Synthesis and characterization of silicone modified acrylic resin and its uses in the emulsion paints

Iranian Polymer Journal (English Edition)

Volumn 14, Issue 3, 2005, Pages 211-222

  Naghash, Hamid Javaherian ^a   Mallakpour, Shadpour ^b   Kayhan, Neda ^a  

^a ISLAMIC AZAD UNIVERSITY   (Iran)

^b ISFAHAN UNIVERSITY OF TECHNOLOGY   (Iran)

Author keywords

Butylacrylate; Emulsion copolymerization; Methacrylic acid; Methylmethacrylate; Vinyltriethoxysilane

Indexed keywords

COPOLYMERS; DIFFERENTIAL SCANNING CALORIMETRY; EMULSIONS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; ORGANIC ACIDS; POLYMERIZATION; POLYMETHYL METHACRYLATES; RESINS; SCANNING ELECTRON MICROSCOPY; SILICONES; SYNTHESIS (CHEMICAL); THERMOGRAVIMETRIC ANALYSIS;

ACRYLIC RESIN; BUTYLACRYLATE (BA); EMULSION PAINTS; METHACRYLIC ACID (MAA); POLYMERIZATION RATES;

PAINT;

EID: 19944425509     PISSN: 10261265     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (44)

1. Kondo H., Koshii T., Silicone water-based emulsion composition, U.S. Patent 4,782,112 (1998).
2. Liles D.T., Murray D.I., Weyenberg D.R., Tselepis A.J., Revis A. Silicone/organic copolymer emulsion from preformed organic emulsions, U.S. Patent 5,482,994 (1996).
3. Yamaya M., kizaki H., Furuya M., Yamamoto A., Silicone resin-containing emulsion composition, method for making same, and article having a cured film of same, U.S. Patent 5,973,068 (1999).
4. Okibe J., Inoue M., Haruna M., Yasuda A., Sundag T., Iwabuchi Y., Sato N., Coating resin composition containing hydrolyzable organosilane, acrylic resin and polyorganosiloxane, U.S. Patent 6,329,456 (2001).
5. Oochi, I., Miki D., Tanaka S., Sawai T., Resin composition, processes for their production and their uses, U.S. Patent 6,287,701 (2001).
6. Campbell J.D., Debling J.A., Deyoung D.J., Giannakitsas I., Hellwig D.R., Schatz D.D., Teymour F., Villalobos M.A., Process for producing polymers by free radical polymerization and condensation reactions and apparatus and products related thereto, U.S. Patent 6, 346, 590, (2002).
7. Matsui F., Uotani N., Murakami M., Itoh Y., Polyorganosiloxane and process for producing the same, U.S. Patent 5,491,203 (1996).
8. Lee I., Acrylic emulsion coatings for formed articles, U.S. Patent 5,700,585 (1997).
9. Lee I., Acrylic emulsion coatings, U.S. Patent 5,712,346 (1998).
10. Czech A., Koczo K., Hydrophilic siloxane latex emulsion, U.S. Patent 6,207,782 (2001).
11. Gornowicz G.A., kennan L.D., Saxena A.k., Tselepis A.J., Homopolymerization of acrylate or methacrylate end blocked polydiorganosiloxanes, U.S. Patent 5,840,813 (1998).
12. Graiver D., Tanaka O., Methods for making polydiorganosiloxane microemulsions, U.S. Patent 5,817,714 (1998).
13. Yang H.W., Pacansky T.J., Inverse emulsion process for preparing hydrophobe-containing polymers., U.S. Patent 4,918,123 (1990).
14. Liles D.T., Murray D.L., Functional polyorganosiloxane emulsions from monohydrolyzable silanes and photocurable compositions therefrom, U.S. Patent 5,480,919 (1996).
15. Share P.E., Pippin W.H., Aqueous compositions containing polymerizable surfactant compounds, U.S. Patent 5,563,214 (1996).
16. Yamauchi T. Kamiyama Y., Aqueous, silicone-modified acrylate polymer emulsion, U.S. Patent 5,852,095 (1998).
17. Walker J.L., Foreman P.B., Removable pressure sensitive adhesive, U.S. Patent 4,716,194 (1987).
18. Pons D.A., Van Hout J.B., Sep W.J., Composition based on an aqueous dispersion of an addition polymer, U.S. Patent 5,100,955 (1992).
19. Werner J.R., Ervin R., Konsza E.E., Waterbased acrylic silane and polyurethane containing coating composition, U.S. Patent 5,204,404 (1993).
