Regioselective iodination of activated arenes using phenyl trimethylammonium dichloroiodate in ionic liquid under microwave irradiation

Synthetic Communications

Volumn 35, Issue 10, 2005, Pages 1313-1318

  Tilve, Rutuja D ^a   Kanetkar, Vinod R ^a  

^a UNIVERSITY OF MUMBAI   (India)

Author keywords

Ionic liquid; Microwave; Phenyltrimethylammonium dichloroiodate; Regio selective iodination

Indexed keywords

ACETONITRILE; AMMONIUM DERIVATIVE; IONIC LIQUID; PHENYLTRIMETHYLAMMONIUM DICHLOROIODATE; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; TOLUENE; TRIMETHYLAMMONIUM SALT DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHROMATOGRAPHY; HEATING; INFRARED SPECTROSCOPY; IODINATION; LIQUID; MICROWAVE IRRADIATION; PROTON NUCLEAR MAGNETIC RESONANCE;

EID: 19544387803     PISSN: 00397911     EISSN: None     Source Type: Journal    
DOI: 10.1081/SCC-200057244     Document Type: Article

References (11)

1. (a) Galli, C. Aromatic iodination; Evidence of reaction intermediate and of the -σcomplex of the transition state. J. Org. Chem. 1991, 56, 3238;
2. (b) Alexander, M. V.; Khandekar, A. C.; Samant, S. D. Synlett 2003, 12, 1895, and references cited therein.
3. 3 based ionic liquid. J. Mol. Cat. (A) 2004, 223, 237;
4. 3 based ionic liquids, J. Mol. Cat. (A) 2004, 223, 75;
5. (c) Paul, A. M.; Khandekar, A. C.; Khadilkar, B. M. Baeyer condensation in chloroaluminate ionic liquid. J. Chem. Res, Synop. 2003, 3, 168;
6. (d) Rebeiro, G. L.; Khadilkar, B. M. Chloroaluminate ionic liquid for Fischer indole synthesis, Org. Pro. Res. Dev. 2002, 6, 826;
7. (e) Khandekar, A. C.; Khadilkar, B. M. Pechmann condensation in chloroaluminate ionic liquids. Synlett 2002, 1, 152;
8. (f) Rebeiro, G. L.; Khadilkar, B. M. Microwave assisted synthesis of room temperature ionic liquid precursors in closed vessel. Synthesis 2001, 3, 370.
9. Tilve, R. D.; Alexander, M. V.; Khadilkar, B. M. Iodination of activated arenes using silfen: An improved protocol. Tetrahedron Lett. 2000, 43, 9457.
10. Krassowska-Swiebocka, B.; Lulinski, P.; Skulski, L. Aromatic iodination of activated arenes and heterocycles with lead tetracetate as oxidant. Synthesis 1995, 926.
11. Orito, K.; Hatakeyama, T.; Takeo, M.; Suginome, H. Iodination of alkyl aryl ethers by mercury (II) oxide-iodine reagent in dichloromethane. Synthesis 1995, 1273.