A Shock-Tube, Laser-Schlieren Study of the Dissociation of 1,1,1-Trifluoroethane: An Intrinsic Non-RRKM Process

Journal of Physical Chemistry A

Volumn 108, Issue 13, 2004, Pages 2443-2450

  Kiefer, J H ^a   Katopodis, C ^a   Santhanam, S ^a   Srinivasan, N K ^a   Tranter, R S ^a  

^a 1120 Science and Engineering Offices   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

LASER-SCHLIEREN (LS) MEASUREMENTS; VIBRATIONAL RELAXATION;

ACTIVATION ANALYSIS; ATMOSPHERICS; DISSOCIATION; EXTRAPOLATION; GROUND STATE; HIGH TEMPERATURE EFFECTS; MOLECULAR DYNAMICS; MOLECULAR VIBRATIONS; REACTION KINETICS; RELAXATION PROCESSES; SHOCK TUBES; THERMAL EFFECTS;

LASER BEAM EFFECTS;

EID: 1842814012     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp036282h     Document Type: Article

References (52)

1. Bunker, D. L.; Hase, W. L. J. Chem. Phys. 1973, 59, 4621. Bunker, D. L. The Theory of Elementary Reaction Rates; Pergamon: London, 1966.
2. Bunker, D. L.; Hase, W. L. J. Chem. Phys. 1973, 59, 4621. Bunker, D. L. The Theory of Elementary Reaction Rates; Pergamon: London, 1966.
3. Holbrook, K. A.; Pilling, M. J.; Robertson, S. H. Unimolecular Reactions; Wiley: New York, 1996. Pritchard, H. O. The Quantum Theory of Unimolecular Reactions; Cambridge: London, 1984, Forst, W. Theory of Unimolecular Reactions; Academic Press: New York, 1973. Gilbert, R. G.; Smith, S. C. Theory of Unimolecular and Recombination Reactions; Blackwell: Oxford, 1990.
4. Holbrook, K. A.; Pilling, M. J.; Robertson, S. H. Unimolecular Reactions; Wiley: New York, 1996. Pritchard, H. O. The Quantum Theory of Unimolecular Reactions; Cambridge: London, 1984, Forst, W. Theory of Unimolecular Reactions; Academic Press: New York, 1973. Gilbert, R. G.; Smith, S. C. Theory of Unimolecular and Recombination Reactions; Blackwell: Oxford, 1990.
5. Holbrook, K. A.; Pilling, M. J.; Robertson, S. H. Unimolecular Reactions; Wiley: New York, 1996. Pritchard, H. O. The Quantum Theory of Unimolecular Reactions; Cambridge: London, 1984, Forst, W. Theory of Unimolecular Reactions; Academic Press: New York, 1973. Gilbert, R. G.; Smith, S. C. Theory of Unimolecular and Recombination Reactions; Blackwell: Oxford, 1990.
6. Holbrook, K. A.; Pilling, M. J.; Robertson, S. H. Unimolecular Reactions; Wiley: New York, 1996. Pritchard, H. O. The Quantum Theory of Unimolecular Reactions; Cambridge: London, 1984, Forst, W. Theory of Unimolecular Reactions; Academic Press: New York, 1973. Gilbert, R. G.; Smith, S. C. Theory of Unimolecular and Recombination Reactions; Blackwell: Oxford, 1990.
7. Some examples, among many, are: Wilson, D. J. J. Phys. Chem. 1960, 64, 323. Grant, E. R.; Bunker, D. L. J. Chem. Phys. 1978, 68, 628. Hedges, R. M.; Reinhardt, W. P. Chem. Phys. Lett. 1982, 91, 241, Hase, W. L.; Wolf, R. J. J. Chem. Phys. 1981, 75, 3809, Hase, W. L.; Wolf, R. J.; Sloane, C. S. J. Chem. Phys. 1979, 71, 2911. Schofield, S. A.; Wolynes, P. G. Chem. Phys. Lett. 1994, 217, 497. Shalashilin, D. V.; Thompson, D. L. J. Chem. Phys. 1997, 107, 6204.
