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Volumn 111, Issue 1, 1989, Pages 321-335

Formation of Monolayer Films by the Spontaneous Assembly of Organic Thiols from Solution onto Gold

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EID: 1942481178     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00183a049     Document Type: Article
Times cited : (3719)

References (98)
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    • It may be argued that this technique yields the true Young contact angle on an ideal surface. On an ideal surface, however, any technique should yield the same contact angle, and on a nonideal surface the maximum advancing contact angle may be very much greater than the Young angle-a drop of water on a feather providing an extreme example see also Spelt, J. K.; Absolom, D. R.; Neumann, A. W. Langmuir 1986, 2, 620–5
    • It may be argued that this technique yields the true Young contact angle on an ideal surface. On an ideal surface, however, any technique should yield the same contact angle, and on a nonideal surface the maximum advancing contact angle may be very much greater than the Young angle-a drop of water on a feather providing an extreme example (see also: Cain, J. B.; Francis, D. W.; Venter, R. D.; Neumann, A. W. J. Colloid Interface Sci. 1983, 94, 123-30; Spelt, J. K.; Absolom, D. R.; Neumann, A. W. Langmuir 1986, 2, 620–5).
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    • The contact angles were not time-dependent, nor was the contact angle of hexadecane affected by prior washing with water. Any reconstruction must be fast and reversible. See also Holmes-Farley, S. R.; Reamey, R. H.; Nuzzo, R. G.; McCarthy, T. J.; Whitesides, G. M. Langmuir 1987, 3, 799–815.
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    • Adsorption of thiols from solution does not appear to require the presence of an oxidizing agent and surface hydrides are not stable on gold above 200 K (Lisowski, E.; Stobinski, L.; Dus, R. Surf. Sci. 1987, 188, L735-741 and references therein). Thus, molecular hydrogen appears to be the most probable final product
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