MCM-41 supported water-soluble TPPTS-Rh complex in ionic liquids: A new robust catalyst for olefin hydroformylation

Chemistry Letters

Volumn 34, Issue 2, 2005, Pages 220-221

  Yang, Yong ^a   Lin, Haiqiang ^a   Deng, Changxi ^a   She, Jiarong ^a   Yuan, Youzhu ^a  

^a XIAMEN UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE; BENZENE; GUANIDINE; HEXANE; LACTIC ACID; MCM 41; RHODIUM; TETRAMETHYLGUANIDINIUM LACTIC ACID; TRIPHENYLPHOSPHINE; UNCLASSIFIED DRUG; WATER;

ARTICLE; CATALYSIS; CATALYST; HYDROFORMYLATION; IONIZATION; MOLECULAR DYNAMICS; PERFORMANCE; POROSITY; REACTION ANALYSIS; SENSITIVITY ANALYSIS; SOLUBILIZATION; STEREOCHEMISTRY; STRUCTURE ANALYSIS; SULFONATION;

EID: 17644421918     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2005.220     Document Type: Article

References (23)

1. For example see, "Ionic Liquids in Synthesis," ed. by P. Wasserscheid and T. Weldon, Wiley-VCH (2003); C. E. Song, Chem. Commun., 2004, 1033; S. T. Handy, Chem. - Eur. J., 9, 2938 (2003) ; J. Dupont, R. F. de Souza, and P. A. Z. Suarez, Chem. Rev., 102, 3667 (2002); R. Sheldon, Chem. Commun., 2001, 2399; P. Wasserscheid and W. Keim, Angew. Chem., Int. Ed., 39, 3772 (2000).
2. For example see, "Ionic Liquids in Synthesis," ed. by P. Wasserscheid and T. Weldon, Wiley-VCH (2003); C. E. Song, Chem. Commun., 2004, 1033; S. T. Handy, Chem. - Eur. J., 9, 2938 (2003) ; J. Dupont, R. F. de Souza, and P. A. Z. Suarez, Chem. Rev., 102, 3667 (2002); R. Sheldon, Chem. Commun., 2001, 2399; P. Wasserscheid and W. Keim, Angew. Chem., Int. Ed., 39, 3772 (2000).
3. For example see, "Ionic Liquids in Synthesis," ed. by P. Wasserscheid and T. Weldon, Wiley-VCH (2003); C. E. Song, Chem. Commun., 2004, 1033; S. T. Handy, Chem. - Eur. J., 9, 2938 (2003) ; J. Dupont, R. F. de Souza, and P. A. Z. Suarez, Chem. Rev., 102, 3667 (2002); R. Sheldon, Chem. Commun., 2001, 2399; P. Wasserscheid and W. Keim, Angew. Chem., Int. Ed., 39, 3772 (2000).
4. For example see, "Ionic Liquids in Synthesis," ed. by P. Wasserscheid and T. Weldon, Wiley-VCH (2003); C. E. Song, Chem. Commun., 2004, 1033; S. T. Handy, Chem. - Eur. J., 9, 2938 (2003) ; J. Dupont, R. F. de Souza, and P. A. Z. Suarez, Chem. Rev., 102, 3667 (2002); R. Sheldon, Chem. Commun., 2001, 2399; P. Wasserscheid and W. Keim, Angew. Chem., Int. Ed., 39, 3772 (2000).
5. For example see, "Ionic Liquids in Synthesis," ed. by P. Wasserscheid and T. Weldon, Wiley-VCH (2003); C. E. Song, Chem. Commun., 2004, 1033; S. T. Handy, Chem. - Eur. J., 9, 2938 (2003) ; J. Dupont, R. F. de Souza, and P. A. Z. Suarez, Chem. Rev., 102, 3667 (2002); R. Sheldon, Chem. Commun., 2001, 2399; P. Wasserscheid and W. Keim, Angew. Chem., Int. Ed., 39, 3772 (2000).
6. For example see, "Ionic Liquids in Synthesis," ed. by P. Wasserscheid and T. Weldon, Wiley-VCH (2003); C. E. Song, Chem. Commun., 2004, 1033; S. T. Handy, Chem. - Eur. J., 9, 2938 (2003) ; J. Dupont, R. F. de Souza, and P. A. Z. Suarez, Chem. Rev., 102, 3667 (2002); R. Sheldon, Chem. Commun., 2001, 2399; P. Wasserscheid and W. Keim, Angew. Chem., Int. Ed., 39, 3772 (2000).
