Strong enhancement of second-harmonic generation (SHG) response through multi-chiral centers and metal-coordination

Dalton Transactions

Volumn , Issue 9, 2005, Pages 1570-1573

  Ye, Qiong ^a   Tang, Yu Zhi ^a   Wang, Xi Sen ^a   Xiong, Ren Gen ^a  

^a NANJING UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CADMIUM COMPOUNDS; COORDINATION REACTIONS; HYDROGENATION; MOLECULAR STRUCTURE; POLYMERS; SYNTHESIS (CHEMICAL); THERMAL EFFECTS; X RAY CRYSTALLOGRAPHY;

LIGANDS; METAL-COORDINATION; METAL-ORGANIC COORDINATION POLYMER (MOCP); MULTI-CHIRAL CENTERS;

SECOND HARMONIC GENERATION;

EID: 18844404433     PISSN: 14779226     EISSN: None     Source Type: Journal    
DOI: 10.1039/b503039k     Document Type: Article

References (52)

1. (a) J. Zyss, Molecular Nonlinear Optics: Materials, Physics, and Devices, Academic Press New York, 1993;
2. (b) F. Agullo-Lopez, J. M. Cabrera, F. Agullo-Rueda, Electrooptics: Phenomena, Materials and Applications, Academic Press, New York, 1994;
3. (c) R. E. Newnham, Structure-Property Relations, Springer, New York, 1975;
4. (d) G. R. Desiraju, Crystal Engineering: The Design of Organic Solids, Elsevier, New York, 1989;
5. (e) J.-M. Lehn, Supramolecular Chemistry: Concepts and Perspectives, VCH Publishers, New York, 1995;
6. (f) T. J. Marks and M. A. Ratner, Angew. Chem., Int. Ed. Engl., 1995, 34, 155;
7. (g) C. Janiak, Dalton Trans., 2003, 2781;
8. (h) S. L. James, Chem. Soc. Rev., 2003, 32, 276;
9. (i) B. Kesanli and W. Lin, Coord. Chem. Rev., 2003, 246, 305;
10. (j) Q- Ye, X.-S. Wang, H. Zhao and R.-G. Xiong, Chem. Soc. Rev., 2005, 34, 208.
11. (a) X.-R. Zeng, R.-G. Xiong, X.-Z. You and K.-K Cheung, Inorg. Chem. Commun., 2000, 3, 341;
12. (b) P. A. Maggard, C. L. Stern and K. R. Poeppelmeier, J. Am. Chem. Soc., 2001, 123, 7742;
13. (c) P. S. Halasyamani and K. R. Poeppelmeier, Chem. Mater., 1998, 10, 2753;
14. (d) H. Zhang, X. Wang, K. Zhang and B. K. Teo, Coord. Chem. Rev., 1999, 183, 157 and references therein;
15. (e) O. R. Evans and W. Lin, Acc. Chem. Res., 2002, 35, 515 and references therein;
16. (f) W. Lin;, O. R. Evans, R.-G. Xiong and Z. Y. Wang, J. Am. Chem. Soc., 1998, 120, 13272;
17. (g) K. T. Holman, A. M. Pivovar, J. A. Swift and M. D. Ward, Acc. Chem. Res., 2001, 34, 107 and references therein;
18. (h) C. Janiak, T. G. Scharmann, P. Albrecht, F. Marlow and R. Macdonald, J. Am. Chem. Soc., 1996, 118, 6307.
19. (a) K. T. Holman, A. M. Pivovar and M. D. Ward, Science, 2001, 294, 1907;
20. (b) H. Zhao, Y.-H. Li, X.-.S. Wang, Z.-R. Qu, L.-Z. Wang, R.-G. Xiong, B. F. Abrahams and Z. L. Xue, Chem. Eur. J., 2004, 10, 2386;
21. (c) Z.-R. Qu, H. Zhao, Y.-P. Wang, X.-S. Wang, Q. Ye, Y.-H. Li, R.-G. Xiong, B. F. Abrahams, Z.-G. Liu, Z. L. Xue and X.-Z. You, Chem. Eur. J., 2004, 10, 54;
22. (d) H. Zhao, Z.-R. Qu, Q. Ye, B. F. Abrahams, Y.-P. Wang, Z.-G. Liu, Z. L. Xue, R.-G. Xiong and X.-Z. You, Chem. Mater., 2003, 15, 4166;
23. (e) Y.-R. Xie, H. Zhao, X.-S. Wang, Z.-R. Qu, R.-G. Xiong, X. Xue, Z. L. Xue and X.-Z. You, Eur. J. Inorg. Chem., 2003, 3712;
24. (f) Z.-R. Qu, Z.-F. Chen, J. Zhang, R.-G. Xiong, B. F. Abrahams and Z. L. Xue, Organometallics, 2003, 22, 2814;
25. (g) M. S. Hendi, P. Hooter, R. E. Davis, V. A. Lynch and K. A. Wheeler, Cryst. Growth Des., 2004, 4, 95;
