Synthesis of Poly(styrene-co-divinylbenzene)-stainless Steel Beads through a Factorial Design of Experiments

Industrial and Engineering Chemistry Research

Volumn 43, Issue 9, 2004, Pages 2093-2103

  Martin, Cristina ^a   Cuellar, Jorge ^a  

^a UNIVERSITY OF SALAMANCA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

AGGLOMERATION; AMMONIUM COMPOUNDS; BENZENE; ORGANIC POLYMERS; POLYMERIZATION; POLYSTYRENES;

FRACTIONAL FACTORIAL DESIGN; MICROBEADS; POLYMERIC LAYER; PREPOLYMERIZATION;

STAINLESS STEEL;

POLY(STYRENE CO DIVINYLBENZENE); POLYMER; POLYSTYRENE DERIVATIVE; UNCLASSIFIED DRUG;

COPOLYMER; STAINLESS STEEL; SYNTHESIS;

ARTICLE; BIOENGINEERING; EMPIRICISM; FACTORIAL ANALYSIS; HYDROGENATION; MATERIALS TESTING; POLYMERIZATION; QUANTUM YIELD; REACTION ANALYSIS; SURFACE PROPERTY; SYNTHESIS;

EID: 1942420837     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie030448j     Document Type: Article

References (39)

1. Rajamani, K.; Shenoy, S. C.; Rao, M. S.; Mao, M. G. Kinetics of the Hydrolysis of Ethyl-Acetate Catalyzed by Cation-Exchange Resin. J. Appl. Chem. Biotechnol. 1978, 28, 699.
2. Metwally, M. S.; El-Hadi, M. F.; El-Wardany, M. A.; Razik, A. A. Synthesis of a New Sulfonated Cation-Exchange Resin and its Application in Catalyzed Hydrolysis of Esters. J. Mater. Sci. 1990, 25, 4223.
3. Schwachula, G.; Hauptmann, R.; Kain, I. Investigation of Formation of Strongly Acid Cation-Exchange Resins Based on Slightly Cross-linked Copolymers. J. Polym. Sci. Polym. Symp. 1974, 47, 103.
4. Byun, H. S.; Burford, R. P.; Fane, A. G. Sulfonation of Cross-Linked Asymmetric Membranes Based on Polystyrene and Divinylbenzene. J. Appl. Polym. Sci. 1994, 52, 825.
5. Seubert, A.; Klingenberg, A. Sulfoacylated Macroporous Polystyrene-Divinylbenzene: A New Type of Cation Exchanger for the Analysis of Multivalent Metal Cations. J. Chromatogr. A 1997, 782, 149.
6. Rhodes, C. N.; Brown, D. R.; Plant, S.; Dale, J. A. Sulphonated Polystyrene Resins: Acidities and Catalytic Activities. React. Funct. Polym. 1999, 40, 187.
7. Jerábek, K.; Prokop, Z.; Revillon, A. Adsorption-Assisted Catalysts. React. Funct. Polym. 1997, 33, 103.
8. Szymonifka, M. J.; Chapman, K. T. Magnetically Manipulatable Polymeric Supports for Solid-Phase Organic-Synthesis. Tetrahedron Lett. 1995, 36, 1597.
9. Rana, S.; White, P.; Bradley, M. Synthesis of Magnetic Beads for Solid-Phase Synthesis and Reaction Scavenging. Tetrahedron Lett. 1999, 40, 8137.
10. Roice, M.; Kumar, K. S.; Pillai, V. N. R. Synthesis, Characterization, and Application of Butanediol Dimethacrylate Cross-Linked Polystyrene: A Flexible Support for Gel Phase Peptide Synthesis. Macrololecules 1999, 32, 8807.
11. Joubert, J. C. Magnetic Microcomposites as Vectors for Bioactive Agents: The State of Art. An. Quim. Int. Ed. 1997, 93, S70.
12. Ujam, L. B.; Clemmitt, R. H.; Chase, H. A. Cell Separation by Expanded Bed Adsorption: Use of Ion Exchange Chromatography for the Separation of E-Coli and S-Cerevisiae. Bioprocess Eng. 2000, 23, 245.
13. Mao, Q. M.; Hearn, M. T. W. Optimization of Affinity and Ion-Exchange Chromatographic Processes for the Purification of Proteins. Biotechnol. Bioeng. 1996, 52, 204.
14. Bautista, L. F.; Martinez, M.; Aracil, J. Adsorption Equilibrium of α-Amylase in Aqueous Solutions. AIChE J. 1999, 45, 761.
15. Martinez, M.; Carrancio, A.; Casillas, J. L.; Aracil, J. Evaluation of Kinetic and Thermodynamic Parameters of Amino-Acids on Modified Divinylbenzene-Polystyrene Resins Using a Liquid-Chromatography Technique. Ind. Eng. Chem. Res. 1995, 34, 4486.
