A facile route of formation of lignin-carbohydrate complexes during alkaline pulping

Journal of Pulp and Paper Science

Volumn 29, Issue 2, 2003, Pages 42-47

  Letumier F ^a   Ammalahti E ^b   Sipila J ^c   Vourinen, T ^a  

^a AALTO UNIVERSITY   (Finland)

^b VTT TECHNICAL RESEARCH CENTRE OF FINLAND   (Finland)

^c UNIVERSITY OF HELSINKI   (Finland)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; CARBOHYDRATES; CHEMICAL BONDS; COMPLEXATION; GAS CHROMATOGRAPHY; HEAT TREATMENT; HIGH TEMPERATURE EFFECTS; KRAFT PROCESS; LIGNIN; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STRUCTURE (COMPOSITION);

CANNIZZARO REACTION; FACILE ROUTE; NUCLEOPHILIC ADDITION;

PULP REFINING;

ALKALINE PULPING; BOND CLEAVAGE; COMPLEX COMPOUNDS; KRAFT PULPING; LIGNINS; METHOXYL GROUPS; NUCLEAR MAGNETIC RESONANCE;

EID: 17944397796     PISSN: 08266220     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (20)

1. Engström, N., Vikkula, A., Teleman, A. and Vuorinen, T., "Structure of Hemicelluloses in Pine Kraft Cooking Liquors", 8th Intl. Symp. Wood. Pulping Chem., Helsinki, Finland, III:195-200 (1995).
2. Gellerstedt, G. and Al-Dajani, W.W., "On the Bleachability of Kraft Pulps", 9th Intl. Symp. Wood. Pulping Chem., PAPTAC, A1:1-4 (1997).
3. Lachenal, D., Cardona, D. and Chirat, C., "Fundamentals of Extended Oxygen Bleaching", 9th Intl. Symp. Wood. Pulping Chem., PAPTAC, D1:1-5 (1997).
4. Karlsson, O. and Westermark, U., "Evidence for Chemical Bonds between Lignin and Cellulose in Kraft Pulps", J. Pulp Paper Sci. 22(10):397-401 (1996).
5. Kotelnikova, N.E., "Characterisation of Structural Features of Lignocarbohydrate Complexes after Sulfate Cooking of Poplar Wood by Spectroscopic and X-Ray Methods" in J.F. Kennedy, G.O. Phillips and P.A. Williams, Eds., Lignocellulosics: Science, Technology, Development and Use, Ellis Horwood, New York, NY, USA, 597-604 (1992).
6. Lai, Y.Z. and Sarkanen, K.V., "Isolation and Structural Studies" in K.V. Sarkanen and C.H. Ludwig, Eds., Lignins, Occurrence, Formation, Structure and Reactions, Wiley & Sons, New York, NY, USA, 165-240 (1971).
7. Omori, S., Aoyama, M. and Sakakibara, A., "Hydrolysis of Lignin with Dioxane-Water. XIX. Reaction of β-O-4 Lignin Model Compounds in the Presence of Carbohydrates", Holzforschung 52:391-397 (1998).
8. Johnson, K.G. and Overend, R.P., "Lignin-Carbohydrate Complexes from Populus deltoides", Holzforschung 45:469-475 (1991).
9. Košíková, B. and Ebringerova, E., "Lignin-Carbohydrate Bonds in a Residual Soda Spruce Pulp Lignin", Wood Sci. Technol. 28:291-296 (1994).
10. Iversen, T. and Wännström, S., "Lignin-Carbohydrate Bonds in a Residual Lignin Isolated from Pine Kraft Pulps", Holzforschung 40:19-22 (1986).
11. 13C NMR Spectroscopy", Carbohydr. Res. 272:55-71 (1995).
12. Johansson, M.H. and Samuelson, O., "Epimerization and Degradation of 2-O-(4-O-Methyl-α-D-glucopyranosyluronic Acid)-D-Xylitol in Alkaline Medium", Carbohydr. Res. 54:295-299 (1977).
13. Johansson, M.H. and Samuelson, O., "Alkaline Destruction of Birch Xylan in the Light of Recent Investigations of its Structure", Svensk Papperstidn. 16:519-524 (1997).
14. Pigman, W. and Anet, E.F.L.J., "Mutarotations and Actions of Acids and Bases" in The Carbohydrates: Chemistry and Biochemistry, W. Pigman and D. Horton., Eds., Academic Press, New York, NY, USA, 165-194 (1972).
15. Klemer, A., Lukowski, H. and Zerhusen, F., "Uber den Alkanischen Abbau Einiger D-Glucose-methyläther: 2-Methyl-und 2,4,6-Trimethyl-D-glucoseen-(2.3)", Chem. Ber. 96:1515-1519 (1963).
16. Tokimatsu, T., Umezawa, T. and Shimada, M., "Synthesis of Four Diastereomeric Lignin-Carbohydrate-Complex (LCC) Model Compounds Composed of a β-0-4 Lignin Model Linked to Methyl β-D-glucoside", Holzforschung 50:156-160 (1996).
17. 4", Holzforschung 49:418-422 (1995).
18. Vuorinen, T. and Alen, R., "Carbohydrates" in E. Sjöström and R. Alén, Eds., Analytical Methods in Wood Chemistry, Pulping and Papermaking, Springer, Berlin, Germany, 37-75 (1999).
19. Lehmann, J., "Structure of Mono-and Oligosaccharides" in Carbohydrates: Structure and Biology, Thieme, Stuttgart, Germany 2-37 (1998).
20. Stoddart, J.F., "Conformation" Stereochemistry of Carbohydrates, Wiley-Interscience, New York, NY, USA, 47-122 (1971).