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Recognition and discrimination capabilities are typically assessed with respect to individual vapors well above their LODs, for example, by matching to calibrated response patterns stored in a library. Pairwise discriminations have been espoused by certain researchers as indicators of the resolving power of an array where the response from each individual vapor in the data set is serially compared to that of another vapor until all possible pairs are made (e.g. refs 33 and 34). Such analyses are of limited value in forecasting performance for practical vapor determination problems because they neglect both the need to recognize the vapors and the possibility that both components are present simultaneously.
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