Deactivation of a commercial catalyst in the epoxidation of ethylene to ethylene oxide - Basis for accelerated testing

Journal of Catalysis

Volumn 224, Issue 1, 2004, Pages 187-196

  Boskovic, G ^a,b   Wolf, D ^a   Bruckner A ^a   Baerns, M ^a  

^a LEIBNIZ INSTITUT FÜR KATALYSE E V AN DER UNIVERSITÄT ROSTOCK   (Germany)

^b UNIVERSITY OF NOVI SAD   (Serbia)

Author keywords

Accelerated deactivation test; Ag based catalyst; Catalyst deactivation; Deactivation compensation; Deactivation mechanism; Ethylene epoxidation; Sintering

Indexed keywords

CARBON DIOXIDE; ETHYLENE; ETHYLENE OXIDE; OXYGEN; SILVER DERIVATIVE;

ARTICLE; CATALYST; CHEMICAL ANALYSIS; CORRELATION ANALYSIS; EPOXIDATION; HIGH TEMPERATURE; OXYGEN CONCENTRATION; REACTION ANALYSIS; REACTOR; TEMPERATURE DEPENDENCE;

EID: 1942436229     PISSN: 00219517     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jcat.2004.02.030     Document Type: Article

References (44)

1. Zomerdijk J.C., Hall M.W. Catal. Rev.-Sci. Eng. 23:1981;163-185.
2. G. Boxhoorn (Shell) EP 207550A1, 1987
3. G. Boxhoorn (Shell) EP 255975, 1988
4. L.A. Kapicak, A.W. Nauman, T.M. Noterman, E.M. Thorsteinsen, Union Carbide, Inc., US 4994588, 1989
5. N. Rizkalla, Scient. Design, Inc., US 5374748, 1994
6. Montrasi G.L., Tauszik G.R., Solari M., Leofanti G. Appl. Catal. 5:1983;359-369.
7. Schouten E.P.S., Borman P.C., Westerterp K.R. Chem. Eng. Process. 35:1996;43-55.
8. McBee E.T., Hass H.B., Wiseman P.A. Ind. Eng. Chem. 37:(3):1945;432-438.
9. Tan S.A., Grant R.B., Lambert R.M. J. Catal. 100:1986;383-391.
10. Yeung K.L., Gavriilidis A., Varma A., Bhasin M.M. J. Catal. 174:1998;1-12.
11. Gleaves J.T., Sault A.G., Madix R.J., Ebner J.R. J. Catal. 121:1990;202-218.
12. Wachs I.E., Kelemen S.R. J. Catal. 71:1981;78-87.
13. Grife B., Blues E., Smith D.B. Appl. Catal. 10:1984;303-312.
14. Tan S.A., Grant R.B., Lambert R.M. Appl. Catal. 31:1987;159-177.
15. Park D.W., Gau G. J. Catal. 105:1987;81-94.
16. Murakami Y., Komai S., Hattori T. Stud. Surf. Sci. Catal. 68:1991;645-652.
17. Presland A.E.B., Price G.L., Trimm D.L. J. Catal. 26:1972;313-317.
18. Verykios X.E., Stein F.P., Coughlin R.W. J. Catal. 66:1980;368-382.
19. Hoflund G.B., Minahan D.M. J. Catal. 162:1996;48-53.
20. Delmon B. Appl. Catal. 15:1985;1-17.
21. Pernicone N. Appl. Catal. 15:1985;17-31.
22. Sie S.T., O'Connor P., Takatsuka T., Woolery G.L. ACS Symp. Ser. 634:1996;6-41.
23. Birtill J.J. Stud. Surf. Sci. Catal. 126:1999;43-62.
24. Haber J., Block J.H., Delmon B. Pure Appl. Chem. 67:(8/9):1995;1257-1306.
25. Boskovic G., Baerns M. Baerns M. Basic Principles of Applied Catalysis. 2003;Springer, Berlin.
26. Christoph R., Baerns M. Stud. Surf. Sci. Catal. 34:1987;355-363.
27. Bartholomew C.H. Appl. Catal. A. 212:2001;17-60.
28. Grant R.B., Lambert R.M. J. Catal. 92:1985;364-375.
29. van Santen R.A., de Groot C.P.M. J. Catal. 98:1986;530-539.
30. Henriques C., Portela M.F., Mazzocchia C. Stud. Surf. Sci. Catal. 86:1994;499-506.
31. Nagy A.J., Mestl G., Herein D., Weinberg G., Kitzelman E., Schlögl R. J. Catal. 182:1999;417-429.
32. Brückner A., Kondratenko E., Berndt H., Müller D., Baerns M. Book of Abstracts. 2001;Proc. North Am. Catal. Society, Toronto.
33. Petrov L., Elyas A., Shopov D. Appl. Catal. 24:1986;145-161.
34. Bournoville J.P., Martino G. Stud. Surf. Sci. Catal. 6:1980;159-171.
35. Levenspiel O. J. Catal. 25:1972;265-272.
36. Butt J.B., Petersen E.E. Activation, Deactivation, and Poisoning of Catalysts. 1988;Academic Press, New York.
37. Berty J.M. Leach B.E. Applied Industrial Catalysis. 1983;58-78 Academic Press, New York.
38. Tajbl D.G., Simons J.B., Carberry J.J. I&EC Fundam. 5:(2):1966;171-175.
39. Ullmann's Encyclopedia of Industrial Chemistry. vol. 10A:1987;117 VCH, Weinheim.
40. Moulijn J.A., van Diepen A.E., Kapteijn F. Appl. Catal. A. 212:2001;3-16.
41. Hoflund G.B., Weaver J.F., Salaita G.N., Minahan D.M. Delmon B., Froment G.F. Catalyst Deactivation 1999. 1999;397-403 Elsevier, Amsterdam.
42. Wu J.C., Harriot P. J. Catal. 39:1975;395-402.
43. Lemaitre J.L., Menon P.G., Delannay F. Delannay F. Characterization of Heterogeneous Catalysts. 1984;299-365 Deckker, New York.
44. Goncharova S.N., Paukshits E.P., Balzhinimaev B.S. Appl. Catal. A. 126:1995;67-84.