The kinetic and mechanistic role of oil-soluble initiators in micro-and macroemulsion polymerizations

Industrial and Engineering Chemistry Research

Volumn 44, Issue 8, 2005, Pages 2561-2567

  Nomura, Mamoru ^a   Suzuki, Kiyoshi ^a  

^a UNIVERSITY OF FUKUI   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ELEMENTARY PARTICLES; INITIATORS (CHEMICAL); POTASSIUM COMPOUNDS; STYRENE;

MICROEMULSION; OIL-SOLUBLE AZO-TYPE INITIATORS; OIL-SOLUBLE INITIATORS; WATER-SOLUBLE INITIATORS;

EMULSION POLYMERIZATION;

POLYMERIZATION;

EID: 18144367790     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie0401612     Document Type: Article

References (11)

1. Nomura, M.; Ikoma, J.; Fujita, K. Kinetics and Mechanism of Particle Formation and Growth in the Emulsion Polymerization Initiated by Oil-soluble Initiator, 2,2′-Azoisobutyronitrile. In Polymer Latexes: Preparation, Characterization, and Applications; Sudol, E. D., El-Aasser, M. S., Eds.; ACS Symposium Series 492; American Chemical Society: Washington, DC, 1992; p 55.
2. Suzuki, K.; Goto, A.; Takayama, M.; Muramatsu, A.; Nomura, M. An Experimental Study on the Kinetics and Mechanism of Styrene Polymerization in Oil-in-water Microemulsion Initiated by Oil-Soluble Initiators. Macromol. Symp. 2000, 155, 199.
3. Nomura, M.; Suzuki, K. A New Kinetic Interpretation of the Styrene Microemulsion Polymerization. Macromol. Chem. Phys. 1997, 198, 3025.
4. Suzuki, K.; Nomura, M.; Harada, M. An Experimental Study on the Kinetics and Mechanism of Styrene Polymerization in Oil-in-water Microemulsion Initiated by Oil-Soluble Initiators. Colloids Surf., A 1999, 153, 23.
5. Quo. J. S.; Sudol, E. D.; Vanderhoff, J. W.; El-Aasser, M. S. J. Polym. Sci., Part A: Polym. Chem. 1992, 30, 691.
6. Asua, M.; Rodriguez, V. S.; Sudol, E. D.; El-Aasser, M. S. The Free Radical Distribution in Emulsion Polymerization Using Oil-Soluble Initiators. J. Polym. Sci., Part A: Polym. Chem. 1989, 27, 3569.
7. Alduncin, J. A.; Forcada, J.; Barandiaran, M. J.; Asua, J. M. On the Main Locus of Radical Formation in Emulsion Polymerization Initiated by Oil-Soluble Initiators. J. Polym. Sci., Part A: Polym. Chem. 1991, 29, 1265.
8. Nomura, M.; Fujita, K. Kinetics and Mechanism of Emulsion Polymerization Initiated by Oil-soluble Initiators. I. The average number of Radicals per Particle. Makromol. Chem., Rapid Commun. 1989, 10, 581-587.
9. Nomura, M.; Yamada, A.; Fujita, S.; Sugimoto, A.; Ikoma, J.; Fujita, K Kinetics and Mechanism of Emulsion Polymerization Initiated by Oil-soluble Initiators. II. Kinetic Behavior of Styrene Emulsion Polymerization Initiated by 2,2′-Azoisobutyronitrile. J. Polym. Sci., Part A: Polym. Chem. 1991, 29, 987.
10. Nomura, M.; Ikoma, J.; Fujita, K. Kinetics and Mechanisms of Emulsion Polymerization Initiated by Oil-Soluble Initiator. IV. Kinetic Modeling of Unseeded Emulsion Polymerization Initiated by 2,2′-Azobisisobutyronitrile. J. Polym. Sci., Part A: Polym. Chem. 1993, 31, 2103.
11. Nomura, M.; Kamada, T.; Suzuki, K.; Fujita, K. Effect of Water-Solubility of Oil-Soluble Initiators on the Particle Formation in the Emulsion Polymerization of Styrene. Proc. 75th ACS Polym. Mater. Sci. Eng. 1999, 80, 516.