Organic reactions increasing the absorption index of atmospheric sulfuric acid aerosols

Geophysical Research Letters

Volumn 32, Issue 3, 2005, Pages 1-5

  Noziere B ^a   Esteve, W ^a  

^a UNIVERSITY OF MIAMI   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; ALDEHYDES; ATMOSPHERIC AEROSOLS; KETONES; LIGHT ABSORPTION; ULTRAVIOLET RADIATION; UPPER ATMOSPHERE;

ABSORPTION INDEX; ALDOL CONDENSATION; ORGANIC REACTIONS; RADIATIVE FORCING;

SULFURIC ACID;

AEROSOL; ATMOSPHERIC CHEMISTRY; SULFURIC ACID;

EID: 17744397724     PISSN: 00948276     EISSN: None     Source Type: Journal    
DOI: 10.1029/2004GL021942     Document Type: Article

References (20)

1. Baigrie, L. M., R. A. Cox, H. Slebocka-Tilk, M. Tencer, and T. Tidwell (1985), Acid-catalyzed enolization and aldol condensation of acetaldehyde, J. Am. Chem. Soc., 107, 3640-3645.
2. Duncan, J. L., L. R. Schindler, and J. T. Roberts (1998), A new sulfate-mediated reaction: Conversion of acetone to trimethylbenzene in the presence of liquid sulfuric acid, Geophys. Res. Lett., 25, 631-634.
3. Duncan, J. L., L. R. Schindler, and J. T. Roberts (1999), Chemistry at and near the surface of liquid sulfuric acid: A kinetic, thermodynamic, and mechanistic analysis of heterogeneous reactions of acetone, J. Phys. Chem. B, 103, 7247-7259.
4. Gosse, S. F., M. Wang, D. Labrie, and P. Chylek (1997), Imaginary part of the refractive index of sulfates and nitrates in the 0.7-2.6 μm spectral region, Appl. Opt., 36, 3622-3634.
5. Hanson, D. R., A. R. Ravishankara, and S. Solomon (1994), Heterogeneous reactions in sulfuric acid aerosols: A framework for model calculations, J. Geophys. Res., 99, 3615-3629.
6. Haywood, J. M., and K. P. Shine (1995), The effect of anthropogenic sulfate and soot aerosol on the clear sky planetary radiation budget, Geophys. Res. Lett., 22, 603-606.
7. Kane, S. M., R. S. Timonen, and M.-T. Leu (1999), Heterogeneous chemistry of acetone in sulfuric acid solutions: Implications for the upper troposphere, J. Phys. Chem. A, 103, 9259-9265.
8. Klassen, J. K., J. Lynton, D. M. Golden, and L. R. Williams (1999), Solubility of acetone in low-temperature (210 K-240 K) sulfuric acid solutions, J. Geophys. Res., 104, 26,355-26,361.
9. Liler, M. (1971), Reaction Mechanisms in Sulphuric Acid, pp. 231-232, Elsevier, New York.
10. McQuarrie, D. A. (1983), Quantum Chemistry, p. 87, Univ. Sci. Books, Mill Valley, Calif.
11. Michelsen, R. R., S. F. M. Ashbourn, and L. T. Iraci (2004), Dissolution, speciation, and reaction of acetaldehyde in cold sulfuric acid, J. Geophys. Res., 109, D23205, doi:10.1029/2004JD005041.
12. Myhre, G., F. Stordal, K. Restad, and I. S. A. Isaksen (1998), Estimation of the direct radiative forcing due to sulfate and soot aerosols, Tellus, Ser. B, 50, 463-477.
13. 4 at different temperatures and compositions: Variations in dissociation and optical properties, J. Phys. Chem. A, 107, 1979-1991.
14. Noziere, B., and D. Riemer (2003), The chemical processing of gas-phase carbonyl compounds by sulfuric acid aerosols: 2.4-pentanedione, Atmos. Environ., 37, 841-851.
15. Palmer, K. F., and D. Williams (1975), Optical constants of sulfuric acid: Application to the clouds of Venus?, Appl. Opt., 14, 208-218.
16. Ramaswamy, V., et al. (2001), Radiative forcing of climate change, in Climate Change 2001: The Scientific Basis: Contribution of Working Group I to the Third Assessment Report of the Intergovernmental Panel on Climate Change, edited by J. T. Houghton et al., pp. 289-348, Cambridge Univ. Press, New York.
17. Sander, R. (1999), Compilation of Henry's Law Constants for inorganic and organic species of potential importance in environmental chemistry (version 3), http://www.mpch-mainz.mpg.de/~sander/res/.
18. Seinfeld, J. H., and S. N. Pandis (1998), Atmospheric Chemistry and Physics, pp. 217, 1169, John Wiley, Hoboken, N. J.
19. Singh, H. B., Y. Chen, A. Staudt, D. J. Jacob, D. Blake, B. Heikes, and J. Snow (2001), Evidence from the Pacific troposphere for large global sources of oxygenated organic compounds, Nature, 410, 1078-1081.
20. Zasetsky, A. Yu., J. J. Sloan, R. Escribano, and D. Fernandez (2002), A new method for the quantitative identification of the composition, size and density of stratospheric aerosols from high resolution IR satellite measurements, Geophys. Res. Lett., 29(22), 2071, doi:10.1029/ 2002GL015816.