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Volumn 69, Issue 2, 2004, Pages 227161-2271611

Classical sudden model for vibrational and rotational excitations in ion-molecule collisions

Author keywords

[No Author keywords available]

Indexed keywords

ENERGY DISSIPATION; FUNCTIONS; HAMILTONIANS; MATHEMATICAL MODELS; POSITIVE IONS; POTENTIAL ENERGY; PROBLEM SOLVING; QUANTUM THEORY; ROTATION; SCATTERING; SPECTRUM ANALYSIS; TRAJECTORIES;

EID: 1942507882     PISSN: 10502947     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article
Times cited : (6)

References (46)
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    • note
    • →) = 0]. This leads to Eq. (6).
  • 40
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    • note
    • E is convex. Even then, multiple impulses are still possible because the potential U(R) affects intramolecular motion after the first impulse, which may happen to lead to a configuration where the hard potential (5) works again. However, this is improbable if the incident atom A is much lighter than the constituent atoms B and C of the molecule.
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    • note
    • In fact, Eq. (23) is shown to be equivalent to a function "B" introduced in Ref. [11], with which Beck [7,11] derived the hard shell model by considering the force normal to the surface.
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    • 2-1/4.
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    • note
    • In usual terminology, "rotational rainbow" only refers to a divergence at the maximum of q, but not at q = 0. The latter divergence is absorbed in the Jacobian dj/dεα1/√ε, between the energy-loss ε and the angular momentum j in the hard shell model, so that the j distribution dσ/(dj dΩ) is finite at j = 0.
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