Detoxification of hexachlorobenzene by dechlorination with potassium-sodium alloy

Chemosphere

Volumn 55, Issue 11, 2004, Pages 1439-1446

  Miyoshi, Kumiko ^a   Nishio, Takehiko ^a   Yasuhara, Akio ^b   Morita, Masatoshi ^b   Shibamoto, Takayuki ^c  

^a UNIVERSITY OF TSUKUBA   (Japan)

^b NATIONAL INSTITUTE FOR ENVIRONMENTAL STUDIES   (Japan)

^c UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Dechlorination; Hexachlorobenzene; K Na alloy; PCBs

Indexed keywords

CONCENTRATION (PROCESS); DECHLORINATION; DETOXIFICATION; HYDROGEN; POTASSIUM ALLOYS; REACTION KINETICS; SOLUTIONS;

CYCLOHEXANES; HEXACHLOROBENZENE (HCB); HIGH PROTON DONATING POWER; WURTZ-FITTIG REACTIONS;

BENZENE;

2,3',4',5 TETRACHLOROBIPHENYL; ALLOY; BENZENE DERIVATIVE; CHLORINE; CYCLOHEXANE; DIMER; HEXACHLOROBENZENE; HYDROGEN; POTASSIUM; PROTON; SODIUM; TETRAHYDROFURAN; TRICHLOROBENZENE;

DECHLORINATION; DETOXIFICATION; HEXACHLOROBENZENE;

ARTICLE; ATOM; CHEMICAL REACTION; CHLORINATION; CONCENTRATION (PARAMETERS); DETOXIFICATION; TEMPERATURE;

EID: 1942425950     PISSN: 00456535     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemosphere.2004.01.025     Document Type: Article

References (30)

