Synthesis and equilibrium studies of mixed-ligand complexes of Co(II), Ni(II), and Cu(II) with some aliphatic dicarboxylic acids and creatinine

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

Volumn 34, Issue 3, 2004, Pages 523-540

  Ahmed, Iman T ^a  

^a El Minia University ^*  (Egypt)

Author keywords

Aliphatic acids; Complex formation; Creatinine; Mixed ligand complex

Indexed keywords

ALIPHATIC DICARBOXYLIC ACID; ANION; COBALT COMPLEX; COPPER COMPLEX; CREATININE; LIGAND; MALIC ACID; METAL ION; NICKEL COMPLEX; SUCCINIC ACID; TARTARIC ACID;

ANALYTIC METHOD; ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; COMPLEX FORMATION; CONDUCTANCE; ELECTRONICS; INFRARED SPECTROSCOPY; IONIC STRENGTH; MEASUREMENT; PH MEASUREMENT; SPECTROSCOPY; STEREOCHEMISTRY; STRUCTURE ANALYSIS; SYNTHESIS; TEMPERATURE; THERMAL ANALYSIS; THERMODYNAMICS; TITRIMETRY;

EID: 1842785159     PISSN: 00945714     EISSN: None     Source Type: Journal    
DOI: 10.1081/SIM-120030438     Document Type: Article

References (38)

