Rheology of diblock copolymer micellar dispersions having soft cores

Macromolecules

Volumn 38, Issue 9, 2005, Pages 3808-3819

  Watanabe, Hiroshi ^a   Matsumiya, Yumi ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL RELAXATION; DAMPING; DIFFUSION; GLASS; MICELLES; OSMOSIS; POLYBUTADIENES; POLYSTYRENES; RHEOLOGY; VISCOELASTICITY;

BROWNIAN STRESS; HOMOPOLYSTYRENE; INTERFACIAL RELAXATION; ORIENTATIONAL RELAXATION;

BLOCK COPOLYMERS;

EID: 18744401653     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma050227k     Document Type: Article

References (59)

1. Watanabe, H.; Kotaka, T.; Hashimoto, T.; Shibayama, M.; Kawai, H. J. Rheol. 1082, 26, 153.
2. Watanabe, H. Acta Polym. 1997, 48, 215.
3. Sato, T.; Watanabe, H.; Osaki, K.; Yao, M. L. Macromolecules 1996, 29, 3881.
4. Watanabe, H.; Kanaya, T.; Takahashi, Y. Macromolecules 2001, 34, 662.
5. Watanabe, H.; Matsumiya, Y.; Kanaya, T.; Takahashi, Y. Macromolecules 2001, 34, 6742.
6. Watanabe, H.; Kotaka, T. J. Rheol. 1983, 27, 223.
7. Watanabe, H.; Sato, T.; Osaki, H. Macromolecules 1998, 29, 104.
8. Watanabe, H.; Sato, T.; Osaki, H. Macromolecules 1996, 29, 113.
9. Matsumiya, Y.; Watanabe, H. Macromolecules 2004, 37, 9861.
10. Watanabe, H.; Sato, T.; Osaki, K.; Hamersky, M. W.; Chapman, B. R.; Lodge, T. Macromolecules 1998, 31, 3740.
11. Gohr, K.; Pakula, T.; Tsutsumi, K.; Schartl, W. Macromolseules 1999, 32, 7156.
12. Gohr, K.; Schartl, W. Macromolecules 2000, 33, 2129.
13. Mellema, J.; van der Werff, J. C.; Blom, C.; de Kruif, C. G. Phys. Rev. A 1989, 39, 3696.
14. Shikata, T.; Pearson, D. S. J. Rheol. 1994, 38, 601.
15. Watanabe, H.; Yao, M. L.; Yamagishi, A.; Osaki, K.; Shikata, T.; Niwa, H.; Morishima, Y. Rheol. Acta 1998, 35, 433.
16. Watanabe, H.; Yao, M. L.; Osaki, K.; Shikata, T.; Niwa, H.; Morishima, Y. Rheol. Acta 1999, 38, 2.
17. Brady, J. F. J. Chem. Phys. 1993, 99, 567.
18. Bender, J. W.; Wagner, N. J. J. Colloid Interface Sci. 1995, 172, 171.
19. Watanabe, H.; Sato, T.; Osaki, K.; Yao, M. L. Macromolecules 1996, 29, 3890.
20. Osaki, K.; Nishizawa, K.; Kurata, M. Macromolecules 1982, 15, 1068.
21. Osaki, K.; Takatori, E.; Kurata, M.; Watanabe, H.; Yoshida, H.; Kotaka, T. Macromolecules 1990, 23, 4392.
22. Takatori, E.; Osaki, K.; Kurata, M.; Hirayama, T. Nihon Reoroji Gakkaishi (J. Soc. Rheol. Jpn.) 1988, 16, 99.
23. Fetters, L. J.; Kiss, A. D.; Pearson, D. S.; Quack, G. F.; Vitus, F. J. Macromolecules 1993, 26, 647.
24. Watanabe, H. Prog. Polym. Sci. 1999, 24, 1253.
25. Watanabe, H.; Yao, M. L.; Sato, T.; Osaki, K. Macromolecules 1997, 30, 5905.
26. Yamane, H.; Takahashi, M.; Hayashi, R.; Okamoto, K.; Kashihara, H.; Masuda, T. J. Rheol. 1998, 42, 567.
27. Okamoto, K.; Takahashi, M.; Yamane, H.; Kashihara, H.; Watanabe, H.; Masuda, T. J. Rheol. 1999, 43, 951.
28. Hayashi, R.; Takahashi, M.; Yamane, H.; Jinnnai, H.; Watanabe, H. Polymer 2001, 42, 757.
