J-coupling and chemical-shift evolution during I-spin irradiation of I mSn systems: Product operator solutions and applications

Concepts in Magnetic Resonance Part A: Bridging Education and Research

Volumn 14, Issue 5, 2002, Pages 287-307

  Skinner, Thomas E ^a   Bendall, M Robin ^b  

^a WRIGHT STATE UNIVERSITY   (United States)

^b Adiabatics Inc   (United States)

Author keywords

J coupling; Product operator formalism; Spin 1 2 systems; Vector models

Indexed keywords

ACCELERATION; ARTICLE; CALIBRATION; DENSITY; IRRADIATION; MAGNETISM; MATHEMATICAL COMPUTING; PROTON NUCLEAR MAGNETIC RESONANCE; SIGNAL DETECTION;

EID: 18544371953     PISSN: 15466086     EISSN: None     Source Type: Journal    
DOI: 10.1002/cmr.10034     Document Type: Article

References (28)

1. Sørensen OW, Eich GW, Levitt ML, Bodenhausen G, Ernst RR. Product operator formalism for the description of NMR pulse experiments. Prog NMR Spectrosc 1983; 16:163-192.
2. Van den Ven RJM, Hilbers CW. A simple formalism for the description of multiple-pulse experiments. Application to a weakly coupled two-spin (I = 1/2) system. J Magn Reson 1983; 54:512-520.
3. Packer KJ, Wright KM. The use of single-spin operator basis sets in the NMR spectroscopy of scalar-coupled spin systems. Mol Phys 1983; 50:797-813.
4. Shriver J. Product operators and coherence transfer in multiple-pulse NMR experiments. Concepts Magn Reson 1992; 4:1-33.
5. Stoll ME, Vega AJ, Vaughan RW. Double resonance interferometry: relaxation times for dipolar forbidden transitions and off-resonance effects in an AX spin system. J Chem Phys 1977; 67:2029-2038.
6. Canet D, Brondeau J, Marchal JP, Nery H. Selective pulses applied to multiplets in homonuclear-coupled NMR spectra; determination of mutual couplings. J Magn Reson 1979; 36:35-51.
7. Brondeau J, Canet D. Polarization transfer via J coupling by semiselective excitation applied to the high gyromagnetic ratio nucleus. J Magn Reson 1982; 47:419-440.
8. Levitt MH, Bodenhausen G, Ernst RR. The illusions of spin decoupling. J Magn Reson 1983; 53:443-461.
9. Bazzo R, Boyd J. A theoretical analysis of homonuclear cross-polarization coherence transfer in liquids. J Magn Reson 1987; 75:452-466.
10. Bazzo R, Boyd J. Pulse shaping and selective excitation. The effect of scalar coupling. J Magn Reson 1988; 79:568-576.
11. Emsley L, Burghardt I, Bodenhausen G. Double selective inversion in NMR and multiple quantum effects in coupled spin systems. J Magn Reson 1990; 90:214-220.
12. Davis DG. Selective excitation of protons directly bonded to carbon-13. J Magn Reson B 1993; 101:229-239.
13. 3S spin systems. J Magn Reson 1998; 130:169-175.
14. n systems during arbitrary RF irradiation of the I spins. J Magn Reson 1999; 141:271-285.
15. Anderson WA, Freeman R. Influence of a second radiofrequency field on high-resolution nuclear magnetic resonance spectra. J Chem Phys 1962; 37:85-103.
16. Waugh JS. Theory of broadband spin decoupling. J Magn Reson 1982; 50:30-49.
17. Shaka AJ, Keeler J. Broadband spin decoupling in isotropic liquids. Prog NMR Spectrosc 1987; 19:47-129.
18. Goldstein H. Classical mechanics. Reading, MA: Addison-Wesley; 1980. p 109.
19. Siminovitch DJ, Rotations in NMR. I. Euler-Rodrigues parameters and quaternions. Concepts Magn Reson 1997; 9:149-171.
20. Siminovitch DJ. Rotations in NMR. II. Applications of the Euler-Rodrigues parameters. Concepts Magn Reson 1997; 9:211-225.
21. Shaka AJ. Composite pulses for ultra-broadband spin inversion. Chem Phys Lett 1985; 120:201-205.
22. Bendall MR, Skinner TE. Novel methods for characterizing a decoupler channel using 'undetectable' quantum coherences. J Magn Reson 1999; 139:175-180.
23. Bendall MR, Skinner TE. J pulses for multiplet-selective NMR. J Magn Reson 1999; 141:262-270.
24. Bendall MR, Skinner TE. Comparison and use of vector and quantum representations of J-coupled spin evolution in an IS system during RF irradiation of one spin. J Magn Reson 2000; 143:329-351.
25. Skinner TE, Bendall MR. A vector model of adiabatic decoupling. J Magn Reson 1998; 134:315-330.
26. Bendall MR, Skinner TE. Calibration of STUD+ parameters to achieve optimally efficient broadband adiabatic decoupling in a single transient. J Magn Reson 1998; 134:331-349.
27. Chiarparin E, Pelupessy P, Bodenhausen G. Selective cross-polarization in solution state NMR. Mol Phys 1998; 95:759-767.
28. Pelupessy P, Chiarparin E. Hartmann-Hahn polarization transfer in liquids: an ideal tool for selective experiments. Concepts Magn Reson 2000; 12:103-124.