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Volumn 56, Issue 28, 2000, Pages 4967-4975

Benzannulation and cyclopentannulation reactions of electron-poor amino- stabilized alkenyl fischer carbene complexes

Author keywords

Carbenes and carbenoids; Cyclopentadienes; Dotz reactions; Phenols

Indexed keywords

ALKENYL GROUP; CARBENE; METAL COMPLEX;

EID: 18844474204     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(00)00210-6     Document Type: Conference Paper
Times cited : (20)

References (60)
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    • (a) The reaction of alkenyl(methoxy)carbene complexes with terminal, electron-poor alkynes furnishes benzannulation products in <22%
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    • (b) Internal, electron-poor alkynes and alkenyl(methoxy)carbene complexes have been reported to give variable mixtures of phenol and lactone products: Refs. 9e,19
    • (b) Internal, electron-poor alkynes and alkenyl(methoxy)carbene complexes have been reported to give variable mixtures of phenol and lactone products: Refs. 9e,19.
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    • 13C-H correlations (HMQC y HMBC experiments)
    • 13C-H correlations (HMQC y HMBC experiments).


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