Selective hydrogenation of 1,3-butadiene: Improvement of selectivity by using additives

Chemical Engineering Journal

Volumn 99, Issue 1, 2004, Pages 45-51

  Alves, J A ^a,b   Bressa, S P ^a,b   Martinez O M ^a,b   Barreto, G F ^a,b  

^a UNIVERSIDAD NACIONAL DE LA PLATA   (Argentina)

^b UNIVERSIDAD NACIONAL DE LA PLATA   (Argentina)

Author keywords

1,3 Butadiene; 1 Butene; Isoprene; Kinetics; Pd catalyst; Selective hydrogenation

Indexed keywords

ABSORPTION; CHEMICAL INDUSTRY; HYDROGENATION; PARTIAL PRESSURE; PRESSURE EFFECTS;

ISOPRENE;

CATALYST SELECTIVITY;

HYDROGENATION;

EID: 1842740951     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2003.09.005     Document Type: Article

References (12)

1. Derrien M.L.Selective hydrogenation applied to the refining of petrochemical raw materials produced by steam cracking Stud. Surf. Sci. Catal. 27 1986 613-666
2. Hub S.Hilaire L.Touroude R.Hydrogenation of but-1-yne and but-1-ene on palladium catalyst. Particle size effect Appl. Catal. 36 1988 307-322
3. J.-P. Boitiaux, J. Cosyns, M. Derrien, G. Léger, Proper design of butadiene hydrogenation process for maximum 1-butene yield by using comprehensive kinetic modeling, in: Proceedings of the AIChE Spring National Meeting, Paper No. 1453, Houston, USA, 1985.
4. Vergel C.Euzen J.P.Trambouze P.Wauqier J.P.Two-phase flow catalytic reactor. Influence of hydrodynamics on selectivity Chem. Eng. Sci. 50 1995 3303-3312
5. Bressa S.P.Ardiaca N.O.Martínez O.M.Barreto G.F.Analysis of operating variables in the catalytic purification of butene-1 in a trickle bed Chin. J. Chem. Eng. 62 1998 103-115
6. Bressa S.P.Alves J.A.Martínez O.M.Barreto G.F.Analysis of operating variables on the performance of a reactor for total hydrogenation of olefins in a C3-C4 stream Chem. Eng. J. 921-3 2003 41-54
7. Ardiaca N.O.Bressa S.P.Alves J.A.Martínez O.M.Barreto G.F.Experimental procedure for kinetic studies on egg-shell catalysts. The case of liquid-phase hydrogenation of 1,3-butadiene and n-butenes on commercial Pd catalysts Catal. Today 643-4 2001 205-215
8. 3 catalyst Stud. Surf. Sci. Catal. 133 2001 527-534
9. Boitiaux J.-P.Cosyns J.Derrien M.Léger G.Newest hydrogenation catalysts Hydrocarb. Process. 644 1985 51-59
10. Bressa S.P.Martínez O.M.Barreto G.F.Kinetic study of the hydrogenation and hydroisomerization of the n-butenes on a commercial palladium/alumina catalyst Ind. Eng. Chem. Res. 42 2003 2081-2092
11. Stewart W.E.Caracotsios M.Sørensen J.P.Parameter estimation from multiresponse data AIChE J. 38 1992 641-650
12. Bressa S.P.Ardiaca N.O.Martínez O.M.Barreto G.F.Approximate expressions to evaluate the performance in butene-1 purification units Chin. J. Chem. Eng. 63 1998 271-276