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note
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31P exchange - between the differently protonated forms is fast, resulting in time averaged signals of a given species. The pH dependence of the chemical shift (Fig. 3) could therefore be used to evaluate the protonation constants.
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22
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note
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2 values. We considered the line width of 10 Hz measured at low temperatures as the non-exchange value, and this is in accordance with our kinetic calculations.
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