, M.; Chen, Q.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1993, 131-132.
16. (c) Finn, R. C.; Zubieta, J. J. Cluster Sci. 2000, 11, 461-482.
17. (a) Jones, L. F.; Batsanov, A.; Brechin, E. K.; Collison, D.; Helliwell, M.; Mallah, T.; McInnes, E. J. L.; Piligkos, S. Angew. Chem., Int. Ed. 2002, 41, 4318-4321.
18. (b) Brechin, E. K.; Soler, M.; Christou, G.; Helliwell, M.; Teat, S. J.; Wernsdorfer, W. Chem. Commun. 2003, 1276-1277.
19. (c) Moragues-Cánovas, M.; Rivière, E.; Ricard, L.; Paulsen, C.; Wernsdorfer, W.; Brechin, E. K.; Mallah, T. Adv. Mater. 2004, 13, 1101-1105.
20. (d) Shaw, R, et al. Chem. Commun. 2004, 1418-1419.
21. Rajaraman, G.; Murugesu, M.; Soler, M.; Wernsdorfer, W.; Helliwell, M.; Teat, S. J.; Christou, G.; Brechin, E. K. J. Am. Chem. Soc. 2004, 126, 15445-15457.
22. Sheldrick, G. M. SHELXTL, version 5; Bruker AXS: Madison, Wisconsin, 1995.
23. (a) van der Sluis, P.; Spek, A. L. Acta Crystallogr., Sect. A 1990, 46, 194-201.
24. (b) Spek, A. L. PLATON, A Multipurpose Crystallographic Tool; Utrecht University: Utrecht, The Netherlands, 1998.
25. (c) Incorporated into the WinGX suite: Farrugia, L. J. J. Appl. Crystallogr. 1999, 32, 837-838.
26. Wernsdorfer, W. Adv. Chem. Phys. 2001, 118, 99-190.
27. van Slageren, J. et al. Phys. Chem. Chem. Phys. 2003, 5, 3837-3843.
28. Kozlov, G. V.; Volkov, A. A. In Millimeter and Submillimeter Wave Spectroscopy of Solids; Grüner, G., Ed.; Springer: Berlin, 1998.
29. (a) Pederson, M. R.; Jackson, K. A. Phys. Rev. B 1990, 41, 7453-7461.
30. (b) Jackson, K. A.; Pederson, M. R. Phys. Rev. B 1990, 42, 3276-3281.
31. (c) Porezag, D. V.; Pederson, M. R. Phys. Rev. A 1999, 60, 2840-2847.
32. (d) Pederson, M. R.; Porezag, D. V.; Kortus, J.; Patton, D. C. Phys. Status Solidi B 2000, 217, 197-218.
33. Perdew, J. P.; Burke, K.; Ernzerhof, M. Phys. Rev. Lett. 1996, 77, 3865-3868.
34. van Vleck, J. Phys. Rev. 1937, 52, 1178-1198.
35. (a) Pederson, M. R.; Khanna, S. N. Phys. Rev. B 1999, 59, 693-696R.
36. (b) Pederson, M. R.; Khanna, S. N. Phys. Rev. B 1999, 60, 9566-9572.
37. Kortus, J.; Pederson, M. R.; Baruah, T.; Bernstein, N.; Hellberg, C. S. Polyhedron 2003, 22, 1871-1876.
38. MAGNET, Davidson, E. R.; Indiana University.
39. Basler, R.; Boskovic, C.; Chaboussant, G.; Güdel, H.-U.; Murrie, M.; Ochsenbein, S. T.; Sieber, A. ChemPhysChem 2003, 4, 910-926.
40. Böni, P.; Furrer, A.; Schefer, J. Principles of Neutron Scattering, Proceedings of the Eigth Summer School on Neutron Scattering, World Scientific Co. Pte. Ltd., 2000.
41. Caciuffo, R.; Amoretti, G.; Murani, A.; Sessoli, R.; Caneschi, A.; Gatteschi, D. Phys. Rev. Lett. 1998, 81, 4744-4747.
42. Yoo, J.; Yamaguchi, A.; Nakano, M.; Krzystek, J.; Streib, W. E.; Brunel, L.-C.; Ishimoto, H.; Christou, G.; Hendrickson, D. N. Inorg. Chem. 2001, 40, 4604-4616.
43. Dressel, M.; Grüner, G. Electrodynamics of Solids; Cambridge University Press: Cambridge, U.K., 2002.
44. Cirera, J.; Kortus, J.; Ruiz, E. To be published.
45. Pederson, M. R.; Bernstein, N.; Kortus, J. Phys. Rev. Lett. 2002, 89, 097202-1/4.