Efficient method for the esterification of carboxylic acids with alcohols using di-2-thienyl carbonate promoted by catalytic amounts of DMAP and Hf(OTf)4

Chemistry Letters

Volumn 34, Issue 2, 2005, Pages 190-191

  Oohashi, Yoshiaki ^a   Fukumoto, Kentarou ^a   Mukaiyama, Teruaki ^a,b  

^a KITASATO INSTITUTE   (Japan)

^b KITASATO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

4 DIMETHYLAMINOPYRIDINE; ALCOHOL DERIVATIVE; CARBONIC ACID; CARBOXYLIC ACID DERIVATIVE; DI 2 THIENYLCARBONIC ACID; HAFNIUM; HAFNIUM 4 TRIFLUOROMETHANESULFONIC ACID; TRIFLUOROMETHANESULFONIC ACID; UNCLASSIFIED DRUG;

ADDITION REACTION; ARTICLE; CATALYSIS; CATALYST; ENERGY YIELD; ESTERIFICATION; MOLECULAR INTERACTION; REACTION ANALYSIS; STRUCTURE ANALYSIS; TECHNIQUE;

EID: 17844375387     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2005.190     Document Type: Article

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28. 3CN (0.05 mL) was added. The reaction mixture was stirred for 30 min at room temperature and then saturated aqueous sodium hydrogencarbonate was added. The mixture was extracted with ether, and the organic layer was washed with water and brine, dried over sodium sulfate. After filtration of the mixture and evaporation of the solvent, the crude product was purified by preparative thin layer chromatography to afford the corresponding ester (42.8 mg, 90%) as a colorless oil.