Ce4+-malonic acid reaction in the presence of O2. Reaction channels leading to tartronic and oxalic acid intermediates

Journal of Physical Chemistry A

Volumn 104, Issue 44, 2000, Pages 9914-9920

  Hegedüs, László ^a,b   Försterling, Horst Dieter ^a,b   Wittmann, Mária ^a,b   Noszticzius, Zoltán ^a,b  

^a PHILIPPS UNIVERSITY MARBURG   (Germany)

^b BUDAPEST UNIVERSITY OF TECHNOLOGY AND ECONOMICS   (Hungary)

Author keywords

[No Author keywords available]

Indexed keywords

CERIUM; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; OXIDATION; OXYGEN; RATE CONSTANTS;

MALONIC ACID; OXALIC ACID; TARTRONIC ACID;

CARBOXYLIC ACIDS;

EID: 18144368412     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp001005l     Document Type: Article

References (24)

1. Oscillations and Traveling Waves in Chemical Systems; Field, R. J., Burger, M., Eds.; Wiley: New York, 1985.
2. Chemical Waves and Patterns; Kapral, R., Showalter, K., Eds.; Kluwer: Dordrecht, The Netherlands, 1995.
3. Field, R. J. In ref 1., p 65.
4. Ruoff, P.; Noyes, R. M. J. Phys. Chem. 1989, 93, 7394.
5. Chou, Y.-C.; Lin, H.-P.; Sun, S. S.; Jwo, J.-J. J. Phys. Chem. 1993, 97, 8450.
6. Wana, J.; Hynne, F.; Sorensen, P. G.; Nielsen, K. J. Phys. Chem. 1996, 700, 17593.
7. Treindl, L.; Ruoff, P.; Kvernberg, P. O. J. Phys. Chem. A 1997, 101, 4606.
8. Zhabotinsky, A. M.; Müller, S. C; Hess, B. Physica D 1991, 49, 47.
9. Zhabotinsky, A. M.; Eager, M. D.; Epstein, I. R. Phys. Rev. Lett. 1993, 71, 1526.
10. Ungvárai, J.; Nagy-Ungvárai, Zs. ACH - Models in Chemistry 1998, 135, 393.
11. Neumann, B.; Müller, S. C. J. Am. Chem. Soc. 1995, 117, 6372.
12. Neumann, B.; Steinbock, O.; Müller, S. C.; Dalai, N. S. J. Phys. Chem. A 1997, 101, 2743.
13. Gao, Y.; Försterling, H.-D.; Noszticzius, Z.; Meyer, B. J. Phys. Chem. 1994, 95, 8377.
14. Sirimungkala, A.; Försterling, H.-D.; Noszticzius, Z. J. Phys. Chem. 1996, 100, 3051.
15. Försterling, H.-D.; Pachl, R.; Schreiber, H. Z Naturforsch. 1987, 42a, 963.
16. The column used for the separation of organic acids was a Merck, Polyspher OA KC cation exchanger column with a length of 30 cm and diameter of 7.8 mm which was proposed by Merck for our special requirements. The column could resolve all the organic acids relevant for the present research except for the oxalic acid-ethane tetracarboxylic acid pair.
17. Oslonovitch, J.; Försterling, H.-D.; Wittmann, M.; Noszticzius, Z. J. Phys. Chem. A 1998, 702, 922.
18. Szalai, I.; Försterling, H.-D.; Noszticzius, Z. J. Phys. Chem. A 1998, 702, 3118.
19. Feigl, F.; Anger, V. Spot tests in organic analysis; Elsevier: Amsterdam, 1966; p 457.
20. Nagygyõry, Sz.; Wittmann, M.; Pintér, Sz.; Visegrády, A.; Dancsó, A.; Thuy, N. B.; Noszticzius, Z.; Hegedûs, L.; Försterling, H.-D. J. Phys. Chem. A 1999, 705, 4885.
21. Schuchmann, M. N.; Rao, R.; Hauser, M.; Müller, S. C.; Sonntag, C. J. Chem. Soc., Perkin Trans. 2000, 2, 941.
22. 2 atmosphere is still an acceptable estimation.
23. Knoller, Y.; Perlmutter-Hayman, B. J. Am. Chem. Soc. 1955, 77, 3212.
24. Krüger, F.; Nagy-Ungvárai, Zs.; Müller, S. C. Physica D 1995, 84, 95.