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A noteworthy example is provided by verdoheme, a green iron porphyrin with an oxygen atom in place of one of the bridging methine units (meso carbons). See for instance: K. T. Nguyen, S. P. Rath, L. Latos-Grazynski, M. M. Olmstead and A. L. Balch, J. Am. Chem. Soc., 2004, 126, 6210;
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