Synthesis and characterization of poly (methyl methacrylate-styrene) copolymeric beads for bone cements

Latin American Applied Research

Volumn 35, Issue 3, 2005, Pages 175-182

  Morejon L ^a   Mendizabal E ^b   Delgado, J A ^a   Davidenko, N ^a   Lopez Dellamary F ^b   Manriquez R ^b   Ginebra, M P ^c   Gil, F J ^c   Planell, J A ^c  

^a UNIVERSITY OF HAVANA   (Cuba)

^b UNIVERSITY OF GUADALAJARA   (Mexico)

^c UNIVERSITAT POLITÈCNICA DE CATALUNYA   (Spain)

Author keywords

Bone cements; Mechanical properties; Poly(methyl metha crylate); Suspension polymerization

Indexed keywords

ABRASION; BARIUM COMPOUNDS; BONE CEMENT; CHARACTERIZATION; HYDROXYAPATITE; MIXTURES; MOLECULAR WEIGHT; POLYMERIZATION; POLYMETHYL METHACRYLATES; POLYSTYRENES; STANDARDS; SYNTHESIS (CHEMICAL);

BARIUM SULFATE; BENZOYL PEROXIDE (BPO); COPOLYMERIC BEADS; SUSPENSION POLYMERIZATION;

COPOLYMERS;

EID: 18944374022     PISSN: 03270793     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (33)

1. Aerdts, A.M., J.W. De Haan and A.L. German, "Proton and Carbon NMR of Alternating and Statistical Sturene-Methyl Methacrylate Copolymers Revisited," Macromolecules, 26, 1965-1971 (1993).
2. ASTM D 638-1991. Standard Method for Tensile Properties of Plastic (1991).
3. ASTM D5045-99 Standard Test Methods for Plane-Strain Fracture Toughness and Strain Energy Release Rate of Plastics Materials (1999).
4. Bishop, R.B., Practical Polymerization for Styrene, Cahners Books, Massachusetts (1971).
5. Brauer, G.M., D.R. Steinberger and J.W. Stansbury, "Dependence of curing time, peak temperature, and mechanical properties on the composition of bone cement," J. Biomed. Mater. Res., 20, 839-852 (1986).
6. Charnley, J., Acrylic cement in Orthopaedic Surgery. Edinburgh-London: E. and S. Livingstone. Williams and Wilkins Editors, Baltimore (1970).
7. Charnley, J., "Anchorange of femoral head prosthesis to shaft of the femur," J. Bone. Joint Surg., 42B, 28-30(1964a).
8. Charnley, J., "Bonding of Prostheses to bone by cement," J. Bone. Joint Surg., 46B, 518-528 (1964b).
9. Encyclopedia of Polymer Science and Engineering: Second Edition, Vol 1, John Wiley & Son, New York, 256 (1985).
10. Freitag, T.A. and S.L. Cannon, "Fracture characteristics of acrylic bone cements. I. Fracture toughness," J Biomed Mater Res, 10(5), 805-828 (1976).
11. Hansen, D and J. Steen, "Additional mechanical tests of bone cements," Acta Orthop Belg,; 58(3), 268-271, (1992).
12. th Ed., John Wiley & Sons, New York, (1996).
13. ISO 5833-2002. International Standard, Implants for Surgery-Acrylic resin cements (2002).
14. Kühn, K. Bone cements: Up- to date comparison of physical and chemicals properties of commercial materials, Springer-verlag Berlin Heidelberg, (2000).
15. Lautenschlager, E.P., S.I. Stupp and J.C. Keller, "Structure and Properties of Acrylic Bone Cement", in Functional Behaviour of Orthopaedic Biomaterials," Eds. P. Ducheyne y G.W Hastings, CRC Press Boca Raton, Florida, 87-117 (1987).
16. Lee, A.J.C., R.S.M Ling and J.D. Wrightson, "Some properties of poly(methyl methacrylate) with reference to its use in orthopaedic surgery," Clin. Orthop., 95, 281-287 (1973).
17. Lee, A.J.C. and R.S.M. Ling, "Further studies of monomer loss by evaporation during the preparation of acrylic cement for use in orthopaedic surgery," Clin. Orthop. Relat. Res., 106, 122-125 (1975).
18. Maxwell, I.A., A.M. Aerdts and A.L German, "Free Radical Copolymerization: An NMR Investigation of Current Kinetic Models," Macromolecules, 26, 1956-1964 (1993).
19. Meyer, P.R., E.P. Lautenschlager and B.K. Moore, "On the Setting Properties of Acrylic Bone Cement," J. of Bone and Joint Surgery, 55-A (1), 149-156 (1973).
20. Morejón, L. "Obtaining and Characterization of new versions of Surgical Cements," Thesis of University Degree, University of Havana, Havana, Cuba (1992).
21. th Edition, John Wiley & Sons, Inc, New York (1991).
22. Pascual, B., B. Vázquez, M. Gurruchaga, M. Goñi, M.P. Ginebra, F.J. Gil, J.A. Planell, B. Levenfeld, and J. San Roman, "New aspects of the effect of size and size distribution on the setting parameters and mechanical properties of acrylic bone cements," Biomaterials 17(5), 509-516 (1996).
23. Pilliar, R.M., R. Blackwell, I. Macnab and H.U. Cameron, "Carbon-fiber reinforced bone cement in orthopaedic surgery," J. Biomed. Mater. Res., 10, 893-906 (1976).
24. Planell, J.A., M.M. Vila, F.J. Gil and F.C.M. Driessens, "Acrylic Bone Cements," Wise DL, Trantolo DJ, Altobelli DE, Taszewski MJ, Grosser JD, Schwantz ER, editors. Encyclopedic Handbook of Biomaterials and Bioengineering, Part B: Applications, Publisher Marcel Dekker Inc., New York, 879-921 (1995).
25. Pourdeyhimi, B. and H.D. Wagner, "Elastic and ultimate properties of acrylic bone cement reinforced with ultra high molecular weight polyethylene fibres," J. Biomed. Mater. Res., 23, 63-80 (1989).
26. Saha, S. and S. Pal, "Mechanical properties of bone cement: A review.", J. Biomed. Mater. Res., 18, 435-462 (1984).
27. Sih, G.C. and A.T. Berman, "Fracture toughness concept applied to methyl methacrylate," J Biomed Mater Res, 14(3), 311-324 (1980).
28. Starck, C.F. "Fracture and fatigue characteristics of acrylic bone cement," J. Biomed. Mater. Res.; 13, 339-342 (1979).
29. Stupp, S.I. and H.L. Yau, "Matrix Polymerization and Stereoregularity of Poly(methacrylates)", University of Illinois Polymer Symposium, Urbana, IL (1981).
30. Topoleski, L.D.T., P. Ducheyne and J.M. Cuckler, "Microstructural pathway of fracture in poly(methyl methacrylate) bone cement," Biomaterials, 14 (15), 1165-1172 (1993).
31. Vila, M.M., Ph.D. Thesis, Optimización de la Fijación de Prótesis-Hueso en implantes articulares cementados, Universitat Politècnica de Catalunya, Spain (1992).
32. Vila, M.M., A. Raya and J.A. Planell, "Mechanical behaviour of a rubber modified bone cement," Advances in Biomaterials, 9, 155-160 (1990).
33. Zaldívar, D., M.E. Cohen, C. Peniche, P. Ortiz and G. Müller, "Influence of molecular weight on the embedding capacity of poly(methyl methacrylate) and poly(methyl methacrylate- styrene) copolymer," Revista CENIC Ciencias Químicas 22 (2-3), 5-7 (1991).