Mechanism of the Norrish-Yang photocyclization reaction of an alanine derivative in the singlet state: Origin of the chiral-memory effect

Angewandte Chemie - International Edition

Volumn 44, Issue 16, 2005, Pages 2390-2393

  Sinicropi, Adalgisa ^b   Barbosa, Frédérique ^a,c   Basosi, Riccardo ^b   Giese, Bernd ^a   Olivucci, Massimo ^b  

^a UNIVERSITY OF BASEL   (Switzerland)

^b UNIVERSITY OF SIENA   (Italy)

^c CEREP   (France)

Author keywords

Ab initio calculations; Chiral memory; Conical intersections; Photocyclization; Reaction mechanisms

Indexed keywords

DERIVATIVES; HYDROGEN BONDS; MOLECULAR STRUCTURE; PHOTOCHEMICAL REACTIONS; STEREOCHEMISTRY;

CHIRAL-MEMORY EFFECT; PHOTOCYCLIZATION; PHOTOREACTIONS; REACTION PATHWAYS;

AMINO ACIDS;

EID: 18044387608     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200461898     Document Type: Article

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