Simple large-scale preparation of 3,3-disubstituted cyclopropenes: Easy access to stereodefined cyclopropylmetals via transition metal-catalyzed hydrometalation

Synthesis

Volumn , Issue 5, 2004, Pages 796-800

  Rubin, Michael ^a   Gevorgyan, Vladimir ^a  

^a UNIVERSITY OF ILLINOIS AT CHICAGO   (United States)

Author keywords

Cyclopropane; Cyclopropene; Hydroboration; Hydrostannation; Transition metal catalysis

Indexed keywords

HALOGENATION; MOLECULAR ORIENTATION; ORGANIC COMPOUNDS; STEREOCHEMISTRY; SUBSTITUTION REACTIONS; TRANSITION METAL ALLOYS;

DEHYDROHALOGENATION; HYDROBORATION; HYDROMETALATION; HYDROSTANNATION;

SYNTHESIS (CHEMICAL);

ACETIC ACID; CARBENOID; METAL DERIVATIVE; PALLADIUM; PROPANE; PROPYLENE; TRANSITION ELEMENT; TRIMETHYLSILYL DERIVATIVE;

ADDITION REACTION; ARTICLE; CATALYSIS; DESILYLATION; DIASTEREOISOMER; ENANTIOSELECTIVITY; HALOGENATION; HYDROBORATION; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 1942424945     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2003-44368     Document Type: Article

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