29. Okamoto, K.; Takahashi, M.; Watanabe, H.; Koyama, K.; Masuda, T. Stress Relaxation of Polyisobutylene/Polydimethylsiloxane Blends under Large Step Strain and Calculation of Stress from Droplet Shape. In Advanced Polymers and Processing (Proceedings of ICAPP 2001 Yonezawa); Iwakura, K., Ed.; City Print: Yonezawa, Japan, 2002; p 195.
30. Wetzel, E. D.; Tucker, C. L. J. Fluid Mech. 2001, 426, 199.
31. Tucker, C. L.; Moldenaers, P. Annu. Rev. Fluid Mech. 2002, 34, 177.
32. Jansseune, T.; Moldenaers, P.; Mewis, J. Rheol. Acta 2004, 43, 592.
33. (a) The PB block of one of the copolymer, PB-PS 16-81, was made with deutrated monomer for a future neutron scattering experiment under shear.
34. (b) Morton, M. Anionic Polymerization: Principles and Practice; Academic Press: New York, 1983.
35. Watanabe, H.; Urakawa, O.; Yamada, H.; Yao, M. L. Macromolecules 1996, 29, 755.
36. Lodge, T. P.; Xu, X.; Ryu, C. Y.; Hamley, I. W.; Fairclough, J. P. A.; Ryan, A. J.; Pedersen, J. S. Macromolecules 1996, 29, 5955.
37. Hanley, K. J.; Lodge, T. P.; Huang, C. I. Macromolecules 2000, 33, 5918.
38. Ferry, J. D. Viscoelastic Properties of Polymers, 3rd ed.; Wiley: New York, 1980.
39. Bates, F. S.; Rosedale, J. H.; Fredrickson, G. H. J. Chem. Phys. 1990, 92, 6255.
40. Bates, F. S.; Fredrickson, G. H. Annu. Rev. Phys. Chem. 1990, 41, 525.
41. Watanabe, H.; Yoshida, H.; Kotaka, T. Macromolecules 1992, 25, 2442.
42. Watanabe, H.; Matsumiya, Y.; Inoue, T. Macromolecules 2002, 36, 2339.
43. Watanabe, H. Kobunshi Ronbunshu 2001, 58, 135.
44. r) were utilized as the viscosities in the iso-ζ state.
45. Raju, V. R.; Menezes, E. V.; Marin, G.; Graessley. W. W.; Fetters, L. J. Macromolecules 1981, 14, 1668.
46. Colby, R. H.; Fetters, L. J.; Graessley, W. W. Macromolecules 1987, 20, 2226.
47. 0,corona as the medium viscosity in the emulsion model.
48. Choi, S. J.; Schowalter, W. R. Phys. Fluids 1975, 18, 420.
49. Palierne, J. F. Rheol. Acta 1990, 29, 204.
50. Graebling, D.; Muller, R.; Palierne, J. F. Macromolecules 1993, 26, 320.
51. Nam, K. H.; Jo, W. H. Polymer 1995, 36, 3727.
52. Wu, S. In Surface and Interfacial Tensions of Polymers, Oligomers, Plasticizers, and Organic Pigments, in Polymer Handbook; Brandrup, J., Immergut, E. H., Eds.; Wiley: New York, 1989.
53. Anastasiadis, S. H.; Gancarz, I.; Koberstein, J. T. Macromolecules 1989, 22, 1449.
54. Park, D. W.; Roe, R. J. Macromolecules 1991, 24, 5324.
55. Koppi, K. A.; Tirrell, M.; Bates, F. S.; Almdal, K.; Mortensen, K. J. Rheol. 1994, 38, 999.
56. In homopolymer blends containing micrometer-sized droplets, the droplet diffusion should occur after the interfacial relaxation, However, the number density of such large droplets is quite small (compared to that of the copolymer micelles examined in this study) so that the viscoelastic intensity associated to the droplet diffusion is too small to be detected experimentally.
57. Hashimoto, T.; Fujimura, M.; Kawai, H. Macromolecules 1980, 13, 1660.
58. Dimarzio, E. A. J. Chem. Phys. 1965, 42, 2101.
59. Miyaki, Y.; Einaga, Y.; Fujita, H. Macromolecules 1978, 11, 1180.