Unusual mechanism of hydrolysis of the tosyl cyanide-cyclopentadiene adduct to the lactam 2-azabicyclo[2.2.1]hept-5-en-3-one

Chemical Communications

Volumn , Issue 15, 1996, Pages 1811-1812

  Morgan, Paul E ^a   McCague, Ray ^b   Whiting, Andrew ^a  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

^b Chiroscience Ltd   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 1842577821     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/CC9960001811     Document Type: Article

References (18)

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10. 3), 4.42 (1 H, m, HCC=N), 5.39 (1 H, m, HC=N), 6.80 (2 H, m, HC=CH), 7.37 and 7.78 (each 2 H. d, J 9 Hz, ArH's).
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15. R. McCague, P. E. Morgan and A. Whiting, unpublished results.
16. 18O, 112.0648.
17. 3O). Other minor products were also detected which were consistent with the fact that sulphinate 7 undergoes disproportionation.
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