Liquid-Phase Hydrogenation of Cinnamaldehyde over a Ru-Sn Sol-Gel Catalyst. 2. Kinetic Modeling

Industrial and Engineering Chemistry Research

Volumn 43, Issue 9, 2004, Pages 2039-2048

  Hájek, Jan ^a   Wärnå, Johan ^a   Murzin, Dmitry Yu ^a  

^a LABORATORY OF INDUSTRIAL CHEMISTRY AND REACTION ENGINEERING   (Finland)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CATALYST DEACTIVATION; CATALYSTS; HYDROGENATION; MATHEMATICAL MODELS; PRESSURE EFFECTS; SOL-GELS; THERMAL EFFECTS;

KINETIC MODELING; LIQUID-PHASE HYDROGENATION; STIRRED BATCH REACTOR;

ALDEHYDES;

CINNAMALDEHYDE; CINNAMYL ALCOHOL; RUTHENIUM COMPLEX; SILICON DIOXIDE; SOLVENT; TIN DERIVATIVE;

HYDROGENATION;

ARTICLE; BATCH REACTOR; CATALYSIS; CATALYST; EXPERIMENT; GEL; HYDROGENATION; KINETICS; LIQUID; MODEL; PERFORMANCE; PRESSURE; REACTION ANALYSIS; STIRRED REACTOR; TEMPERATURE DEPENDENCE;

EID: 1942516994     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie034081u     Document Type: Article

References (30)

1. Rase, H. F. Handbook of Commercial Catalysts: Heterogeneous Catalysts; CRC Press: Boca Raton, FL, 2000.
2. Nishimura, S. Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis; Wiley-Interscience: New York, 2001.
3. Streitwieser, A.; Heathcock, C. H.; Kosower, E. M. Introduction to Organic Chemistry; Macmillan Publishing: New York, 1992.
4. Egee, S. N. Organic Chemistry, Structure and Reactivity; D. C. Heath: Lexington, MA, 1994.
5. Szollosi, Gy.; Mastalir, A.; Molnar, A.; Bartok, M. Hydrogenation of α,β-unsaturated ketones on metal catalysts. React. Kinet. Catal. Lett. 1996, 57, 29.
6. Claus, P. Selective hydrogenation of α,β-unsaturated aldehydes and other C=O and C=C bonds containing compounds. Top. Catal. 1998, 5, 51.
7. Cordier, G. α,β-Ethylenic alcohols. Ger. Offen. 1977, 37 pp.
8. Rylander, P. N.; Steele, D. R. Hydrogenation of α,β -unsaturated aldehydes to unsaturated alcohols over osmium catalysts. Tetrahedron Lett. 1969, 20, 1579.
9. Gallezot, P.; Richard, D. Selective hydrogenation of α,β -unsaturated aldehydes. Catal. Rev.-Sci. Eng. 1998, 40, 81.
10. Sokol'skii, D. V.; Anisimova, N. V.; Zharmagambetova, A. K.; Mukhamedzhanova, S. G.; Edygenova, L. N. Platinum-ferric oxide catalytic system for hydrogenation reactions. React. Kinet. Catal. Lett. 1987, 33, 399.
11. Schroeder, U.; De Verdier, L. Influence of oxygen and iron in the liquid-phase hydrogenation of α,β-unsaturated aldehydes. J. Catal. 1993, 142, 490.
12. Coq, B.; Kumbhar, P. S.; Moreau, C.; Moreau, P.; Figueras, F. Zirconia-supported monometallic Ru and bimetallic Ru-Sn, Ru-Fe catalysts: Role of metal support interaction in the hydrogenation of cinnamaldehyde. J. Phys. Chem. 1994, 98, 10180.
13. 3 catalysts. J. Mol. Catal. A 1996, 108, 41.
14. Brinker, C. J. Sol-Gel Science: The Physics & Chemistry of Sol-Gel Processing; Academic Press: San Diego, 1990.
15. Klein, L. C.; Sakka, S.; Pope, E. J.; Woolfrey, J. L. Sol-Gel Processing of Advanced Materials; American Ceramic Society: Westerville, OH, 1998.
16. Turner, C. W. Sol-gel process-principles and applications. Am. Ceram. Soc. Bull. 1991, 70, 1487.
17. Ishii, K.; Mizukami, F.; Niwa, S.-I.; Kutsuzawa, R.; Toba, M.; Fujii, Y. A new catalyst preparation by a combination of complexing agent-assisted sol-gel and impregnation methods. Catal. Lett. 1998, 52, 49.
18. 2. J. Solid State Chem. 2001, 158, 154.
19. Zou, W.; Gonzalez, R. D. Thermal stability of silica supported palladium catalysts prepared by the sol-gel method. Appl. Catal. A 1995, 126, 351.
20. Ward, D. A.; Ko, E. I. Preparing catalytic materials by the sol-gel method. Ind. Eng. Chem. Res. 1995, 34, 421.
21. Lopez, T.; Herrera, L.; Gomez, R.; Zou, W.; Robinson, K.; Gonzalez, R. D. Improved mechanical stability of supported ruthenium catalysts: preparation by the sol-gel method. J. Catal. 1992, 136, 621.
22. Tronconi, E.; Crisafulli, C.; Galvagno, S.; Donato, A.; Neri, G.; Pietropaolo, R. Kinetics of liquid-phase hydrogenation of cinnamaldehyde over a platinum-tin/nylon catalyst. Ind. Eng. Chem. Res. 1990, 29, 1766.
23. Neri, G.; Bonaccorsi, L.; Mercadante, L.; Galvagno, S. Kinetic analysis of cinnamaldehyde hydrogenation over alumina-supported ruthenium catalysts. Ind. Eng. Chem. Res. 1997, 36, 3554.
24. Belohlav, Z.; Zamostny, P. A rate-controlling step in Langmuir-Hinshelwood kinetic models. Can. J. Chem. Eng. 2000, 78, 513.
25. Vergunst, T.; Kapteijn, F.; Moulijn, J. A. Kinetics of cinnamaldehyde hydrogenation-concentration dependent selectivity. Catal. Today 2001, 66, 381.
26. Hindmarsh, A. C. ODEPACK-A Systematized Collection of ODE-Solvers. In Scientific Computing; Steppleman, R., et al., Eds.; IMACS/North Holland Publishing Company: Amsterdam, The Netherlands, 1983; pp 55-64.
27. Haario, H. MODEST User's Manual; Profmath Oy: Helsinki, Finland, 2001.
28. Temkin, M. I.; Murzin, D. Yu.; Kul'kova, N. V. Mechanism of liquid-phase hydrogenation of a benzene ring. Kinet. Katal. 1989, 30, 637.
29. Murzin, D. Yu.; Kul'kova, N. V. Non-equilibrium effects in the liquid-phase catalytic hydrogenation. Catal. Today 1995, 24, 35.
30. Ponec, V. On the role of promoters in hydrogenations on metals; α,β-unsaturated aldehydes and ketones. Appl. Catal. A 1997, 149, 27.