Substitution and intramolecular rearrangement of trans-[ReO(X)(acac 2en/pn)]0/+ (X = OH2 or Cl-) to yield asymmetric cis-[ReO(Y)(acac2en/pn)] complexes with cyanide and thiocyanate

Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

Volumn 35, Issue 1, 2005, Pages 53-59

  Green, Jenny L ^a   Benny, Paul D ^a   Engelbrecht, Hendrik P ^a   Barnes, Charles L ^a   Jurisson, Silvia S ^a  

^a UNIVERSITY OF MISSOURI   (United States)

Author keywords

Re(V) cyanide complex; Re(V) thiocyanate complexes; Rhenium(V); Schiffbase complexes

Indexed keywords

CHLORINE; CYANIDE; RHENIUM; SCHIFF BASE; THIOCYANATE; WATER;

ARTICLE; REACTION ANALYSIS; SPECTROSCOPY; STRUCTURE ANALYSIS; SUBSTITUTION REACTION; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

EID: 18344389593     PISSN: 15533174     EISSN: None     Source Type: Journal    
DOI: 10.1081/SIM-200047547     Document Type: Article

References (22)

1. Basson, S. S.; Leipoldt, J. G.; Roodt, A.; Purcell, W. The Crystal Structure of bis(1,4-dithioniumbicyclo[2,2,2]octane)-μ-oxobis [tetracyanooxorhenate(V)] tetrahydrate. Transition Met. Chem. 1987, 12, 82-84.
2. 2}], and Example of Four-co-ordination by a Potentially Sexidentate Ligand. J. Chem. Soc. Dalton Trans. 1989, 1405-1407.
3. 2. Inorg. Chim. Acta 1990, 170, 23-26.
4. 2 Schiff Base Monomer and Dimer Complexes. Inorg. Chem. 2003, 42, 6519-6527.
5. Benny, P. D.; Green, J. L.; Engelbrecht, H. P.; Barnes, C. L.; Jurisson, S. S. Reactivity of Re(V) Oxo Schiff Base Complexes with Phosphine Ligands: Rearrangement and Reduction Reactions. Inorg. Chem. 2005, under revision.
6. Bereau, V. M.; Khan, S. I.; Abu-Omar, M. M. Synthesis of Enantiopure Oxorhenium(V) and Arylimidorhenium(V) "3 + 2" Schiff Base Complexes. X-ray Diffraction, Cyclic Voltammetry, UV-Vis, and Circular Dichroism Characterizations. Inorg. Chem. 2001, 40, 6767-6773.
7. Bottomley, L. A.; Wojciechowski, P. E.; Holder, G. N. Voltammetry of Monomeric and Dimeric Oxorhenium(V) Complexes of Schiff Base Ligands N,N′-ethylenebis(acetylacetone)diimine, N,N′-ethylene(salicylidene) diimine and N,N′-phenylbis(salicylidene) diimine. Inorg. Chim. Acta 1997, 255, 149-155.
8. Buckingham, D. A. The linkage isomerism of thiocyanate bonded to cobalt(III). Coord. Chem. Rev. 1994, 135/136, 587-621.
9. Carrondo, M. A. A. F. de C.T.; Middleton, A. R.; Skapski, A. C.; West, A. P.; Wilkinson, G. A Novel Linear O-Re-O-Re-O-Re-O System: The Synthesis and X-ray Structure of Di-μ-oxo-bis{[N,N′-ethylenebis(acetylacetiminato)]- oxorhenium(V)}[N,N′-ethylenebis(acetylacetiminato)]rhenium(V)Perrhenate. Inorg. Chim. Acta 1980, 44, L7-L8.
10. Davison, A.; Jones, A. G.; Muller, L.; Tatz, R.; Trop, H. S. Synthesis and Characterization of Oxopentakis(isothiocyanato)metalate(V) Complexes of Rhenium and Technetium. Inorg. Chem. 1981, 20, 1160-1163.
11. Hermann, W. A.; Rauch, M. U.; Artis, G. R.J. Multiple Bonds between Main Group Elements and Transition Metals. 153. Rhenium(V) Oxo Complexes with Tetradentate Schiff Bases: Structural Considerations. Inorg. Chem. 1996, 35, 1988-1991.
12. 2(CDO)BMe. Inorg. Chem. 1998, 37, 1922-1928.
13. 2O. Acta Crystallogr. C. 1991, 47, 501.
14. Middleton, A. R.; Masters, A. F.; Wilkinson, G. Schiff Base Complexes of Rhenium(IV) and Rhenium(V). J. Chem. Soc. Dalton Trans. 1979, 542-546.
15. Purcell, W.; Roodt, A.; Basson, S. S.; Geipoldt, J. G. The Crystal Structure of Tetraphenylphosphonium Tetracyanohydroxooxorhenium(V). Transition Met. Chem. 1989, 14, 5-6.
16. Purcell, W.; Roodt, A.; Basson, S. S.; Leipoldt, J. C. The Crystal Structure of Tetraethylammonium Aquatetracyanooxorhenate(V). Transition Met. Chem. 1990, 15, 239-241.
17. Sheldrick, G. M. SHELXS-97, Crystal Structure Solution; University of Gottingen: Gottingen, Germany, 1997a.
18. Sheldrick, G. M. SHELXL-97, Crystal Structure Refinement; University of Gottingen: Gottingen, Germany, 1997b.
19. Trop, H. S.; Jones, A. G.; Davison, A. Technetium Cyanide Chemistry: Synthesis and Characterization of Technetium(III) and -(V) Cyanide Complexes. Inorg. Chem. 1980, 19, 1993-1997.
20. Tisato, F.; Refosco, F.; Mazzi, U.; Bandoli, G.; Dolmella, A. Synthesis, Characterization and Electrochemical Studies on Technetium(V) and Rhenium(V) Oxo-complexes with N,N′-2-Hydroxypropane-1,3-bis(salicylideneimine). Inorg. Chim. Acta. 1989, 164, 127-135.
21. Tisato, F.; Refosco, F.; Mazzi, U.; Bandoli, G.; Nicolini, M. Rhenium(V) oxo complexes with Schiff Base Ligands Containing Four or Five Coordination Sites. X-ray Molecular Structure of [N,N′-3-azapentane-1,5- diylbis(salicylideneiminato)(3-)-O,O′,N,N′,N″]oxorhenium (V). Inorg. Chim. Acta 1991, 189, 97-103.
22. van Bommel, K. J.C.; Verboom, W.; Kooijman, H.; Spek, A. L.; Reinhoudt, D. N. Rhenium(V)-Salen Complexes: Configurational Control and Ligand Exchange. Inorg. Chem. 1998, 37, 4197-4203.