1. Abramovitch R.A., Zhou H.B., Davis M., Peters L. Decomposition of PCBs and other polychlorinated aromatics in soil using microwave energy. Chemosphere. 37:1998;1427-1436.
2. Ahling B., Bjorseth A., Lunde G. Formation of chlorinated hydrocarbons during combustion of poly(vinyl chloride). Chemosphere. 7:1978;799-806.
3. Augustijn-Beckers P.W.M., Hornsby A.G., Wauchope R.D. SCS/ARS.CES pesticide properties database for environmental decision making II. Additional compounds. Rev. Environ. Contam. Toxicol. 137:1994;1-82.
4. Bailey R.E. Global hexachlorobenzene emissions. Chemosphere. 43:2001;167-182.
5. Bonnet J., El Mejdoub N., Trouve G., Delfosse L. J. Anal. Appl. Pyrolysis. 44:1997;1-11.
6. Calaminus B., Trouve G., Delfosse L. Experimental study of the quantitative conversion of hexachlorobenzene during high temperature pyrolysis. J. Anal. Appl. Pyrolysis. 27:1993;281-292.
7. Chang B.V., Su C.J., Yuan S. Microbial hexachlorobenzene dechlorination under three reducing conditions. Chemosphere. 36:1998;2721-2730.
8. Edwards I.R., Ferry D.G., Temple W.A. Fungicides and related compounds. Hayes W.J. Jr., Laws E.R. Jr. Handbook of Pesticide Toxicology. 1991;6-8 Academic Press, New York.
9. El Mejdoub N., Souizi A., Delfosse L. Experimental and numerical study of the thermal destruction of hexachlorobenzene. J. Anal. Appl. Pyrolysis. 47:1998;77-94.
10. Fatepure B.Z., Vogel T.M. Complete degradation of polychlorinated hydrocarbons by a two-stage biofilm reactor. Appl. Environ. Microbiol. 57:1991;3418-3422.
11. Foster W.G., McMahon A., Villeneuve D.C. Hexachlorobenzene (HCB) suppresses circulating progesterone concentration during the luteal phase in the cynomolgus monkey. J. Appl. Toxicol. 12:1992;13-17.
12. Franklin T.C., Darlington J., Solouki T., Tran N. The use of the oxidation of barium peroxide in aqueous surfactant systems in the electrolytic destruction of organic compounds. J. Electrochem. Soc. 138:1991;2285-2288.
13. Kalu E.E., White R.E. In situ degradation of polyhalogenated aromatic hydrocarbons by electrochemically generated superoxide ions. J. Electrochem. Soc. 138:1991;3656-3660.
14. Kinner L.L., Manahan S.E., Larsen D.W. Mechanistic study of the ChemChar process using hexachlorobenzene as a surrogate for monitoring reaction products. Chemosphere. 24:1992;1867-1884.
15. Kinner L.L., McGowin A.E., Manahan S.E., Larsen D.W. ChemChar process for destruction of sorbed hexachlorobenzene with char sorbent regeneration. Toxicol. Environ. Chem. 37:1992;1-10.
16. Kirk P.W.W., Rogers H.R., Lester J.N. The fate of chlorobenzenes and permethrins during anaerobic sewage sludge digestion. Chemosphere. 18:1989;1771-1784.
17. Kloster G., Reisinger K.J. Laboratory scale pyrolysis experiments using halogenated benzenes. Anal. Appl. Pyrolysis. 17:1990;357-369.
18. Klusmeier W., Vogler P., Ohrbach K.-H., Weber H., Kettrup A. Thermal decomposition of pentachlorobenzene, hexachlorobenzene and octachlorostyrene in air. J. Anal. Appl. Pyrolysis. 14:1988;25-36.
19. Lee J.J., Yao C.P., Wang Y.Y., Wan C.C. Electrochemical decomposition of chlorinated benzenes in dimethylformamide solvent. Environ. Sci. Technol. 26:1992;553-556.
20. Mackenzie K., Kopinke F.D., Remmler M. Reductive destruction of halogenated hydrocarbons in liquids and solids with solvated electrons. Chemosphere. 33:1996;1495-1513.
21. Miyoshi K., Nishio T., Yasuhara A., Morita M. Dechlorination of hexachlorobiphenyl by using potassium-sodium alloy. Chemosphere. 41:2000;819-824.
22. Newhook R., Dormer W. Environmental Health Criteria 195: Hexachlorobenzene. 1997;WHO.
23. Nowakowska M., Szczubialka K. Photosensitized dechlorination of polychlorinated benzenes. 1. Carbazole-photosensitized dechlorination of hexachlorobenzene. Chemosphere. 39:1999;71-80.
24. Stach J., Pekarek V., Endrst R., Hetflejs J. Dechlorination of hexachlorobenzene on MWI fly ash. Chemosphere. 39:1999;2391-2399.
25. Sugimoto H., Matsumoto S., Sawyer D.T. Oxygenation of polychloro aromatic hydrocarbons by a superoxide ion in aprotic media. J. Am. Chem. Soc. 109:1987;8081-8082.
26. Sugimoto H., Matsumoto S., Sawyer D.T. Degradation and dehalogenation of polychlorobiphenyls and halogenated aromatic molecules by superoxide ion and by electrolytic reduction. Environ. Sci. Technol. 22:1988;1182-1186.
27. Von Manikowsky S., Sagunski H., Papke O., Fabig K.-R., Neus H., Schumann M., Spannhake K., Karmaus W., Osius N., Zier B. PCDD/PCDF indoor exposure in day-care centers and PCDD/PCDF blood concentrations of female employees. Environ. Health Persp. Suppl. 106:1998;707-714.
28. 3 catalysis. Appl. Catal. B: Environ. 20:1999;249-256.
29. Yasuhara A., Morita M. Formation of chlorinated compounds in pyrolysis of trichloroethylene. Chemosphere. 21:1990;479-486.
30. Yuan S.Y., Su C.J., Chang V. Microbial dechlorination of hexachlorobenzene in anaerobic sewage sludge. Chemosphere. 38:1999;1015-1023.