Resonances in the Ba...FCH3+hv→BaF+CH3 reaction probability

Journal of Chemical Physics

Volumn 111, Issue 2, 1999, Pages 460-463

  Skowronek, S ^a   Jimenez J B ^a   Gonzalez Urena A ^a  

^a INSTITUTO PLURIDISCIPLINAR   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 17944390857     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.479326     Document Type: Article

References (28)

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18. -1, one may conclude that the BaF product can either be formed in an electronically excited state or in its ground state, but with v≥3. Both BaF ionization potential and fundamental frequency values are taken from K. P. Huber and G. Herzberg, Molecular Spectra and Molecular Structure, Vol. IV. Constants of Diatomic Molecules (Van Nostrand Reinhold, New York, 1979).
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21. Actually, rather than a reaction probability this ratio can be taken as a partial cross section leading into the photodissociation i channel. [See, for example, R. Schinke, Photodissociation Dynamics (Cambridge University Press, Cambridge, 1992).] Nevertheless, the small range of impact parameters associated with the excited van der Waals molecular configuration, as well as the involved photoinitiated intracluster reaction, suggest to us to consider it as a (bimolecular) reaction probability.
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