Stannylated allylsulfones as versatile new building blocks

Synlett

Volumn , Issue 8, 2005, Pages 1271-1274

  Kazmaier, Uli ^a   Wesquet, Alexander ^a  

^a SAARLAND UNIVERSITY   (Germany)

Author keywords

Hydrostannation; Julia Lythgoe olefination; Stille coupling; Sulfones

Indexed keywords

COBALT DERIVATIVE; MOLYBDENUM; SULFONE; TIN; UNCLASSIFIED DRUG; VINYL DERIVATIVE; VINYL STANNATE;

ARTICLE; CHEMICAL MODIFICATION; CHEMICAL REACTION; HYDROSTANNATION; OLEFINATION; STEREOCHEMISTRY; STILLE REACTION;

EID: 19944372391     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2005-868478     Document Type: Article

References (25)

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13. (b) Kazmaier, U.; Schauß, D.; Pohlman, M.; Raddatz, S. Synthesis 2000, 914.
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19. Angew. Chem. 2003, 115, 318.
20. 10,Sn = 9.9 Hz, C-10), 66.3 (t, C-5), 128.5 (2 d, C-2), 128.8 (2 d, C-3), 133.4 (d, C-4), 135.9 (s, C-1), 138.6 (t, C-7), 141.4 (s, C-6).
21. 3): δ = 42.2 (t, C-8), 61.6 (t, C-5), 121.5 (t, C-7), 126.6 (d, C-12), 128.5, 128.6, 129.0, 129.2 (4 × 2 d, C-2, C-3, C-10, C-11), 133.7 (d, C-4), 136.8 (d, C-9), 137.9 (d, C-6), 138.4 (s, C-1).
22. 3S (378.49): C, 72.99; H, 5.86. Found: C, 72.89; H, 5.96.
23. 3): δ = 41.4 (t, C-8), 122.1 (t, C-7), 126.5 (d, C-11), 128.4, 128.7, 128.8, 129.0, 129.8, 130.0 (6 × 2 d, C-2, C-3, C-10, C-11, C-15, C-16), 130.3 (d, C-17), 133.0 (s, C-14), 133.3 (d, C-4), 136.8 (d, C-13), 137.0 (s, C-9), 138.6 (s, C-1), 140.8 (s, C-5), 141.9 (c, C-6).
24. Bernard, A. M.; Frongia, A.; Piras, P. P.; Secci, F. Synlett 2004, 1064.
25. 3): δ = 38.7 (t, C-9), 118,7 (t, C-7), 126.1 (d, C-13), 126.4 (2 d, C-2), 127.5 (d, C-4), 128.4, 128.6, 128.8 (3 × 2 d, C-3, C-11, C-12), 129.1 (d, C-5), 130.6 (d, C-6), 137.2 (s, C-10), 139.4 (s, C-1), 145.0 (s, C-7).