20. Asanaka Y., Takeuchi H., Ohiwa M., Nakatsuka T., Yamoto S., Reactive particulate resin, method for producing the same, and resin composition for thermoforming, U.S. Patent 5,459,179 (1995).
21. Tahara S., Hashimoto T., Kanayama T., Process for producing water-base resin dispersion, U.S.Patent 5,489,645 (1996).
22. Asanaka Y., Takeuchi H., Ohiwa M., Nakatsuka T., Yamoto S., Reactive particulate resin and method for its production, U.S. Patent 5,494,974 (1996).
23. Yang M., Liu H., Zhang H., Chen D., Wang J., Wang C., Silicone acrylic emulsion coatings., Tuliao Gongye, 30, 12-15 (2000).
24. Maeda O., Kobayashi H., Kageishi K., Acrylic silicone emulsion compositions for coatings with good resistance to water and weather, Japan Patent, 26,691 (2000).
25. Liu D., Nie Z., Xu W., Sun L., Chen G., Acrylic polysiloxane coatings for building materials and their manufacture., Faming zhuanli shenqing Gongkai shuomingshu CN, China Patent 97,105,779 (1997).
26. Wang Y., Zhang B., Zhu K., Study on process of acrylate-silicone emulsion copolymerization., Tuliao Gongye, 30, 1-2 (2000).
27. Qiao Y., Yu J., Song D., Wang D., Hou Z., Synthesis of silicone modified acrylic emulsion and its film structure., Tuliao Gongye, 31, 3-6 (2001).
28. You B., Chen X., Li D., Feng Q., Wu L., Study on emulsion polymerization of silanes/acrylate., Zhanjie, 21, 21-23 (2000).
29. Chen Z., Synthesis and properties of silicone modified styrene-acrylic emulsion,. Tuliao Gongye, 29, 15-16 (1999).
30. Yamaya M., Furuya M., Kizaki H., Yamamoto A., Silicone resin-containing emulsion composition, making method, and article having cured film of the composition, U.S. Patent 6,147,156 (2000).
31. Shaffie A., Moustafa, A.B., Mohamed E.S., Badran A.S., The course of emulsion polymerization of vinyl acetate using redox systems of different oxidizing agents, J. Polym. Sci. Part A: Polym. Chem., 35, 3141-3149 (1997).
32. Naveen Kumar P., Paresh Sanghvi G.S., Shah D.O., Surekha D., Kinetics and behaviour of copolymerization in emulsion and microemulsion systems, Langmuir, 16, 5864-5870 (2000).
33. Badran A.S., Moustafa A.B., Yehia A.A. Shendy S.M.M., Emulsion polymerization of vinyl acetate initiated by potassium persulfate cyclohexanone sodium bisulfite redoxe pair system, J. Polym. Sci. Part A: Polym. Chem., 28, 411-424 (1990).
34. Lambourne R., Paint and Surface Coatings Theory and Practice, Edited by Ellis Horwood Market Cross House, Chichester, West Sussex, England Ch. 9, pp. 359-363 (1987).
35. Swaraj P. Surface Coatings Science and Technology, John Wiley, Ch. 8, pp. 559-594 (1986).
36. Konno M., Shimizu K., Arai K., Saito S., J. Polym. Sci. Part A, Polym. Chem., 25, 223-230 (1987).
37. Peng H., Huang G.F., Lu W., li X.B., Huang S.Q., Kinetics and nucleation mechanism of organosilicon composite emulsion polymerization., Gongneng Gaofenzi xuebao, 13, 173-176 (2000).
38. Song Z., Poehlein G.W., Kinetics of emulsifier free emulsion polymerization of styrene, J. Polym. Sci. Part A, Polym. Chem. 28, 2359-2392 (1990).
39. Arai K., Arai M., Iwasaki S., Saito S., J. Polym. Sci, Polym. Chem., 20, 1203- (1982).
40. Harkins W.D., General theory of mechanism of emulsion polymerization., J. Am. Chem. Soc., 69, 1428-1444 (1947).
41. Smith W.V., Ewart R.H., Kinetics of emulsion polymerization, J. Chem. Phys., 16, 592-599 (1948).
42. Kumar K., Rana K.S., Mechanical properties and aging behaviour of styrene-butadiene-vinyltriethoxysilane coupled carbon black vulcanizates., Iran. Polym. J., 11, 287-293 (2002).
43. Sun Z., Ding W., Liu J., Li J., High weather-resistant silicone-modified acrylic resin and its coating., Shanghai Tuliao, 4, 201-204 (1998).
44. Kan C.Y., Zhu X.L., Yuan Q., Kong X.Z., Graft emulsion copolymerization of acrylates and siloxane., Polym. Adv. Technol., 8, 631-633 (1997).