16. Saunders: M. S.; Vierow, J. B.; Carta, G. Uptake of Phenylalanine and Tyrosine by a Strong-Acid Exchanger. AIChE J. 1989, 35, 53.
17. Habbaba, M. M.; Ulgen, K. O. Analysis of Protein Adsorption to Ion Exchangers in a Finite Bath. J. Chem. Technol. Biotechnol. 1997, 69, 405.
18. Burns, M. A.; Graves, D. S. Continuous Affinity Chromatography Using a Magnetically Stabilized Fluidized Bed. Biotechnol. Prog. 1985, 1, 95.
19. Burns, M. A.; Graves, D. J. Application of Magnetically Stabilized Fluidized-Beds to Bioseparations. React. Polym. 1987, 6, 45.
20. Webb, C.; Kang, H. K.; Moffat, G.; Williams, R. A.; Estevez, A. M.; Cuellar, J.; Jaraiz, E.; Galan, M. A. The Magnetically Stabilized Fluidized Bed Bioreactor: a Tool for Improved Mass Transfer in Immobilized Enzyme Systems? Chem. Eng. J. Biochem. Eng. 1996, 61, 241.
21. Halling, P. J.; Dunnill, P. Magnetic Supports for Immobilized Enzymes and Bioaffinity Adsorbents. Enzyme Microb. Technol. 1980, 2, 2.
22. Benner, S. A. Magnetic Particles as Supports for Organic Synthesis. U.S. Patent 4,638,032, 1987.
23. Ugelstad, J.; Ellingsen, T.; Berge, A.; Helgee, O. B. Process for Preparing Magnetic Polymer Particles. U.S. Patent 4,774,265, 1988.
24. Iman, M.; Celebi, S. S.; Özdural, A. R. Preparation of Photooxidized Magnetic Polystyrene Beads for Enzyme Immobilization. React. Polym. 1992, 17, 325.
25. Li, X.; Sun, Z. Synthesis of Magnetic Polymer Microspheres and Application for Immobilization of Proteinase of Bacillus Subtilis. J. Appl. Polym. Sci. 1995, 58, 1991.
26. Sucholeiki, I. Process for Synthesis of Organic Compounds Using Magnetic Particles. U.S. Patent 5,684,130, 1997.
27. Sucholeiki, I.; Margetts, G.; Roberts, M. Composite magnetic beads. U.S. Patent 5,834,121, 1998.
28. Ramos, J.; Millan, A.; Palacio, F. Production of Magnetic Nanoparticles in a Polyvinylpyridine Matrix. Polymer 2000, 41, 8461.
29. Ramirez, L. P.; Landfester, K. Magnetic Polystyrene Nanoparticles with a High Magnetite Content Obtained by Miniemulsion Processes. Macromol. Chem. Phys. 2003, 204, 22.
30. Cuellar, J.; Jaraiz, E. Determination of the magnetic susceptibility of solids used in the design of a magnetic valve for solids. Chem. Eng. J. 1986, 32, 121.
31. Zborowski, M.; Fuh, C. B.; Green, R.; Sun, L. P.; Chalmers, J. J. Analytical Magnetapheresis of Ferritin-Labeled Lymphocytes. Anal. Chem. 1995, 67, 3702.
32. Yuan, H. G.; Kalfas, G.; Ray, W. H. Suspension polymerization. JMS-Rev. Macromol. Chem. Phys. 1991, C31, 215.
33. Martin, C. Ph.D. Dissertation, University of Salamanca, Salamanca, Spain, 2003.
34. Martin, C.; Cuellar, J. Synthesis of a Novel Magnetic Resin and the Study of Equilibrium in Cation Exchange with Amino Acids. Ind. Eng. Chem. Res. 2004, 43, 475.
35. Box, G. E. P.; Hunter, W. G.; Hunter, J. S. Statistics for Experimenters. An Introduction to Design, Data Analysis, and Model Building; Wiley: New York, 1978.
36. Montgomery, D. C. Design and Analysis of Experiments; Wiley: New York, 2001.
37. Hamielec, A. E.; Tobita, H. Polymerization Process. Ullman's Encyclopedia of Industrial Chemistry; Wiley-VCH: Weinheim, Germany, 2002.
38. Martin, C.; Ramirez, L.; Cuellar, J. Stainless steel microcoated with sulfonated polystyrene-co-divinylbenzene. Surf Coat. Technol. 2003, 165, 58.
39. Odian, G. Principles of Polymerization; Wiley-Interscience: New York, 1991; p 215.