26. (h) B. Dalhus and C. H. Gorbitz, Acta Crystallogr., Sect. B, 2000, 56, 715;
27. (i) S. P. Anthony and T. P. Radhakrishnan, Chem. Commun., 2004, 1058;
28. (j) Q. Ye, Y.-H. Li, Q. Wu, Y,-M. Song, J.-X. Wang, H. Zhao, R.-G. Xiong and Z.-L. Xue, Chem. Eur. J., 2005, 11, 988.
29. (a) R.-G. Xiong, X. Xue, H. Zhao, X.-Z. You, B. F. Abrahams and Z. Xue, Angew. Chem., Int. Ed., 2002, 41, 3800;
30. (b) L.-Z. Wang, Z.-R. Qu, H. Zhao, X.-S. Wang, R.-G. Xiong and Z. Xue, Inorg. Chem., 2003, 42, 3969;
31. (c) X.-F. Huang, Y.-M. Song, Q. Wu, Q. Ye, X.-B. Chen, R.-G. Xiong and X.-Z. You, Inorg. Chem. Commun, 2005, 8, 58;
32. (d) Y.-C. Wang, H. Zhao, Y.-M. Song, X.-S. Wang and R.-G. Xiong, Appl. Organomet. Chem., 2004, 18, 494;
33. (e) H. Zhao, Q. Ye, Q. Wu, Y.-M. Song, Y.-J. Liu and R.-G. Xiong, Z. Anorg. Allg. Chem., 2004, 630, 1367;
34. (f) L.-Z. Wang, X.-S. Wang, Y.-H. Li, Z.-P. Bei, R.-G. Xiong, M. Xiong and G.-W. Li, Chin. J. Inorg. Chem., 2002, 18, 1191;
35. (g) Z.-R. Qu, H. Zhao, Y.-H. Li, Y.-M. Song, Y.-J. Liu, Q. Ye, R.-G. Xiong, B. F. Abrahams, Z. Xue and X.-Z. You, Inorg. Chem., 2003, 42, 7710;
36. (h) Q. Ye, Y.-H. Li, Y.-M. Song, X.-F. Huang, R.-G. Xiong and Z. Xue, Inorg. Chem., 2005, 44, in press.
37. (a) X. Xue, X.-S. Wang, L.-Z. Wang, R.-G. Xiong, B. F. Abrahams, X.-Z. You, Z. Xue and C.-M. Che, Inorg. Chem., 2002, 41, 6544;
38. (b) X. Xue, B. F. Abrahams, R.-G. Xiong and X.-Z. You, Aust. J. Chem., 2002, 55, 495;
39. (c) R.-G. Xiong, X.-Z. You, B. F. Abrahams, Z. Xue and C.-M. Che, Angew. Chem., Int. Ed., 2001, 40, 4422;
40. (d) R.-G. Xiong, J. Zhang, Z.-F. Chen, X.-Z. You, C.-M. Che and H.-K. Fun, J. Chem. Soc., Dalton. Trans., 2001, 780.
41. (a) Z. P. Demko and K. B. Sharpless, J. Org. Chem., 2001, 66, 7945;
42. (b) Z. P. Demko and K. B. Sharpless, Org. Lett., 2001, 3, 4091;
43. (c) F. Himo, Z. P. Demko, L. Noodleman and K. B. Sharpless, J. Am. Chem. Soc., 2002, 124, 12210.
44. -1): 3448(br, m), 3052(w), 1608(vs), 1543(m), 1392(m), 1267(w), 1228(w), 1202(w), 1067(w), 1016(m), 831(w), 805(w), 786(w),697(w), 669(w), 624(w), 536(w), 511(w), 436(w). Anal. Calc. C, 62.39; H, 3.68; N, 18.20. Found: C, 62.43; H, 3.70; N, 18.07%.
45. -1, S = 1.113, Flack value is 0.04(6). CCDC reference number 218957. See http://www.rsc.org/ suppdata/dt/b5/b503039k/ for crystallographic data in CIF or other electronic format.
46. 3 are about 80 and 1 times that of urea, respectively.
47. The measurement of electric hysteresis loop: The ferroelectric property of a solid state sample was measured using a powdered sample in the form of a pellet using an RT6000 ferroelectric tester (Radiant Technologies) at room temperature while the sample was immersed in insulating oil. The electric hysteresis loop was observed by virtual ground mode (the measurement is ac, the frequency is ca. 4.5-10 Hz).
48. (a) Di Bella, S. Chem. Soc. Rev., 2000, 30, 355;
49. (b) S. Hoshino, Y. Okayaand R. Pepinsky, Phys. Rev., 1959, 115, 323;
50. (c) S. R. Fletcher, E. T. Keve and A. C. Skapski, Ferroelectrics, 1976, 14, 789;
51. (d) X. Solans, F. Franco and C. Miravitlles, Ferroelectrics, 1985, 62, 59.
52. S. K. Kurtz and T. T Perry, J. Appl. Phys., 1968, 39, 3798.