1. Brainerd, H.; Margen, S.; Shatton, M. Current Diagnosis and Treatment; Lang Medicinal Publications: California, 1968; 502.
2. Muralidharan, S.; Nagaraja, K.S.; Udupa, M.R. Creatinine complexes of zinc, cadmium and mercury. Polyhedron 1984, 3, 619-621.
3. Bontchev, P.R.; Mitewa, M.; Gentcheva, G. New platinum(II) and platinum(III) complexes of creatinine. Pure & Appl. Chem. 1989, 61, 897-902.
4. Mittewa, M.; Gencheva, G.; Bontchev, P.R.; Angelova, O. Monomeric Pt(II) and Pd(II) complexes with creatinine. Crystal structure of tetrakis (creatinine)-platinum(II) diperchlorate. Polyhedron 1988, 7, 1273-1278.
5. Muralidharan, S.; Nagaraja, K.S.; Udupa, M.R. Stability constants of divalent zinc, cadmium and mercury complexes of creatinine. Trans. SAEST 1983, 18, 323-325.
6. Canty, A.J.; Fyfe, M.; Gatehouse, B.M. Organometallic compounds containing a guanidinum group. Phenylmercury(II) derivatives of creatine and creatinine. Inorg. Chem. 1978, 77, 1467-1471.
7. Udupa, M.R.; Krebs, B. Crystal and molecular structure of creatininium tetrachlorocuparate(II). Inorg. Chim. Acta 1979, 33, 241-244.
8. Udupa, M.R.; Krebs, B. Crystal and molecular structure of bis(creatinine) silver(I) perchlorate dihydrate. Inorg. Chim. Acta 1981, 55, 153-156.
9. Mitewa, M.; Bontchev, P.R.; Kabassanov, K. A Four-membered chelate complex of Cu(II) with creatinine. Polyhedron 1985, 4, 1159-1161.
10. Gencheva, G.; Ivanova, I.; Mitewa, M. Dimeric Ni(II)-creatinine complex formed in anhydrous organic medium. J. Prakt. Chem. 1991, 333, 669-670.
11. 2O. Monatsh. Chem. 1988, 119, 1189-1199.
12. 2. Spectrochim. Acta 1991, 47A, 577-584.
13. Mahmoud, M.R.; Hamed, M.M.A.; Ahmed, I.T. Potentiometric studies on ternary complexes of some heavy metal ions containing N-(2-acetamido)- iminodiacetic acid and amino acids. Arch. Pharm. Res. 1993, 16, 78-81.
14. Hamed, M.M.A.; Saleh, M.B.; Ahmed, I.T.; Mahmoud, M.R. Formation constants of ternary complexes of some heavy metal ions with N-(2-acetamido)iminodiacetic acid and aliphatic or aromatic acids. J. Chem. Eng. Data 1994, 39, 565-567.
15. Mahmoud, M.R.; Hamed, M.M.A.; Ibrahim, S.A.; Ahmed, I.T. Divalent transition ion ternary complexes of N-(2-acetamido)iminodiacetic acid and some bi-and tricarboxylic aliphatic acids. Synth. React. Inorg. Met.-Org. Chem. 1994, 24, 1661-1679.
16. 2O Soluble ternary complexes of divalent metal ions with N-(2-acetamido) iminodiacetic acid and heterocyclic diimines. Transition. Met. Chem. 1994, 19, 494-497.
17. Mahmoud, M.R.; Ibrahim, S.A.; Hassan, A.M.A.; Ahmed, I.T. Ternary complexes of N-(2-acetamido)iminodiacetic acid and some aromatic acids. Isolation and stability constant in solution. Transition. Met. Chem. 1996, 21, 1-4.
18. 18. Mahmoud, M.R.; Abdel-Hamid, M.I.; Ismail, N.M.; Ahmed, I.T. Mixed-ligand complexes of Ni(II) and Cu(II) with N-(2-acetamido)iminodiacetic acid and some dicarboxylic amino acids. Polish. J. Chem. 1996, 70, 544-548; Chem. Abstr. 1996, 125, 47573d.
19. Mahmoud, M.R.; Abdel-Hamid, M.I.; Ismail, N.M.; Ahmed, I.T. Mixed-ligand complexes of Ni(II) and Cu(II) with N-(2-acetamido)iminodiacetic acid and some dicarboxylic amino acids. Polish. J. Chem. 1996, 70, 544-548; Chem. Abstr. 1996, 125, 47573d.
20. Ahmed, I.T. Divalent transition metal complexes of N-(2-acetamido) iminodiacetic acid and thiosemicarbazide as well as dithiocarbazate derivatives. Synth. React. Inorg. Met.-Org. Chem. 1996, 26, 1455-1465.
21. n- + dipicolinic acid + N-(2-acetamido)iminodiacetic acid or aromatic acids. J. Chem. Eng. Data 1996, 41, 386-390.
22. Ahmed, I.T.; Boraei, A.A.A.; Ibrahim, S.A. Mixed-ligand complexes of some metal ions with N-(2-acetamido)iminodiacetic acid and salicylic acid derivatives: synthesis, solution equilibria and characterization studies. Synth. React. Inorg. Met.-Org. Chem. 1997, 27, 169-186.
23. Ahmed, I.T.; Boraei, A.A.A.; El-Roudi, O.M. Mixed-ligand complexes of some divalent transition metal ions with dicarboxylic amino acids and 8-hydroxy-quinoline. J. Chem. Eng. Data 1998, 43, 459-464.
24. Boraei, A.A.A.; Ahmed, I.T. Divalent transition metal ion mixed-ligand complexes of tricine or glycylglycine and 8-hydroxyquinoline: synthesis, chracterization, and formation constants. Synth. React. Inorg. Met.-Org. Chem. 2002, 32, 981-1000.
25. Vogel, A.I. A Text Book of Quantitative Inorganic Analysis, 3rd Ed.; Longman: London, 1975; 435-443.
26. Geary, W.J. Use of conductivity measurements in organic solvents for the characterization of coordination compounds. Coord. Chem. Rev. 1971, 7, 81-122.
27. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 3rd Ed.; Wiley: New York, 1978.
28. Martin-Gil, F.J.; Martin-Gil, J. Platinum(II) and palladium(II) complexes of creatinine. Platinum blues. Inorg. Chim. Acta 1987, 137, 131-134.
29. Lever, A.B.P. Inorganic Electronic Spectroscopy; Elsevier: Amsterdam, 1968.
30. Nishikawa, H.; Yamada, S. Planar quadricoordinate complexes of cobalt (II) with Schiff bases derivatives from salicylaldehyde. Bull. Chem. Soc. Jpn. 1964, 37, 8-12.
31. Everett, G.W. Jr.; Holm, R.H. Existence of the planar ⇌ tetrahedral equilibrium in solutions of cobalt(II) complexes. J. Am. Chem. Soc. 1965, 87, 5266-5267.
32. Nicolini, M.; Pecile, C.; Turco, A. High spin-low spin conformational equilibrium in the complex dithiocyanatobis(triethylphosphine)Co(II). Coord. Chem. Rev. 1966, 1, 133-144.
33. Lever, A.B.P.; Lewis, J.; Nyholm, R.S. Pyrazine metal complexes. III. derivatives of nickel(II). J. Chem. Soc. 1963, 5042-5048.
34. Irving, H.; Rossotti, H.S. The calculation of formation curves of metal complexes from pH-titration curves in mixed solvents. J. Chem. Soc. 1954, 2904-2910.
35. Irving, H.; Rossotti, H.S. Methods for computing successive stability constants from experimental formation curves. J. Chem. Soc. 1953, 3397-3405.
36. Weast, R.C. CRC Hand Book of Chemistry and Physics, 1st Ed.; CRC Press, Inc.: Boca Raton, Florida, 1988; D-102.
37. Cotton, F.M.; Wilkinson, G. Advanced Inorganic Chemistry; Wiley (Eastern): New Delhi, 1972; 569.
38. William, R.J.P. The stability of complex ions with special reference to hydration. J. Phys. Chem. 1954, 58, 121-126.