8. Some examples, among many, are: Wilson, D. J. J. Phys. Chem. 1960, 64, 323. Grant, E. R.; Bunker, D. L. J. Chem. Phys. 1978, 68, 628. Hedges, R. M.; Reinhardt, W. P. Chem. Phys. Lett. 1982, 91, 241, Hase, W. L.; Wolf, R. J. J. Chem. Phys. 1981, 75, 3809, Hase, W. L.; Wolf, R. J.; Sloane, C. S. J. Chem. Phys. 1979, 71, 2911. Schofield, S. A.; Wolynes, P. G. Chem. Phys. Lett. 1994, 217, 497. Shalashilin, D. V.; Thompson, D. L. J. Chem. Phys. 1997, 107, 6204.
9. Some examples, among many, are: Wilson, D. J. J. Phys. Chem. 1960, 64, 323. Grant, E. R.; Bunker, D. L. J. Chem. Phys. 1978, 68, 628. Hedges, R. M.; Reinhardt, W. P. Chem. Phys. Lett. 1982, 91, 241, Hase, W. L.; Wolf, R. J. J. Chem. Phys. 1981, 75, 3809, Hase, W. L.; Wolf, R. J.; Sloane, C. S. J. Chem. Phys. 1979, 71, 2911. Schofield, S. A.; Wolynes, P. G. Chem. Phys. Lett. 1994, 217, 497. Shalashilin, D. V.; Thompson, D. L. J. Chem. Phys. 1997, 107, 6204.
10. Some examples, among many, are: Wilson, D. J. J. Phys. Chem. 1960, 64, 323. Grant, E. R.; Bunker, D. L. J. Chem. Phys. 1978, 68, 628. Hedges, R. M.; Reinhardt, W. P. Chem. Phys. Lett. 1982, 91, 241, Hase, W. L.; Wolf, R. J. J. Chem. Phys. 1981, 75, 3809, Hase, W. L.; Wolf, R. J.; Sloane, C. S. J. Chem. Phys. 1979, 71, 2911. Schofield, S. A.; Wolynes, P. G. Chem. Phys. Lett. 1994, 217, 497. Shalashilin, D. V.; Thompson, D. L. J. Chem. Phys. 1997, 107, 6204.
11. Some examples, among many, are: Wilson, D. J. J. Phys. Chem. 1960, 64, 323. Grant, E. R.; Bunker, D. L. J. Chem. Phys. 1978, 68, 628. Hedges, R. M.; Reinhardt, W. P. Chem. Phys. Lett. 1982, 91, 241, Hase, W. L.; Wolf, R. J. J. Chem. Phys. 1981, 75, 3809, Hase, W. L.; Wolf, R. J.; Sloane, C. S. J. Chem. Phys. 1979, 71, 2911. Schofield, S. A.; Wolynes, P. G. Chem. Phys. Lett. 1994, 217, 497. Shalashilin, D. V.; Thompson, D. L. J. Chem. Phys. 1997, 107, 6204.
12. Some examples, among many, are: Wilson, D. J. J. Phys. Chem. 1960, 64, 323. Grant, E. R.; Bunker, D. L. J. Chem. Phys. 1978, 68, 628. Hedges, R. M.; Reinhardt, W. P. Chem. Phys. Lett. 1982, 91, 241, Hase, W. L.; Wolf, R. J. J. Chem. Phys. 1981, 75, 3809, Hase, W. L.; Wolf, R. J.; Sloane, C. S. J. Chem. Phys. 1979, 71, 2911. Schofield, S. A.; Wolynes, P. G. Chem. Phys. Lett. 1994, 217, 497. Shalashilin, D. V.; Thompson, D. L. J. Chem. Phys. 1997, 107, 6204.
13. Some examples, among many, are: Wilson, D. J. J. Phys. Chem. 1960, 64, 323. Grant, E. R.; Bunker, D. L. J. Chem. Phys. 1978, 68, 628. Hedges, R. M.; Reinhardt, W. P. Chem. Phys. Lett. 1982, 91, 241, Hase, W. L.; Wolf, R. J. J. Chem. Phys. 1981, 75, 3809, Hase, W. L.; Wolf, R. J.; Sloane, C. S. J. Chem. Phys. 1979, 71, 2911. Schofield, S. A.; Wolynes, P. G. Chem. Phys. Lett. 1994, 217, 497. Shalashilin, D. V.; Thompson, D. L. J. Chem. Phys. 1997, 107, 6204.
14. Meagher, J.; Chao, K. J.; Barker, J. R.; Rabinovitch, B. S. J. Phys. Chem. 1974, 78, 2535.
15. Rodgers, P. J.; Selco, J. I.; Rowland, F. S. Chem. Phys. Lett. 1983, 97, 313.
16. See Meyer, A.; Schroeder, J.; Troe, J.; Votsmeier, M. J. Phys. Chem. 2001, 105, 4381, and references therein.
17. Kappel, Ch.; Luther, K.; Troe, J. Phys. Chem. Chem. Phys. 2002, 4, 4392.
18. Klippenstein, S. J.; Harding, L. B. J. Phys. Chem. 1999, 103, 9388.
19. Kiefer, J. H. Pros. Combust. Inst. 1998, 27, 113.
20. Srinivasan, N. K.; Kiefer, J. H.; Tranter, R. S. J. Phys. Chem. 2003, 107, 1532.