7. Y. Chauvin, L. Mussmann, and H. Olivier, Angew. Chem., Int. Ed., 34, 2698 (1995); J. Dupont, S. M. Silva, and R. F. de Souza, Catal. Lett., 77, 131 (2001).
8. Y. Chauvin, L. Mussmann, and H. Olivier, Angew. Chem., Int. Ed., 34, 2698 (1995); J. Dupont, S. M. Silva, and R. F. de Souza, Catal. Lett., 77, 131 (2001).
9. D. DeCastro, E. Sauvage, M. H. Valkenberg, and W. F. Hölderich, J. Catal., 196, 86 (2000); J. Huang, T. Jiang, H. X. Gao, B. X. Han, Z. M. Liu, W. Z. Wu, Y. H. Chang, and G. Y. Zhao, Angew. Chem., Int. Ed., 43, 1397 (2004).
10. D. DeCastro, E. Sauvage, M. H. Valkenberg, and W. F. Hölderich, J. Catal., 196, 86 (2000); J. Huang, T. Jiang, H. X. Gao, B. X. Han, Z. M. Liu, W. Z. Wu, Y. H. Chang, and G. Y. Zhao, Angew. Chem., Int. Ed., 43, 1397 (2004).
11. C. P. Mehnert, R. A. Cook, N. C. Dispenziere, and M. Afework, J. Am. Chem. Soc., 124, 12932 (2002); C. P. Mehnert, E. J. Mozeleski, and R. A. Cook, Chem. Commun., 2002, 3010.
12. C. P. Mehnert, R. A. Cook, N. C. Dispenziere, and M. Afework, J. Am. Chem. Soc., 124, 12932 (2002); C. P. Mehnert, E. J. Mozeleski, and R. A. Cook, Chem. Commun., 2002, 3010.
13. A. Riisager, P. Wasserscheid, R. Van Hal, and R. Fehrmann, J. Catal., 219, 452 (2003); A. Riisager, K. M. Eriksen, P. Wasserscheid, and R. Fehrmann, Catal. Lett., 90, 149 (2003).
14. A. Riisager, P. Wasserscheid, R. Van Hal, and R. Fehrmann, J. Catal., 219, 452 (2003); A. Riisager, K. M. Eriksen, P. Wasserscheid, and R. Fehrmann, Catal. Lett., 90, 149 (2003).
15. 2 and TPPTS were dissolved in 10 mL of degassed dry methanol. After adding desired amount of IL, the solution was stirred at room temperature under Ar for 2h. The 0.5 g of carrier which was pre-treated under vacuum at 473 K for 2 h was added to the above solution. The mixture was stirred under Ar for 2 h. A light yellow SILPC was obtained by removal of solvent under vacuum, followed by drying in vacuum at 353 K for 24 h.
16. Q. R. Peng, Y. Yang, and Y. Z. Yuan, J. Mol. Catal. A: Chem., 219, 175 (2004).
17. A. Z. Z. Paulo, E. L. D. Jeane, and E. Sandra, Polyhedron, 7, 1217 (1996).
18. N. M. M. Mateus, L. C. Branco, N. M. T. Lourenco, and C. A. M. Afonso, Green Chem., 3, 347 (2003).
19. F. Favre, H. Olivier-Bourbigou, D. Commereuc, and L. Saussine, Chem. Commun., 2001, 1360.
20. C. P. Mehnert, R. A. Cook, N. C. Dispenziere, and E. J. Mozeleski, Polyhedron, 23, 2679 (2004).
21. T. Malmström, C. Andersson, and J. Hjortkjaer, J. Mol. Catal. A: Chem., 139, 139 (1999).
22. I. T. Horváth, Catal. Lett., 6, 43 (1990); Y. Z. Yuan, H. B. Zhang, Y. Q. Yang, Y. Zhang, and K. R. Tsai, Catal. Today, 74, 5 (2002).
23. I. T. Horváth, Catal. Lett., 6, 43 (1990); Y. Z. Yuan, H. B. Zhang, Y. Q. Yang, Y. Zhang, and K. R. Tsai, Catal. Today, 74, 5 (2002).