Evidence of Underestimation in PAH Sorption/Desorption Due to System Nonequilibrium and Interaction with Soil Constituents

Journal of Environmental Science and Health - Part A Toxic/Hazardous Substances and Environmental Engineering

Volumn 39, Issue 5, 2004, Pages 1147-1162

  Hwang, Sangchul ^a   Cutright, Teresa J ^a  

^a University of Akron   (United States)

Author keywords

Clay minerals; Equilibrium; Isotherms; Kinetics; Phenanthrene; Pyrene; SOM

Indexed keywords

CLAY MINERALS; DESORPTION; HEALTH; POLYCYCLIC AROMATIC HYDROCARBONS; SOILS; TOXIC MATERIALS;

DESORPTIVE FACTOR; PHENANTHRENE'S (PHES); PYRENE (PYR); SOIL ORGANIC MATTER (SOM);

ENVIRONMENTAL ENGINEERING;

DISSOLVED ORGANIC MATTER; PHENANTHRENE DERIVATIVE; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; PYRENE; SOIL ORGANIC MATTER; SORBENT;

ARTICLE; CHEMICAL INTERACTION; CLAY; CONCENTRATION (PARAMETERS); DESORPTION; SOIL CHEMISTRY; SOIL POLLUTION; THERMODYNAMICS;

ADSORPTION; FORECASTING; MODELS, THEORETICAL; POLYCYCLIC HYDROCARBONS, AROMATIC; REPRODUCIBILITY OF RESULTS; SOIL POLLUTANTS;

EID: 1942516485     PISSN: 10934529     EISSN: None     Source Type: Journal    
DOI: 10.1081/ESE-120030300     Document Type: Article

References (23)

1. Luthy, R.G.; Aiken, G.R.; Brusseau, M.L.; Cunningham, S.D.; Gschwend, P.M.; Pignatello, J.J.; Reinhard, M.; Traina, S.J.; Weber, W.J., Jr.; Westall, J.C. Sequestration of hydrophobic organic contaminants by geosorbents. Environ. Sci. Technol. 1997, 31, 3341-3347.
2. Wilcke, W. Polycyclic aromatic hydrocarbons (PAHs) in soil - a review. J. Plant Nut. Soil Sci. 2000, 163, 229-248.
3. Ghosh, D.R.; Keinath, T.M. Effect of clay minerals present in aquifer soils on the adsorption and desorption of hydrophobic organic compounds. Environ. Progr. 1994, 13, 51-59.
4. Weber, W.J., Jr.; Huang, W.; LeBoeuf, E.J. Geosorbent organic matter and its relationship to the binding and sequestration of organic contaminants. Colloids Surfaces A: Physicochem. Eng. Aspects 1999, 151, 167-179.
5. Pignatello, J.J.; Xing, B. Critical review: mechanisms of slow sorption of organic chemicals to natural particles. Environ. Sci. Technol. 1996, 30, 1-11.
6. Huang, W.; Weber, W.J., Jr. A distributed reactivity model for sorption by soils and sediments. 10. Relationships between desorption, hysteresis, and the chemical characteristics of organic domains. Environ. Sci. Technol. 1997, 31, 2562-2569.
7. Cornelissen, G.; Rigterink, H.; Ferdinandy, M.M.; van Noort, P.C.M. Rapidly desorbing fractions of PAHs in contaminated sediments as a predictor of the extent of bioremediation. Environ. Sci. Technol. 1998, 32, 966-970.
8. Kunz, G.W.; Dixon, J.B. Pretreatment for mineralogical analysis. Methods of Soil Analysis. Part 1. Physical and Mineralogical Methods; American Society of Agronomy: Madison, WI, 1982; 91-100.
9. 2 organic matter-removal method on δD of smectite-rich samples. Geochim. Cosmochim. Acta 2000, 64, 3829-3827.
10. Jackson, M.L. Soil Chemical Analysis; Jackson Publishing: Madison, WI, 1985; 23-36.
11. Wattel-Koekkoek, E.J.W.; van Genuchten, P.P.L.; Buurman, P.; van Lagen, B. Amount and composition of clay associated soil organic matter in a range of kaolinitic and smectitic soils. Geoderma 2001, 99, 27-49.
12. Karickhoff, S.W.; Brown, D.S.; Scott, T.A. Sorption of hydrophobic pollutanta on natural sediments. Water Res. 1979, 13, 241-248.
13. Hassett, J.J.; Banwart, W.L.; Wood, S.G.; Means, J.C. Sorption of α-naphthol. Implications concerning the limits of hydrophobic sorption. Soil Sci. Soc. Am. J. 1981, 45, 38-42.
14. Brusseau, M.L.; Jessup, R.E.; Rao, S.C. Non-equilibrium sorption of organic chemicals: elucidation of rate-limiting processes. Environ. Sci. Technol. 1991, 25, 134-142.
15. Froment, G.F.; Bischoff, K.B. Chemical Reactor Analysis and Design, 2nd Ed.; John Wiley: New York, 1990; 62 pp.
16. Chefetz, B.; Deshmukh, A.P.; Hatcher, P.G.; Guthrie, E.A. Pyrene sorption by natural organic matter. Environ. Sci. Technol. 2000, 34, 2925-2930.
17. Brady, N.C.; Weil, R.R. Elements of the Nature and Properties of Soils; Prentice-Hall Inc.: New Jersey, 2000; 20-26.
18. Jota, M.A.; Hasset, J.P. Effects of environmental variables on binding of a PCB congener by dissolved humic substances. Environ. Toxicol. Chem. 1991, 10, 483-491.
19. McCarthy, J.F.; Zachara, J.M. Subsurface transport of contaminants. Environ. Sci. Technol. 1989, 23, 496-504.
20. oc values. Environ. Sci. Technol. 1987, 21, 243-248.
21. Mackay, A.A.; Gschwend, P.M. Enhanced concentrations of PAHs in groundwater at a coal tar site. Environ. Sci. Technol. 2001, 35, 1320-1328.
22. Johnson, W.P.; Amy, G.L. Facilitated transport and enhanced desorption of polycyclic aromatic hydrocarbons by natural organic matter in aquifer sediments. Environ. Sci. Technol. 1995, 29, 807-817.
23. Kogel-Knabner, I.; Raber, B.; Totsche, K.U. Desorption of polycyclic aromatic hydrocarbon from soil in the presence of dissolved organic matter: effect of solution composition and aging. J. Environ. Qual. 2000, 29, 906-916.