Dry reforming kinetics over a bulk molybdenum carbide catalyst

Chemical Engineering Science

Volumn 60, Issue 13, 2005, Pages 3553-3559

  Lamont, David C ^a   Thomson, William J ^a  

^a Washington State University   (United States)

Author keywords

Dry methane reforming; Kinetics; Mass transfer; Molybdenum carbide; Stability

Indexed keywords

AGGLOMERATION; CARBON MONOXIDE; CHEMISORPTION; MASS TRANSFER; METHANE; MOLYBDENUM COMPOUNDS; NICKEL; PARTIAL PRESSURE; PRECIOUS METALS; REACTION KINETICS; REFORMING REACTIONS;

DIFFERENTIAL ANALYSIS; DRY REFORMING KINETICS; MOLYBDENUM CARBIDE; RATE EXPRESSION;

CATALYSTS;

KINETICS;

EID: 17644425740     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2005.01.021     Document Type: Article

References (22)

1. P.A. Aegerter, W.W.C. Quigley, G.J. Simpson, D.D. Ziegler, J.W. Logan, K.R. McCrea, S. Glazier, and M. Bussell Thiophene hydrodesulfurization over alumina-supported molybdenum carbide and nitride catalysts adsorption sites, catalytic activities and nature of the active surface Journal of Catalysis 165 1996 109 121
2. A.J. Brungs, A.P.E. York, and M.L.H. Green Comparison of the group V and VI transition metal carbides for methane dry reforming and thermodynamic prediction of their relative stabilities Catalysis Letters 57 1999 65 69
3. J.B. Claridge, A.P.E. York, A.J. Brungs, C. Marquez-Alvarez, J. Sloan, S.C. Tsang, and M.L.H. Green New catalysts for the conversion of methane to synthesis gas molybdenum and tungsten carbide Journal of Catalysis 180 1998 85 100
4. 2C catalysts under fuel reforming conditions Applied Catalysis A 253 2003 397 407
5. B. Diaz, S.J. Sawhill, D.H. Bale, R. Main, D.C. Phillips, S. Korlann, R. Self, and M.E. Bussell Hydrodesulfurization over supported monometallic, bimetallic and promoted carbide and nitride catalysts Catalysis Today 86 2003 191 209
6. G.M. Dolce, P.E. Savage, and L.T. Thompson Hydrotreatment activities of supported molybdenum nitrides and carbides Energy and Fuels 11 1997 668 675
7. LaMont, D.C., Thomson, W.J., 2004. The influence of mass transfer conditions on the stability of molybdenum carbide for dry methane reforming. Applied Catalysis A 274, 173-178.
8. D.C. LaMont, A.J. Gilligan, A.R.S. Darujati, A.S. Chellappa, and W.J. Thomson The effect of Mo 2 C synthesis and pretreatment on catalytic stability in oxidative reforming environments Applied Catalysis A 255 2003 239 253
9. E. Lecrenay, K. Sakanishi, and I. Mochida Catalytic hydrodesulfurization of gas oil and model sulfur compounds over commercial and laboratory-made CoMo and NiMo catalysts activity and reaction scheme Catalysis Today 39 1997 13 20
10. J.S. Lee, and M. Boudart Hydrodesulfurization of thiophene over unsupported molybdenum carbide Applied Catalysis 19 1985 207 210
11. 3 catalyst Applied Catalysis A 228 2002 227 235
12. 4 over unsupported and zirconia supported molybdenum carbide catalysts Catalysis Today 77 2002 161 165
13. 3 catalyst Industrial and Engineering Chemistry Research 36 1997 5180 5188
14. J. Patt, D.J. Moon, C. Phillips, and L. Thompson Molybdenum carbide catalysts for water-gas shift Catalysis Letters 65 2000 193 195
15. M.L. Pritchard, R.L. McCauley, B.N. Gallaher, and W.J. Thomson The effects of sulfur and oxygen on the catalytic activity of molybdenum carbide during dry methane reforming Applied Catalysis A 275 2004 213 220
16. S. Ramanathan, and S.T. Oyama New catalysts for hydroprocessing transition metal carbides and nitrides The Journal of Physical Chemistry 99 1995 16365 16372
17. 2 reforming Journal of Catalysis 201 2001 206 212
18. 3 catalysts Journal of Catalysis 204 2001 468 511
19. T. Xiao, A.P.E. York, V.C. Williams, H. A.-Megren, A. Hanif, X. Zhou, and M.L.H. Green Preparation of molybdenum carbides using butane and their catalytic performance Chemistry of Materials 12 2000 3896 3905
20. T. Xiao, A. Hanif, A.P.E. York, Y. Nishizaka, and M.L.H. Green Study on the mechanism of partial oxidation of methane to synthesis gas over molybdenum carbide catalyst Physical Chemistry Chemical Physics 4 2002 4549 4554
21. A.P.E. York, J.B. Claridge, A.J. Brungs, S.C. Tsang, and M.L.H. Green Molybdenum and tungsten carbides as catalysts for the conversion of methane to synthesis gas using stoichiometric feedstocks Chemical Communications 1 1997 39 40
22. Z.L. Zhang, V.A. Tsipouriari, A.M. Efstathiou, and X.E. Verykios Reforming of methane with carbon dioxide to synthesis gas over supported rhodium catalysts I. Effects of support and metal crystallite size on reaction activity and deactivation characteristics Journal of Catalysis 158 1996 51 63