21. Santhanam, S.; Kiefer, J. H.; Tranter, R. S.; Srinivasan, N. K. Int. J. Chem. Kinet. 2003, 35, 381.
22. Lehmann, K. K.; Scoles, G.; Pate, B. H. Annu. Rev. Phys. Chem. 1994, 45, 241.
23. Fletcher, F. J.; Rabinovitch, B. S.; Watkins, K. W.; Locker, D. J. J. Phys. Chem. 1966, 70, 2823, and references therein.
24. Collister, J. L.; Pritchard, H. O. Can. J. Chem. 1976, 54, 2380.
25. Dianxun, W.; Ximei, Q.; Peng, J. Chem. Phys. Lett. 1996, 255, 149.
26. Kiefer, J. H.; Manson, A. C. Rev. Sci. Instrum. 1981, 52, 1392.
27. Kiefer, J. H., In Shock Waves in Chemistry; Lifshitz, A., Ed.: Marcel Dekker: New York, 1981; p 219.
28. Kiefer, J. H.; Kumaran, S. S.; Sundaram, S. J. Chem. Phys. 1993, 99, 3531, See also ref 10 and ref 11.
29. Gardiner, W. C., Jr.; Hidaka, Y.; Tanzawa, T. Combust. Flame 1981, 40, 213.
30. Stein, S. E.; Ruckers, J M.; Brown, R. L. NIST Stand. Ref. Database 25, Thermochemical Data, version 1, 2, 1991.
31. NIST Computational Chemistry Comparison and Benchmark Database, NIST Stand. Ref. Database, http://kinetics.nist.gov/index.php 2003, 101.
32. Just, Th. Proc. Combust. Inst. 1994, 25, 687.
33. Curtiss, L. A.; Ragavachari, K.; Redfern, P. C.; Rassolov, V.; Pople, J. A. J. Chem. Phys. 1998, 109, 7764.
34. Sianesi, D.; Nelli, G.; Fontanelli, R. Chimica e L'Industria 1968, 50, 619.
35. Tschiukow-Roux, E.; Quiring, W. J. J. Phys. Chem. 1971, 75, 295.
36. Cadman, P.; Day, M.; Trotman-Dickenson, A. F. J. Chem. Soc. A 1971, 1356.
37. Tsang, W.; Lifshitz, A. Int. J. Chem. Kinet. 1998, 30, 621.
38. Mitin, P. V.; Barabanov, V. G.; Volkov, G. V. Kinet. Catal. 1988, 29, 1279.
39. Cottrell, T. L.; McCoubrey, J. C. Molecular Energy Transfer in Gases; Butterworths: London, 1961. Stevens, B. Collision Activation in Cases; Pergamon: London, 1967. Lambert, J. D.; Salter, R. Proc. Roy. Soc. 1959, A253, 277.
40. Cottrell, T. L.; McCoubrey, J. C. Molecular Energy Transfer in Gases; Butterworths: London, 1961. Stevens, B. Collision Activation in Cases; Pergamon: London, 1967. Lambert, J. D.; Salter, R. Proc. Roy. Soc. 1959, A253, 277.
41. Cottrell, T. L.; McCoubrey, J. C. Molecular Energy Transfer in Gases; Butterworths: London, 1961. Stevens, B. Collision Activation in Cases; Pergamon: London, 1967. Lambert, J. D.; Salter, R. Proc. Roy. Soc. 1959, A253, 277.
42. Kiefer, J. H.; Sahukar, G. C.; Santhanam, S.; Srinivasan, N. K.; Tranter, R. S. J. Chem. Phys. 2004, 120, 918.
43. See Tsang, W.; Kiefer, J. H. Unimolecular Reactions of Large Polyatomic Molecules. Advanced Series in Physical Chemistry, Chemical Dynamics and Kinetics of Small Radicals Ft. 1; World Scientific: Singapore, 1995; p 58. Also note refs 10, 11, and 18.
44. Holmes, R.; Jones, G. R.; Pusat, N. J. Chem. Phys. 1964, 41, 2512.
45. Snider, N. J. Phys. Chem. 1989, 93, 5789.
46. Marcus, R. A.; Hase, W. L.; Swamy, K. N. J. Phys. Chem. 1984, 88, 6717.
47. Parks, N. J.; Krohn, K. A.; Root, J. W. J. Chem. Phys. 1971, 55, 5785.
48. Chang, H. W.; Craig, N. L.; Setser, D. W. J. Phys. Chem. 1972, 76, 954.
49. Gilbert, R. G.; Luther, K.; Troe, J. Ber. Bunsen-Ges. Phys. Chem. 1983, 87, 169.
50. Pitzer, K. S.; Gwinn, W. D. J. Chem. Phys. 1942, 10, 428.
51. Troe, J. J. Phys. Chem. 1979, 83, 114.
52. Troe, J. J. Chem. Phys. 1977, 66, 4758.