Oxaphosphetane versus betaine formation in epoxide ring opening by PPh 3: A mechanistic probe by ab initio and DFT modeling

Tetrahedron Letters

Volumn 46, Issue 23, 2005, Pages 4087-4090

  Kalaiselvan, Anbarasan ^a   Venuvanalingam, Ponnambalam ^a  

^a BHARATHIDASAN UNIVERSITY   (India)

Author keywords

Ab initio and DFT modeling; Betaine; Deoxygenation; Oxaphosphetane

Indexed keywords

2,3 DIMETHYLEPOXIDE; ALKANE DERIVATIVE; EPOXIDE; OXAPHOSPHETANE; UNCLASSIFIED DRUG;

AB INITIO CALCULATION; ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CRYSTAL STRUCTURE; DENSITY FUNCTIONAL THEORY; DEOXYGENATION; RING OPENING; ROTATION; STEREOCHEMISTRY; WITTIG REACTION;

EID: 18844411636     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2005.04.024     Document Type: Article

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