Frontal polymerization of acrylic monomers for the consolidation of stone

Polymers for Advanced Technologies

Volumn 16, Issue 4, 2005, Pages 293-298

  Vicini, Silvia ^a   Mariani, Alberto ^b   Princi, Elisabetta ^a   Bidali, Simone ^b   Pincin, Silvia ^a   Fiori, Stefano ^b   Pedemonte, Enrico ^a   Brunetti, Antonio ^b  

^a UNIVERSITY OF GENOA   (Italy)

^b UNIVERSITY OF SASSARI   (Italy)

Author keywords

Adhesion; Copolymerization; Fluoropolymers; Frontal polymerization; Stone consolidation and protection

Indexed keywords

ACRYLICS; PLASTIC PRODUCTS; POLYMERIZATION; SOCIAL ASPECTS;

CULTURAL HERITAGE; FRONTAL POLYMERIZATION (FP); POLYMERIC COMPOUNDS; STONES;

MONOMERS;

POLYMER SCIENCE;

EID: 17744392622     PISSN: 10427147     EISSN: None     Source Type: Journal    
DOI: 10.1002/pat.584     Document Type: Article

References (28)

1. Amoroso GG, Fassina V. Stone Decay and Conservation. Elsevier: Losanna, 1983.
2. Flory PJ. Principles of Polymer Chemistry. Cornell University Press: Ithaca, NY, 1962.
3. Vicini S, Princi E, Moggi G, Pedemonte E. Consolidation and protection of stone manufactered object of artistic interest with polymeric materials prepared by in situ polymerization. La Chimica e l'Industria 1999; 81: 1013.
4. Vicini S, Margutti S, Moggi G, Pedemonte E. In situ copolymerisation of ethylmethacrylate and methylacrylate for the restoration of stone artefacts. J. Cultural Heritage 2001; 2 143.
5. Vicini S, Margutti S, Princi E, Moggi G, Pedemonte E. In situ copolymerization for the consolidation of stone artefacts. Macromol. Chem. Phys. 2002; 203: 1413.
6. www.rohmhaas.com/coatings/ (last visited 02/02/2005).
7. Chiantore O, Lazzari M. Photo-oxidative stability of paraloid acrylic protective polymers. Polymer 2001; 42: 17.
8. Vicini S, Princi E, Pedemonte E, Lazzari M, Chiantore O. In situ polymerisation of unfluorinated and fluorinated acrylic copolymers for the conservation of stone. J. Appl. Polym. Sci. 2004; 91: 3202.
9. Ferry JD. Viscoelastic Properties of Polymer (3rd edn). John Wiley: New York, 1980.
10. Pojman JA. Traveling fronts of methacrylic acid polymerization. J. Am. Chem. Soc. 1991; 113: 6284.
11. Khan AM, Pojman JA. The use of frontal polymerization in polymer synthesis. Trends Polym. Sci. 1996; 4: 253.
12. Mariani A, Fiori S, Chekanov Y, Pojman JA. Frontal ring-opening metathesis polymerization of dicyclopentadiene. Macromolecules 2001; 34: 6539.
13. Brunetti A, Princi E, Vicini S, Pincin S, Bidali S, Mariani A. Visualization of monomer and polymer inside porous stones by using X-ray tomography. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 2004; 222 235-241.
14. Chechilo NM, Khvilivitskii RJ, Enikolopyan NS. On the phenomenon of polymerization reaction spreading. Dokl. Akad. Nauk SSSR 1972; 204: 1180.
15. Fortenberry DI, Pojman JA. Solvent-free synthesis of polyacrylamide by frontal polymerization. J. Polym. Sci., Part A: Polym Chem. 2000; 38: 1129.
16. Chekanov Y, Arrington D, Brust G, Pojman JA. Frontal curing of epoxy resin: comparison of mechanical and thermal properties to batch cured materials. J. Appl. Polym. Sci. 1997; 66: 1209.
17. Kim C, Teng H, Tucker CL, White SR. The continuous curing process for thermoset polymer composites. Part 1: Modeling and demonstration. J. Comp. Mater. 1995; 29: 1222.
18. Pojman JA, Elcan W, Khan AM, Mathias L. Binary polymerization fronts: a new method to produce simultaneous interpenetrating polymer networks (SINs). J. Polym. Sci., Part A: Polym Chem. 1997; 35: 227.
19. Brady RF, Laronson C. Elastomeric fluorinated polyurethane coatings for nontoxic fouling control. Biofouling 2003; 19: 63.
20. Brewis DM. Adhesion to polymers: how important are weak boundary layers? Int. J. Adhesion & Adhesives 1993; 13: 251.
21. Castelvetro V, Aglietto M, Montagnini di Mirabello L, Toniolo L, Peruzzi R, Chiantore O. Adapting the properties of new fluorinated acrylic polymers to suit the conservation of ancient monuments. Surface Coat. Intern. 1998; 11: 551.
22. Ciardelli F, Aglietto M, Montagnini di Mirabello L, Passaglia E, Giancristoforo S, Castelvetro V, Ruggeri G. New fluorinated acrylic polymers for improving weatherability of building stone materials. Prog. Org. Coat. 1997; 15: 43.
23. Alessandrini G, Aglietto M, Castelvetro V, Ciardelli F, Peruzzi R, Toniolo L. Comparative evaluation of fluorinated and unfluorinated acrylic copolymers as water-repellent coating material for stone. J. Appl. Polym. Sci. 2000; 76: 962.
24. Carpene' F. Le meraviglie della Pietra di Finale. Bacchetta Ed: Alberga, 1997.
25. Vicini S, Princi E, Gattorno S, Massa B, Pedemonte E. Pietra di Finale: caratterizzazione petrografia e problemi di reversibilità nel consolidamento mediante polimerizzazione in situ. Proceedings of the XIX Convegno Internazionale Scienza e Beni Culturali "La reversibilità nel restauro", Bressanone, 2003; 243.
26. Normal Protocol 11/85. Water Absorption by Capillarity-Capillarity Absorption Coefficient. ICR-CNR: Rome, 1986.
27. Normal Protocol 7/81. Water Absorption by Complete Immersion-Capacity of Imbibition. ICR-CNR: Rome, 1981.
28. Normal Protocol 21/85. Water Vapour Permeability. ICR-CNR: Rome, 1986.