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Volumn 7, Issue 9, 2005, Pages 1918-1925

Indices for predicting the quality of leaving groups

Author keywords

[No Author keywords available]

Indexed keywords

ANION; CARBON; CATION;

EID: 18844369545     PISSN: 14639076     EISSN: None     Source Type: Journal    
DOI: 10.1039/b500996k     Document Type: Article
Times cited : (134)

References (43)
  • 1
  • 12
    • 18844409703 scopus 로고    scopus 로고
    • note
    • The original definition of Parr and Pearson differs from the modern definition by a factor of 1/2.
  • 15
    • 18844456745 scopus 로고    scopus 로고
    • note
    • One can use either the vertical or adiabatic ionization potential and electron affinity. Since rearrangements in the leaving group's geometry upon dissociation can lead to enhanced stability, the adiabatic quantities are used here.
  • 21
    • 18844452075 scopus 로고    scopus 로고
    • note
    • This is an artifact of the choice of the perfect electron donor; a real electron donor would rarely, if ever, forfeit an entire electron to an leaving group.
  • 22
    • 18844432958 scopus 로고    scopus 로고
    • note
    • Because the ionization potential is always greater than the electron affinity, eqn. (7) does not need to be written as a conditional function.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.